Water purification is the process of removing undesirable chemicals, biological contaminants, suspended solids, and gases from water. The goal is to produce water fit for specific purposes. Most water is purified and disinfected for human consumption (drinking water), but water purification may also be carried out for a variety of other purposes, including medical, pharmacological, chemical, and industrial applications. The methods used include physical processes such as filtration, sedimentation, and distillation; biological processes such as slow sand filters or biologically active carbon; chemical processes such as flocculation and chlorination; and the use of electromagnetic radiation such as ultraviolet light.
Water purification may reduce the concentration of particulate matter including suspended particles, parasites, bacteria, algae, viruses, and fungi as well as reduce the concentration of a range of dissolved and particulate matter.
The standards for drinking water quality are typically set by governments or by international standards. These standards usually include minimum and maximum concentrations of contaminants, depending on the intended use of the water.
Visual inspection cannot determine if water is of appropriate quality. Simple procedures such as boiling or the use of a household activated carbon filter are not sufficient for treating all possible contaminants that may be present in water from an unknown source. Even natural spring water – considered safe for all practical purposes in the 19th century – must now be tested before determining what kind of treatment, if any, is needed. Chemical and microbiological analysis, while expensive, are the only way to obtain the information necessary for deciding on the appropriate method of purification.
According to a 2007 World Health Organization (WHO) report, 1.1 billion people lack access to an improved drinking water supply; 88% of the 4 billion annual cases of diarrheal disease are attributed to unsafe water and inadequate sanitation and hygiene, while 1.8 million people die from diarrheal disease each year. The WHO estimates that 94% of these diarrheal disease cases are preventable through modifications to the environment, including access to safe water. Simple techniques for treating water at home, such as chlorination, filters, and solar disinfection, and for storing it in safe containers could save a huge number of lives each year. Reducing deaths from waterborne diseases is a major public health goal in developing countries.
The goals of the treatment are to remove unwanted constituents in the water and to make it safe to drink or fit for a specific purpose in industry or medical applications. Widely varied techniques are available to remove contaminants like fine solids, micro-organisms and some dissolved inorganic and organic materials, or environmental persistent pharmaceutical pollutants. The choice of method will depend on the quality of the water being treated, the cost of the treatment process and the quality standards expected of the processed water.
The processes below are the ones commonly used in water purification plants. Some or most may not be used depending on the scale of the plant and quality of the raw (source) water.
Pure water has a pH close to 7 (neither alkaline nor acidic). Sea water can have pH values that range from 7.5 to 8.4 (moderately alkaline). Fresh water can have widely ranging pH values depending on the geology of the drainage basin or aquifer and the influence of contaminant inputs (acid rain). If the water is acidic (lower than 7), lime, soda ash, or sodium hydroxide can be added to raise the pH during water purification processes. Lime addition increases the calcium ion concentration, thus raising the water hardness. For highly acidic waters, forced draft degasifiers can be an effective way to raise the pH, by stripping dissolved carbon dioxide from the water. Making the water alkaline helps coagulation and flocculation processes work effectively and also helps to minimize the risk of lead being dissolved from lead pipes and from lead solder in pipe fittings. Sufficient alkalinity also reduces the corrosiveness of water to iron pipes. Acid (carbonic acid, hydrochloric acid or sulfuric acid) may be added to alkaline waters in some circumstances to lower the pH. Alkaline water (above pH 7.0) does not necessarily mean that lead or copper from the plumbing system will not be dissolved into the water. The ability of water to precipitate calcium carbonate to protect metal surfaces and reduce the likelihood of toxic metals being dissolved in water is a function of pH, mineral content, temperature, alkalinity and calcium concentration.
One of the first steps in most conventional water purification processes is the addition of chemicals to assist in the removal of particles suspended in water. Particles can be inorganic such as clay and silt or organic such as algae, bacteria, viruses, protozoa and natural organic matter. Inorganic and organic particles contribute to the turbidity and color of water.
The addition of inorganic coagulants such as aluminum sulfate (or alum) or iron (III) salts such as iron(III) chloride cause several simultaneous chemical and physical interactions on and among the particles. Within seconds, negative charges on the particles are neutralized by inorganic coagulants. Also within seconds, metal hydroxide precipitates of the iron and aluminium ions begin to form. These precipitates combine into larger particles under natural processes such as Brownian motion and through induced mixing which is sometimes referred to as flocculation. Amorphous metal hydroxides are known as "floc". Large, amorphous aluminum and iron (III) hydroxides adsorb and enmesh particles in suspension and facilitate the removal of particles by subsequent processes of sedimentation and filtration.:8.2–8.3
Aluminum hydroxides are formed within a fairly narrow pH range, typically: 5.5 to about 7.7. Iron (III) hydroxides can form over a larger pH range including pH levels lower than are effective for alum, typically: 5.0 to 8.5.:679
In the literature, there is much debate and confusion over the usage of the terms coagulation and flocculation: Where does coagulation end and flocculation begin? In water purification plants, there is usually a high energy, rapid mix unit process (detention time in seconds) whereby the coagulant chemicals are added followed by flocculation basins (detention times range from 15 to 45 minutes) where low energy inputs turn large paddles or other gentle mixing devices to enhance the formation of floc. In fact, coagulation and flocculation processes are ongoing once the metal salt coagulants are added.:74–5
Organic polymers were developed in the 1960s as aids to coagulants and, in some cases, as replacements for the inorganic metal salt coagulants. Synthetic organic polymers are high molecular weight compounds that carry negative, positive or neutral charges. When organic polymers are added to water with particulates, the high molecular weight compounds adsorb onto particle surfaces and through interparticle bridging coalesce with other particles to form floc. PolyDADMAC is a popular cationic (positively charged) organic polymer used in water purification plants.:667–8
Waters exiting the flocculation basin may enter the sedimentation basin, also called a clarifier or settling basin. It is a large tank with low water velocities, allowing floc to settle to the bottom. The sedimentation basin is best located close to the flocculation basin so the transit between the two processes does not permit settlement or floc break up. Sedimentation basins may be rectangular, where water flows from end to end, or circular where flow is from the centre outward. Sedimentation basin outflow is typically over a weir so only a thin top layer of water—that furthest from the sludge—exits.
In 1904, Allen Hazen showed that the efficiency of a sedimentation process was a function of the particle settling velocity, the flow through the tank and the surface area of tank. Sedimentation tanks are typically designed within a range of overflow rates of 0.5 to 1.0 gallons per minute per square foot (or 1.25 to 2.5 meters per hour). In general, sedimentation basin efficiency is not a function of detention time or depth of the basin. Although, basin depth must be sufficient so that water currents do not disturb the sludge and settled particle interactions are promoted. As particle concentrations in the settled water increase near the sludge surface on the bottom of the tank, settling velocities can increase due to collisions and agglomeration of particles. Typical detention times for sedimentation vary from 1.5 to 4 hours and basin depths vary from 10 to 15 feet (3 to 4.5 meters).:9.39–9.40:790–1:140–2, 171
Inclined flat plates or tubes can be added to traditional sedimentation basins to improve particle removal performance. Inclined plates and tubes drastically increase the surface area available for particles to be removed in concert with Hazen's original theory. The amount of ground surface area occupied by a sedimentation basin with inclined plates or tubes can be far smaller than a conventional sedimentation basin.
As particles settle to the bottom of a sedimentation basin, a layer of sludge is formed on the floor of the tank which must be removed and treated. The amount of sludge generated is significant, often 3 to 5 percent of the total volume of water to be treated. The cost of treating and disposing of the sludge can impact the operating cost of a water treatment plant. The sedimentation basin may be equipped with mechanical cleaning devices that continually clean its bottom, or the basin can be periodically taken out of service and cleaned manually.
A subcategory of sedimentation is the removal of particulates by entrapment in a layer of suspended floc as the water is forced upward. The major advantage of floc blanket clarifiers is that they occupy a smaller footprint than conventional sedimentation. Disadvantages are that particle removal efficiency can be highly variable depending on changes in influent water quality and influent water flow rate.:835–6
When particles to be removed do not settle out of solution easily, dissolved air flotation (DAF) is often used. After coagulation and flocculation processes, water flows to DAF tanks where air diffusers on the tank bottom create fine bubbles that attach to floc resulting in a floating mass of concentrated floc. The floating floc blanket is removed from the surface and clarified water is withdrawn from the bottom of the DAF tank. Water supplies that are particularly vulnerable to unicellular algae blooms and supplies with low turbidity and high colour often employ DAF.:9.46
After separating most floc, the water is filtered as the final step to remove remaining suspended particles and unsettled floc.
The most common type of filter is a rapid sand filter. Water moves vertically through sand which often has a layer of activated carbon or anthracite coal above the sand. The top layer removes organic compounds, which contribute to taste and odour. The space between sand particles is larger than the smallest suspended particles, so simple filtration is not enough. Most particles pass through surface layers but are trapped in pore spaces or adhere to sand particles. Effective filtration extends into the depth of the filter. This property of the filter is key to its operation: if the top layer of sand were to block all the particles, the filter would quickly clog.
To clean the filter, water is passed quickly upward through the filter, opposite the normal direction (called backflushing or backwashing) to remove embedded or unwanted particles. Prior to this step, compressed air may be blown up through the bottom of the filter to break up the compacted filter media to aid the backwashing process; this is known as air scouring. This contaminated water can be disposed of, along with the sludge from the sedimentation basin, or it can be recycled by mixing with the raw water entering the plant although this is often considered poor practice since it re-introduces an elevated concentration of bacteria into the raw water.
Some water treatment plants employ pressure filters. These work on the same principle as rapid gravity filters, differing in that the filter medium is enclosed in a steel vessel and the water is forced through it under pressure.
Slow sand filters may be used where there is sufficient land and space, as the water must be passed very slowly through the filters. These filters rely on biological treatment processes for their action rather than physical filtration. The filters are carefully constructed using graded layers of sand, with the coarsest sand, along with some gravel, at the bottom and finest sand at the top. Drains at the base convey treated water away for disinfection. Filtration depends on the development of a thin biological layer, called the zoogleal layer or Schmutzdecke, on the surface of the filter. An effective slow sand filter may remain in service for many weeks or even months if the pretreatment is well designed and produces water with a very low available nutrient level which physical methods of treatment rarely achieve. Very low nutrient levels allow water to be safely sent through distribution systems with very low disinfectant levels, thereby reducing consumer irritation over offensive levels of chlorine and chlorine by-products. Slow sand filters are not backwashed; they are maintained by having the top layer of sand scraped off when flow is eventually obstructed by biological growth.
A specific "large-scale" form of slow sand filter is the process of bank filtration, in which natural sediments in a riverbank are used to provide a first stage of contaminant filtration. While typically not clean enough to be used directly for drinking water, the water gained from the associated extraction wells is much less problematic than river water taken directly from the major streams where bank filtration is often used.
Membrane filters are widely used for filtering both drinking water and sewage. For drinking water, membrane filters can remove virtually all particles larger than 0.2 μm—including giardia and cryptosporidium. Membrane filters are an effective form of tertiary treatment when it is desired to reuse the water for industry, for limited domestic purposes, or before discharging the water into a river that is used by towns further downstream. They are widely used in industry, particularly for beverage preparation (including bottled water). However no filtration can remove substances that are actually dissolved in the water such as phosphates, nitrates and heavy metal ions.
Ultrafiltration membranes use polymer membranes with chemically formed microscopic pores that can be used to filter out dissolved substances avoiding the use of coagulants. The type of membrane media determines how much pressure is needed to drive the water through and what sizes of micro-organisms can be filtered out.
Ion exchange: Ion exchange systems use ion exchange resin- or zeolite-packed columns to replace unwanted ions. The most common case is water softening consisting of removal of Ca2+ and Mg2+ ions replacing them with benign (soap friendly) Na+ or K+ ions. Ion exchange resins are also used to remove toxic ions such as nitrite, lead, mercury, arsenic and many others.
Precipitative softening::13.12–13.58 Water rich in hardness (calcium and magnesium ions) is treated with lime (calcium oxide) and/or soda-ash (sodium carbonate) to precipitate calcium carbonate out of solution utilizing the common-ion effect.
Electrodeionization: Water is passed between a positive electrode and a negative electrode. Ion exchange membranes allow only positive ions to migrate from the treated water toward the negative electrode and only negative ions toward the positive electrode. High purity deionized water is produced continuously, similar to ion exchange treatment. Complete removal of ions from water is possible if the right conditions are met. The water is normally pre-treated with a reverse osmosis unit to remove non-ionic organic contaminants, and with gas transfer membranes to remove carbon dioxide. A water recovery of 99% is possible if the concentrate stream is fed to the RO inlet.
Disinfection is accomplished both by filtering out harmful micro-organisms and by adding disinfectant chemicals. Water is disinfected to kill any pathogens which pass through the filters and to provide a residual dose of disinfectant to kill or inactivate potentially harmful micro-organisms in the storage and distribution systems. Possible pathogens include viruses, bacteria, including Salmonella, Cholera, Campylobacter and Shigella, and protozoa, including Giardia lamblia and other cryptosporidia. After the introduction of any chemical disinfecting agent, the water is usually held in temporary storage – often called a contact tank or clear well – to allow the disinfecting action to complete.
The most common disinfection method involves some form of chlorine or its compounds such as chloramine or chlorine dioxide. Chlorine is a strong oxidant that rapidly kills many harmful micro-organisms. Because chlorine is a toxic gas, there is a danger of a release associated with its use. This problem is avoided by the use of sodium hypochlorite, which is a relatively inexpensive solution used in household bleach that releases free chlorine when dissolved in water. Chlorine solutions can be generated on site by electrolyzing common salt solutions. A solid form, calcium hypochlorite, releases chlorine on contact with water. Handling the solid, however, requires more routine human contact through opening bags and pouring than the use of gas cylinders or bleach, which are more easily automated. The generation of liquid sodium hypochlorite is inexpensive and also safer than the use of gas or solid chlorine. Chlorine levels up to 4 milligrams per liter (4 parts per million) are considered safe in drinking water.
All forms of chlorine are widely used, despite their respective drawbacks. One drawback is that chlorine from any source reacts with natural organic compounds in the water to form potentially harmful chemical by-products. These by-products, trihalomethanes (THMs) and haloacetic acids (HAAs), are both carcinogenic in large quantities and are regulated by the United States Environmental Protection Agency (EPA) and the Drinking Water Inspectorate in the UK. The formation of THMs and haloacetic acids may be minimized by effective removal of as many organics from the water as possible prior to chlorine addition. Although chlorine is effective in killing bacteria, it has limited effectiveness against pathogenic protozoa that form cysts in water such as Giardia lamblia and Cryptosporidium.
Chlorine dioxide is a faster-acting disinfectant than elemental chlorine. It is relatively rarely used because in some circumstances it may create excessive amounts of chlorite, which is a by-product regulated to low allowable levels in the United States. Chlorine dioxide can be supplied as an aqueous solution and added to water to avoid gas handling problems; chlorine dioxide gas accumulations may spontaneously detonate.
The use of chloramine is becoming more common as a disinfectant. Although chloramine is not as strong an oxidant, it provides a longer-lasting residual than free chlorine because of its lower redox potential compared to free chlorine. It also does not readily form THMs or haloacetic acids (disinfection byproducts).
It is possible to convert chlorine to chloramine by adding ammonia to the water after adding chlorine. The chlorine and ammonia react to form chloramine. Water distribution systems disinfected with chloramines may experience nitrification, as ammonia is a nutrient for bacterial growth, with nitrates being generated as a by-product.
Ozone disinfection, or ozonation, Ozone is an unstable molecule which readily gives up one atom of oxygen providing a powerful oxidizing agent which is toxic to most waterborne organisms. It is a very strong, broad spectrum disinfectant that is widely used in Europe and in a few municipalities in the United States and Canada. It is an effective method to inactivate harmful protozoa that form cysts. It also works well against almost all other pathogens. Ozone is made by passing oxygen through ultraviolet light or a "cold" electrical discharge. To use ozone as a disinfectant, it must be created on-site and added to the water by bubble contact. Some of the advantages of ozone include the production of fewer dangerous by-products and the absence of taste and odour problems (in comparison to chlorination). No residual ozone is left in the water. In the absence of a residual disinfectant in the water, chlorine or chloramine may be added throughout a distribution system to remove any potential pathogens in the distribution piping.
Ozone has been used in drinking water plants since 1906 where the first industrial ozonation plant was built in Nice, France. The U.S. Food and Drug Administration has accepted ozone as being safe; and it is applied as an anti-microbiological agent for the treatment, storage, and processing of foods. However, although fewer by-products are formed by ozonation, it has been discovered that ozone reacts with bromide ions in water to produce concentrations of the suspected carcinogen bromate. Bromide can be found in fresh water supplies in sufficient concentrations to produce (after ozonation) more than 10 parts per billion (ppb) of bromate — the maximum contaminant level established by the USEPA. Ozone disinfection is also energy intensive.
Ultraviolet light (UV) is very effective at inactivating cysts, in low turbidity water. UV light's disinfection effectiveness decreases as turbidity increases, a result of the absorption, scattering, and shadowing caused by the suspended solids. The main disadvantage to the use of UV radiation is that, like ozone treatment, it leaves no residual disinfectant in the water; therefore, it is sometimes necessary to add a residual disinfectant after the primary disinfection process. This is often done through the addition of chloramines, discussed above as a primary disinfectant. When used in this manner, chloramines provide an effective residual disinfectant with very few of the negative effects of chlorination.
Over 2 million people in 28 developing countries use Solar Disinfection for daily drinking water treatment.
Like UV, ionizing radiation (X-rays, gamma rays, and electron beams) has been used to sterilize water.
Bromine and iodine can also be used as disinfectants. However, chlorine in water is over three times more effective as a disinfectant against Escherichia coli than an equivalent concentration of bromine, and over six times more effective than an equivalent concentration of iodine. Iodine is commonly used for portable water purification, and bromine is common as a swimming pool disinfectant.
Potable water purification devices and methods are available for disinfection and treatment in emergencies or in remote locations. Disinfection is the primary goal, since aesthetic considerations such as taste, odour, appearance, and trace chemical contamination do not affect the short-term safety of drinking water.
Other popular methods for purifying water, especially for local private supplies are listed below. In some countries some of these methods are also used for large scale municipal supplies. Particularly important are distillation (de-salination of seawater) and reverse osmosis.
Many municipalities have moved from free chlorine to chloramine as a disinfection agent. However, chloramine appears to be a corrosive agent in some water systems. Chloramine can dissolve the "protective" film inside older service lines, leading to the leaching of lead into residential spigots. This can result in harmful exposure, including elevated blood lead levels. Lead is a known neurotoxin.
Distillation removes all minerals from water, and the membrane methods of reverse osmosis and nanofiltration remove most to all minerals. This results in demineralized water which is not considered ideal drinking water. The World Health Organization has investigated the health effects of demineralized water since 1980. Experiments in humans found that demineralized water increased diuresis and the elimination of electrolytes, with decreased blood serum potassium concentration. Magnesium, calcium, and other minerals in water can help to protect against nutritional deficiency. Demineralized water may also increase the risk from toxic metals because it more readily leaches materials from piping like lead and cadmium, which is prevented by dissolved minerals such as calcium and magnesium. Low-mineral water has been implicated in specific cases of lead poisoning in infants, when lead from pipes leached at especially high rates into the water. Recommendations for magnesium have been put at a minimum of 10 mg/L with 20–30 mg/L optimum; for calcium a 20 mg/L minimum and a 40–80 mg/L optimum, and a total water hardness (adding magnesium and calcium) of 2 to 4 mmol/L. At water hardness above 5 mmol/L, higher incidence of gallstones, kidney stones, urinary stones, arthrosis, and arthropathies have been observed. Additionally, desalination processes can increase the risk of bacterial contamination.
The first experiments into water filtration were made in the 17th century. Sir Francis Bacon attempted to desalinate sea water by passing the flow through a sand filter. Although his experiment did not succeed, it marked the beginning of a new interest in the field. The fathers of microscopy, Antonie van Leeuwenhoek and Robert Hooke, used the newly invented microscope to observe for the first time small material particles that lay suspended in the water, laying the groundwork for the future understanding of waterborne pathogens.
The first documented use of sand filters to purify the water supply dates to 1804, when the owner of a bleachery in Paisley, Scotland, John Gibb, installed an experimental filter, selling his unwanted surplus to the public. This method was refined in the following two decades by engineers working for private water companies, and it culminated in the first treated public water supply in the world, installed by engineer James Simpson for the Chelsea Waterworks Company in London in 1829. This installation provided filtered water for every resident of the area, and the network design was widely copied throughout the United Kingdom in the ensuing decades.
The practice of water treatment soon became mainstream and common, and the virtues of the system were made starkly apparent after the investigations of the physician John Snow during the 1854 Broad Street cholera outbreak. Snow was sceptical of the then-dominant miasma theory that stated that diseases were caused by noxious "bad airs". Although the germ theory of disease had not yet been developed, Snow's observations led him to discount the prevailing theory. His 1855 essay On the Mode of Communication of Cholera conclusively demonstrated the role of the water supply in spreading the cholera epidemic in Soho, with the use of a dot distribution map and statistical proof to illustrate the connection between the quality of the water source and cholera cases. His data convinced the local council to disable the water pump, which promptly ended the outbreak.
The Metropolis Water Act introduced the regulation of the water supply companies in London, including minimum standards of water quality for the first time. The Act "made provision for securing the supply to the Metropolis of pure and wholesome water", and required that all water be "effectually filtered" from 31 December 1855. This was followed up with legislation for the mandatory inspection of water quality, including comprehensive chemical analyses, in 1858. This legislation set a worldwide precedent for similar state public health interventions across Europe. The Metropolitan Commission of Sewers was formed at the same time, water filtration was adopted throughout the country, and new water intakes on the Thames were established above Teddington Lock. Automatic pressure filters, where the water is forced under pressure through the filtration system, were innovated in 1899 in England.
John Snow was the first to successfully use chlorine to disinfect the water supply in Soho that had helped spread the cholera outbreak. William Soper also used chlorinated lime to treat the sewage produced by typhoid patients in 1879.
In a paper published in 1894, Moritz Traube formally proposed the addition of chloride of lime (calcium hypochlorite) to water to render it "germ-free." Two other investigators confirmed Traube's findings and published their papers in 1895. Early attempts at implementing water chlorination at a water treatment plant were made in 1893 in Hamburg, Germany and in 1897 the city of Maidstone England was the first to have its entire water supply treated with chlorine.
Permanent water chlorination began in 1905, when a faulty slow sand filter and a contaminated water supply led to a serious typhoid fever epidemic in Lincoln, England. Dr. Alexander Cruickshank Houston used chlorination of the water to stem the epidemic. His installation fed a concentrated solution of chloride of lime to the water being treated. The chlorination of the water supply helped stop the epidemic and as a precaution, the chlorination was continued until 1911 when a new water supply was instituted.
The first continuous use of chlorine in the United States for disinfection took place in 1908 at Boonton Reservoir (on the Rockaway River), which served as the supply for Jersey City, New Jersey. Chlorination was achieved by controlled additions of dilute solutions of chloride of lime (calcium hypochlorite) at doses of 0.2 to 0.35 ppm. The treatment process was conceived by Dr. John L. Leal and the chlorination plant was designed by George Warren Fuller. Over the next few years, chlorine disinfection using chloride of lime were rapidly installed in drinking water systems around the world.
The technique of purification of drinking water by use of compressed liquefied chlorine gas was developed by a British officer in the Indian Medical Service, Vincent B. Nesfield, in 1903. According to his own account:
It occurred to me that chlorine gas might be found satisfactory ... if suitable means could be found for using it.... The next important question was how to render the gas portable. This might be accomplished in two ways: By liquefying it, and storing it in lead-lined iron vessels, having a jet with a very fine capillary canal, and fitted with a tap or a screw cap. The tap is turned on, and the cylinder placed in the amount of water required. The chlorine bubbles out, and in ten to fifteen minutes the water is absolutely safe. This method would be of use on a large scale, as for service water carts.
U.S. Army Major Carl Rogers Darnall, Professor of Chemistry at the Army Medical School, gave the first practical demonstration of this in 1910. Shortly thereafter, Major William J. L. Lyster of the Army Medical Department used a solution of calcium hypochlorite in a linen bag to treat water. For many decades, Lyster's method remained the standard for U.S. ground forces in the field and in camps, implemented in the form of the familiar Lyster Bag (also spelled Lister Bag). This work became the basis for present day systems of municipal water purification.
Aluminum chlorohydrate is a group of specific aluminum salts having the general formula AlnCl(3n-m)(OH)m. It is used in cosmetics as an antiperspirant and as a coagulant in water purification.
In water purification, this compound is preferred in some cases because of its high charge, which makes it more effective at destabilizing and removing suspended materials than other aluminum salts such as aluminum sulfate, aluminum chloride and various forms of polyaluminum chloride and polyaluminum chlorisulfate, in which the aluminum structure results in a lower net charge than aluminum chlorohydrate. Further, the high degree of neutralization of the HCl results in minimal impact on treated water pH when compared to other aluminum and iron salts.Chicago Harbor
Generally, the Chicago Harbor comprises the public rivers, canals, and lakes within the territorial limits of the City of Chicago and all connecting slips, basins, piers, breakwaters, and permanent structures therein for a distance of three miles from the shore between the extended north and south lines of the city. The greater Chicago Harbor includes portions of the Chicago River, the Calumet River, the Ogden Canal, the Chicago Sanitary and Ship Canal, Lake Calumet, and Lake Michigan.In a more narrow sense, the Chicago Harbor is that artificial harbor on Lake Michigan located at the mouth of the Chicago River bounded by outer breakwaters to the north and east, Northerly Island to the south, and the Chicago shoreline to the west. The main entrance to this harbor is marked by the Chicago Harbor Lighthouse. The Jardine Water Purification Plant, Navy Pier, the Chicago Harbor Lock, Coast Guard Station Chicago, the municipal harbors - Dusable Harbor and Monroe Harbor, and the yacht clubs - Chicago Yacht Club and Columbia Yacht Club are all located here.The Port of Chicago is located within the greater Chicago Harbor in and around Calumet Harbor, the Calumet River, and Lake Calumet.
The Chicago Park District operates a municipal harbor system within the greater Chicago Harbor in Lake Michigan for recreational boaters. With accommodations for 6000 boats, it is the largest system of its kind in the nation. The system comprises (from north to south) Montrose Harbor, Belmont Harbor, Diversey Harbor, Dusable Harbor, Monroe Harbor, Burnham Harbor, 31st Street Harbor, 59th Street Harbor, and Jackson Park Inner and Outer Harbors.Environmental technology
Environmental technology (envirotech), green technology (greentech) or clean technology (cleantech) is the application of one or more of environmental science, green chemistry, environmental monitoring and electronic devices to monitor, model and conserve the natural environment and resources, and to curb the negative impacts of human involvement. The term is also used to describe sustainable energy generation technologies such as photovoltaics, wind turbines, bioreactors, etc. Sustainable development is the core of environmental technologies. The term environmental technologies is also used to describe a class of electronic devices that can promote sustainable management of resources.Epidemic Prevention and Water Purification Department
The Epidemic Prevention and Water Purification Department was a department of the Imperial Japanese Army from 1936 to the dissolution of the Army in 1945. While its public mission was to prevent the spread of disease and monitor water supply, several field armies also assigned units the mission of manufacturing biological weapons. Many units also performed human experimentation.Freshwater biology
Freshwater biology is the scientific biological study of freshwater ecosystems and is a branch of limnology. This field seeks to understand the relationships between living organisms in their physical environment. These physical environments may include rivers, lakes, streams, or wetlands. This discipline is also widely used in industrial processes to make use of biological processes such as sewage treatment and water purification. Water flow is an essential aspect to species distribution and influence when and where species interact in freshwater environments.In the UK the Freshwater Biological Association based near Windermere in Cumbria was one of the early institutions to research te biology of freshwater and promote the concepts of trophism in lakes and demonstrated the process of migration from oligotrophic water through mesotrophic to marsh.
Freshwater biology is also used to study the effects of climate change and increased human impact on both aquatic systems and wider ecosystems.Hydrobiology
Hydrobiology is the science of life and life processes in water. Much of modern hydrobiology can be viewed as a sub-discipline of ecology but the sphere of hydrobiology includes taxonomy, economic biology, industrial biology, morphology, physiology etc. The one distinguishing aspect is that all relate to aquatic organisms. Much work is closely related to limnology and can be divided into lotic system ecology (flowing waters) and lentic system ecology (still waters).
One of the significant areas of current research is eutrophication. Special attention is paid to biotic interactions in plankton assemblage including the microbial loop, the mechanism of influencing water blooms, phosphorus load and lake turnover. Another subject of research is the acidification of mountain lakes. Long-term studies are carried out on changes in the ionic composition of the water of rivers, lakes and reservoirs in connection with acid rain and fertilisation. One goal of current research is elucidation of the basic environmental functions of the ecosystem in reservoirs, which are important for water quality management and water supply.
Much of the early work of hydrobiologists concentrated on the biological processes utilised in sewage treatment and water purification especially slow sand filters. Other historically important work sought to provide biotic indices for classifying waters according to the biotic communities that they supported. This work continues to this day in Europe in the development of classification tools for assessing water bodies for the EU water framework directive.Ion-exchange resin
An ion-exchange resin or ion-exchange polymer is a resin or polymer that acts as a medium for ion exchange. It is an insoluble matrix (or support structure) normally in the form of small (0.25–0.5 mm radius) microbeads, usually white or yellowish, fabricated from an organic polymer substrate. The beads are typically porous, providing a large surface area on and inside them. The trapping of ions occurs along with the accompanying release of other ions, and thus the process is called ion exchange. There are multiple types of ion-exchange resin. Most commercial resins are made of polystyrene sulfonate.
Ion-exchange resins are widely used in different separation, purification, and decontamination processes. The most common examples are water softening and water purification. In many cases ion-exchange resins were introduced in such processes as a more flexible alternative to the use of natural or artificial zeolites. Also, ion-exchange resins are highly effective in the biodiesel filtration process.Jardine Water Purification Plant
The Jardine Water Purification Plant, formerly the Central District Filtration Plant, is the largest capacity water filtration plant in the world, located at 1000 East Ohio Street, north of Navy Pier in Chicago, Illinois. It draws raw water from two of the city's water cribs far offshore in Lake Michigan and supplies 2/3 of water per day to consumers in the Chicagoland Area, the Sawyer Water Purification Plant Supplies the other 1/3. Constructed in the 1960s, it began functioning in 1968. The plant was renamed after James W. Jardine, a 42-year city employee, who served as water commissioner from 1953 until his retirement in 1973. Shortly thereafter the Ohio Street Beach was formed in the bay created by the plant. Landscaping around the plant and in the adjoining Milton Olive Park was designed by Dan Kiley, and a statue, Hymn to Water, by Milton Horn graces the front entrance.
The southern portion of the city is served by a separate plant, the Sawyer Water Purification Plant. Together the two plants supply water to about 3 million residents in the city and 118 suburbs.Moringa oleifera
Moringa oleifera is the most widely cultivated species in the genus Moringa, the only genus in the plant family Moringaceae. Common names include moringa, drumstick tree (from the long, slender, triangular seed-pods), horseradish tree (from the taste of the roots, which resembles horseradish), and ben oil tree or benzoil tree (from the oil which is derived from the seeds).
M. oleifera is a fast-growing, drought-resistant tree, native to tropical and subtropical regions of South Asia. It is widely cultivated for its young seed pods and leaves used as vegetables and for traditional herbal medicine. It is also used for water purification. M. oleifera is considered to be an aggressive invasive species.Organic matter
Organic matter, organic material, or natural organic matter (NOM) refers to the large pool of carbon-based compounds found within natural and engineered, terrestrial and aquatic environments. It is matter composed of organic compounds that have come from the remains of organisms such as plants and animals and their waste products in the environment. Organic molecules can also be made by chemical reactions that don't involve life. Basic structures are created from cellulose, tannin, cutin, and lignin, along with other various proteins, lipids, and carbohydrates. Organic matter is very important in the movement of nutrients in the environment and plays a role in water retention on the surface of the planet.Organisms involved in water purification
Most organisms involved in water purification originate from the waste, wastewater or water stream itself or arrive as resting spore of some form from the atmosphere. In a very few cases, mostly associated with constructed wetlands, specific organisms are planted to maximise the efficiency of the process.Portable water purification
Portable water purification devices are self-contained, easily transported units used to purify water from untreated sources (such as rivers, lakes, and wells) for drinking purposes. Their main function is to eliminate pathogens, and often also of suspended solids and some unpalatable or toxic compounds.
These units provide an autonomous supply of drinking water to people without access to clean water supply services, including inhabitants of developing countries and disaster areas, military personnel, campers, hikers, and workers in wilderness, and survivalists. They are also called point-of-use (POU) water treatment systems and field water disinfection techniques.
Techniques include heat (including boiling), filtration, activated charcoal adsorption, chemical disinfection (e.g. chlorination, iodine, ozonation, etc.), ultraviolet purification (including sodis), distillation (including solar distillation), and flocculation. Often these are used in combination.Purification
Purification is the process of rendering something pure, i.e. clean of foreign elements and/or pollution, and may refer to:
List of purification methods in chemistry
Organisms used in water purification
Purification of quantum state in quantum mechanics, especially quantum information
Purification theorem in game theory and economics, a Nash equilibrium consisting of randomly mixed strategies
Ritual purification, the religious activity to remove uncleanliness
Purification of the Virgin, a Christian liturgical feast
Purification Rundown in Scientology, a procedure that supposedly rids the body of toxins
Purification (album), a 2002 Crimson Thorn album
Purification (film), a 2012 film
Sweat lodgeReverse osmosis
Reverse osmosis (RO) is a water purification process that uses a partially permeable membrane to remove ions, unwanted molecules and larger particles from drinking water. In reverse osmosis, an applied pressure is used to overcome osmotic pressure, a colligative property, that is driven by chemical potential differences of the solvent, a thermodynamic parameter. Reverse osmosis can remove many types of dissolved and suspended chemical species as well as biological ones (principally bacteria) from water, and is used in both industrial processes and the production of potable water. The result is that the solute is retained on the pressurized side of the membrane and the pure solvent is allowed to pass to the other side. To be "selective", this membrane should not allow large molecules or ions through the pores (holes), but should allow smaller components of the solution (such as solvent molecules, i.e., water, H2O) to pass freely.In the normal osmosis process, the solvent naturally moves from an area of low solute concentration (high water potential), through a membrane, to an area of high solute concentration (low water potential). The driving force for the movement of the solvent is the reduction in the free energy of the system when the difference in solvent concentration on either side of a membrane is reduced, generating osmotic pressure due to the solvent moving into the more concentrated solution. Applying an external pressure to reverse the natural flow of pure solvent, thus, is reverse osmosis. The process is similar to other membrane technology applications.
Reverse osmosis differs from filtration in that the mechanism of fluid flow is by osmosis across a membrane. The predominant removal mechanism in membrane filtration is straining, or size exclusion, where the pores are 0.01 micrometers or larger, so the process can theoretically achieve perfect efficiency regardless of parameters such as the solution's pressure and concentration. Reverse osmosis instead involves solvent diffusion across a membrane that is either nonporous or uses nanofiltration with pores 0.001 micrometers in size. The predominant removal mechanism is from differences in solubility or diffusivity, and the process is dependent on pressure, solute concentration, and other conditions. Reverse osmosis is most commonly known for its use in drinking water purification from seawater, removing the salt and other effluent materials from the water molecules.Seoul City Route 92
Seoul Metropolitan City Route 92 (Korean: 서울특별시도 제92호선) is an urban road located in Gyeonggi Province and Seoul, South Korea. With a total length of 44.6 km (27.7 mi), this road starts from the Haengju Bridge in Gangseo District, Seoul to Amsa Water Purification Facilities in Gangdong District. Nambu Beltway is a part of this route.Unit Ei 1644
Unit Ei 1644 (Japanese: 栄1644部隊) — also known as Unit 1644 — was a laboratory and one of the water purification centers established under control of the Epidemic Prevention and Water Purification Department. It was established in 1939 in Japanese-occupied Nanking as a satellite unit of Unit 731.
An anonymous researcher, who claims he was attached to Unit 1644, says that it regularly carried out human vivisections as well as infecting humans with cholera, typhus, and bubonic plague. The researcher and his family had not yet reached an agreement about releasing his name.Water pumping
The pumping of water is a basic and practical technique, far more practical than scooping it up with one's hands or lifting it in a hand-held bucket. This is true whether the water is drawn from a fresh source, moved to a needed location, purified, or used for irrigation, washing, or sewage treatment, or for evacuating water from an undesirable location. Regardless of the outcome, the energy required to pump water is an extremely demanding component of water consumption. All other processes depend or benefit either from water descending from a higher elevation or some pressurized plumbing system.
The ancient concept of the aqueduct took simple and eloquent advantage of maintaining elevation of water for as long and far a distance as possible. Thus, as water moves over great distances, it retains a larger component of its potential energy by spending small portions of this energy flowing down a slight gradation. A useful aqueduct system ultimately depends on a fresh water source existing at a higher elevation than the location where the water can be of use. Gravity does all the work. In all other instances, pumps are necessary.
In day-to-day situations, available water is often contaminated, unhealthy, or even naturally poisonous, so that it is necessary to pump potable water from lower levels to higher levels, where it can be of use. A fresh water source in a lower stream, river, pond, or lake is often pumped to higher ground for irrigation, livestock, cooking, cleaning or other uses by humans, who quite naturally need fresh water. This will purify mostly fresh water, and the treatment of largely contaminated water refer endlessly to pumping.Water supply network
A water supply system or water supply network is a system of engineered hydrologic and hydraulic components which provide water supply. A water supply system typically includes:
A drainage basin (see water purification - sources of drinking water).
A raw water collection point (above or below ground) where the water accumulates, such as a lake, a river, or groundwater from an underground aquifer. Raw water may be transferred using uncovered ground-level aqueducts, covered tunnels or underground water pipes to water purification facilities.
Water purification facilities. Treated water is transferred using water pipes (usually underground).
Water storage facilities such as reservoirs, water tanks, or water towers. Smaller water systems may store the water in cisterns or pressure vessels. Tall buildings may also need to store water locally in pressure vessels in order for the water to reach the upper floors.
Additional water pressurizing components such as pumping stations may need to be situated at the outlet of underground or above ground reservoirs or cisterns (if gravity flow is impractical).
A pipe network for distribution of water to the consumers (which may be private houses or industrial, commercial or institution establishments) and other usage points (such as fire hydrants).
Connections to the sewers (underground pipes, or aboveground ditches in some developing countries) are generally found downstream of the water consumers, but the sewer system is considered to be a separate system, rather than part of the water supply system.Water supply networks are often run by public utilities of the water industry.Water treatment
Water treatment is any process that improves the quality of water to make it more acceptable for a specific end-use. The end use may be drinking, industrial water supply, irrigation, river flow maintenance, water recreation or many other uses, including being safely returned to the environment. Water treatment removes contaminants and undesirable components, or reduces their concentration so that the water becomes fit for its desired end-use. This treatment is crucial to human health and allows humans to benefit from both drinking and irrigation use.