A solar cell, or photovoltaic cell, is an electrical device that converts the energy of light directly into electricity by the photovoltaic effect, which is a physical and chemical phenomenon. It is a form of photoelectric cell, defined as a device whose electrical characteristics, such as current, voltage, or resistance, vary when exposed to light. Individual solar cell devices can be combined to form modules, otherwise known as solar panels. In basic terms a single junction silicon solar cell can produce a maximum open-circuit voltage of approximately 0.5 to 0.6 volts.
Solar cells are described as being photovoltaic, irrespective of whether the source is sunlight or an artificial light. They are used as a photodetector (for example infrared detectors), detecting light or other electromagnetic radiation near the visible range, or measuring light intensity.
The operation of a photovoltaic (PV) cell requires three basic attributes:
In contrast, a solar thermal collector supplies heat by absorbing sunlight, for the purpose of either direct heating or indirect electrical power generation from heat. A "photoelectrolytic cell" (photoelectrochemical cell), on the other hand, refers either to a type of photovoltaic cell (like that developed by Edmond Becquerel and modern dye-sensitized solar cells), or to a device that splits water directly into hydrogen and oxygen using only solar illumination.
Assemblies of solar cells are used to make solar modules that generate electrical power from sunlight, as distinguished from a "solar thermal module" or "solar hot water panel". A solar array generates solar power using solar energy.
Multiple solar cells in an integrated group, all oriented in one plane, constitute a solar photovoltaic panel or module. Photovoltaic modules often have a sheet of glass on the sun-facing side, allowing light to pass while protecting the semiconductor wafers. Solar cells are usually connected in series and parallel circuits or series in modules, creating an additive voltage. Connecting cells in parallel yields a higher current; however, problems such as shadow effects can shut down the weaker (less illuminated) parallel string (a number of series connected cells) causing substantial power loss and possible damage because of the reverse bias applied to the shadowed cells by their illuminated partners. Strings of series cells are usually handled independently and not connected in parallel, though as of 2014, individual power boxes are often supplied for each module, and are connected in parallel. Although modules can be interconnected to create an array with the desired peak DC voltage and loading current capacity, using independent MPPTs (maximum power point trackers) is preferable. Otherwise, shunt diodes can reduce shadowing power loss in arrays with series/parallel connected cells.
|USD/W||Australia||China||France||Germany||Italy||Japan||United Kingdom||United States|
|Source: IEA – Technology Roadmap: Solar Photovoltaic Energy report, 2014 edition:15|
Note: DOE – Photovoltaic System Pricing Trends reports lower prices for the U.S.
The photovoltaic effect was experimentally demonstrated first by French physicist Edmond Becquerel. In 1839, at age 19, he built the world's first photovoltaic cell in his father's laboratory. Willoughby Smith first described the "Effect of Light on Selenium during the passage of an Electric Current" in a 20 February 1873 issue of Nature. In 1883 Charles Fritts built the first solid state photovoltaic cell by coating the semiconductor selenium with a thin layer of gold to form the junctions; the device was only around 1% efficient. Other milestones include:
Solar cells were first used in a prominent application when they were proposed and flown on the Vanguard satellite in 1958, as an alternative power source to the primary battery power source. By adding cells to the outside of the body, the mission time could be extended with no major changes to the spacecraft or its power systems. In 1959 the United States launched Explorer 6, featuring large wing-shaped solar arrays, which became a common feature in satellites. These arrays consisted of 9600 Hoffman solar cells.
By the 1960s, solar cells were (and still are) the main power source for most Earth orbiting satellites and a number of probes into the solar system, since they offered the best power-to-weight ratio. However, this success was possible because in the space application, power system costs could be high, because space users had few other power options, and were willing to pay for the best possible cells. The space power market drove the development of higher efficiencies in solar cells up until the National Science Foundation "Research Applied to National Needs" program began to push development of solar cells for terrestrial applications.
In the early 1990s the technology used for space solar cells diverged from the silicon technology used for terrestrial panels, with the spacecraft application shifting to gallium arsenide-based III-V semiconductor materials, which then evolved into the modern III-V multijunction photovoltaic cell used on spacecraft.
Improvements were gradual over the 1960s. This was also the reason that costs remained high, because space users were willing to pay for the best possible cells, leaving no reason to invest in lower-cost, less-efficient solutions. The price was determined largely by the semiconductor industry; their move to integrated circuits in the 1960s led to the availability of larger boules at lower relative prices. As their price fell, the price of the resulting cells did as well. These effects lowered 1971 cell costs to some $100 per watt.
In late 1969 Elliot Berman joined Exxon's task force which was looking for projects 30 years in the future and in April 1973 he founded Solar Power Corporation, a wholly owned subsidiary of Exxon at that time. The group had concluded that electrical power would be much more expensive by 2000, and felt that this increase in price would make alternative energy sources more attractive. He conducted a market study and concluded that a price per watt of about $20/watt would create significant demand. The team eliminated the steps of polishing the wafers and coating them with an anti-reflective layer, relying on the rough-sawn wafer surface. The team also replaced the expensive materials and hand wiring used in space applications with a printed circuit board on the back, acrylic plastic on the front, and silicone glue between the two, "potting" the cells. Solar cells could be made using cast-off material from the electronics market. By 1973 they announced a product, and SPC convinced Tideland Signal to use its panels to power navigational buoys, initially for the U.S. Coast Guard.
Research into solar power for terrestrial applications became prominent with the U.S. National Science Foundation's Advanced Solar Energy Research and Development Division within the "Research Applied to National Needs" program, which ran from 1969 to 1977, and funded research on developing solar power for ground electrical power systems. A 1973 conference, the "Cherry Hill Conference", set forth the technology goals required to achieve this goal and outlined an ambitious project for achieving them, kicking off an applied research program that would be ongoing for several decades. The program was eventually taken over by the Energy Research and Development Administration (ERDA), which was later merged into the U.S. Department of Energy.
Following the 1973 oil crisis, oil companies used their higher profits to start (or buy) solar firms, and were for decades the largest producers. Exxon, ARCO, Shell, Amoco (later purchased by BP) and Mobil all had major solar divisions during the 1970s and 1980s. Technology companies also participated, including General Electric, Motorola, IBM, Tyco and RCA.
Adjusting for inflation, it cost $96 per watt for a solar module in the mid-1970s. Process improvements and a very large boost in production have brought that figure down 99%, to 68¢ per watt in 2016, according to data from Bloomberg New Energy Finance. Swanson's law is an observation similar to Moore's Law that states that solar cell prices fall 20% for every doubling of industry capacity. It was featured in an article in the British weekly newspaper The Economist in late 2012.
Further improvements reduced production cost to under $1 per watt, with wholesale costs well under $2. Balance of system costs were then higher than those of the panels. Large commercial arrays could be built, as of 2010, at below $3.40 a watt, fully commissioned.
As the semiconductor industry moved to ever-larger boules, older equipment became inexpensive. Cell sizes grew as equipment became available on the surplus market; ARCO Solar's original panels used cells 2 to 4 inches (50 to 100 mm) in diameter. Panels in the 1990s and early 2000s generally used 125 mm wafers; since 2008, almost all new panels use 156 mm cells. The widespread introduction of flat screen televisions in the late 1990s and early 2000s led to the wide availability of large, high-quality glass sheets to cover the panels.
During the 1990s, polysilicon ("poly") cells became increasingly popular. These cells offer less efficiency than their monosilicon ("mono") counterparts, but they are grown in large vats that reduce cost. By the mid-2000s, poly was dominant in the low-cost panel market, but more recently the mono returned to widespread use.
Manufacturers of wafer-based cells responded to high silicon prices in 2004–2008 with rapid reductions in silicon consumption. In 2008, according to Jef Poortmans, director of IMEC's organic and solar department, current cells use 8–9 grams (0.28–0.32 oz) of silicon per watt of power generation, with wafer thicknesses in the neighborhood of 200 microns. Crystalline silicon panels dominate worldwide markets and are mostly manufactured in China and Taiwan. By late 2011, a drop in European demand dropped prices for crystalline solar modules to about $1.09 per watt down sharply from 2010. Prices continued to fall in 2012, reaching $0.62/watt by 4Q2012.
Solar PV is growing fastest in Asia, with China and Japan currently accounting for half of worldwide deployment. Global installed PV capacity reached at least 301 gigawatts in 2016, and grew to supply 1.3% of global power by 2016.
In fact, the harnessed energy of silicon solar cells at the cost of a dollar has surpassed its oil counterpart since 2004. It was anticipated that electricity from PV will be competitive with wholesale electricity costs all across Europe and the energy payback time of crystalline silicon modules can be reduced to below 0.5 years by 2020.
Solar-specific feed-in tariffs vary by country and within countries. Such tariffs encourage the development of solar power projects. Widespread grid parity, the point at which photovoltaic electricity is equal to or cheaper than grid power without subsidies, likely requires advances on all three fronts. Proponents of solar hope to achieve grid parity first in areas with abundant sun and high electricity costs such as in California and Japan. In 2007 BP claimed grid parity for Hawaii and other islands that otherwise use diesel fuel to produce electricity. George W. Bush set 2015 as the date for grid parity in the US. The Photovoltaic Association reported in 2012 that Australia had reached grid parity (ignoring feed in tariffs).
The price of solar panels fell steadily for 40 years, interrupted in 2004 when high subsidies in Germany drastically increased demand there and greatly increased the price of purified silicon (which is used in computer chips as well as solar panels). The recession of 2008 and the onset of Chinese manufacturing caused prices to resume their decline. In the four years after January 2008 prices for solar modules in Germany dropped from €3 to €1 per peak watt. During that same time production capacity surged with an annual growth of more than 50%. China increased market share from 8% in 2008 to over 55% in the last quarter of 2010. In December 2012 the price of Chinese solar panels had dropped to $0.60/Wp (crystalline modules). (The abbreviation Wp stands for watt peak capacity, or the maximum capacity under optimal conditions.)
As of the end of 2016, it was reported that spot prices for assembled solar panels (not cells) had fallen to a record-low of US$0.36/Wp. The second largest supplier, Canadian Solar Inc., had reported costs of US$0.37/Wp in the third quarter of 2016, having dropped $0.02 from the previous quarter, and hence was probably still at least breaking even. Many producers expected costs would drop to the vicinity of $0.30 by the end of 2017. It was also reported that new solar installations were cheaper than coal-based thermal power plants in some regions of the world, and this was expected to be the case in most of the world within a decade.
The solar cell works in several steps:
The most commonly known solar cell is configured as a large-area p–n junction made from silicon. Other possible solar cell types are organic solar cells, dye sensitized solar cells, perovskite solar cells, quantum dot solar cells etc. The illuminated side of a solar cell generally has a transparent conducting film for allowing light to enter into active material and to collect the generated charge carriers. Typically, films with high transmittance and high electrical conductance such as indium tin oxide, conducting polymers or conducting nanowire networks are used for the purpose.
Solar cell efficiency may be broken down into reflectance efficiency, thermodynamic efficiency, charge carrier separation efficiency and conductive efficiency. The overall efficiency is the product of these individual metrics.
A solar cell has a voltage dependent efficiency curve, temperature coefficients, and allowable shadow angles.
Due to the difficulty in measuring these parameters directly, other parameters are substituted: thermodynamic efficiency, quantum efficiency, integrated quantum efficiency, VOC ratio, and fill factor. Reflectance losses are a portion of quantum efficiency under "external quantum efficiency". Recombination losses make up another portion of quantum efficiency, VOC ratio, and fill factor. Resistive losses are predominantly categorized under fill factor, but also make up minor portions of quantum efficiency, VOC ratio.
The fill factor is the ratio of the actual maximum obtainable power to the product of the open circuit voltage and short circuit current. This is a key parameter in evaluating performance. In 2009, typical commercial solar cells had a fill factor > 0.70. Grade B cells were usually between 0.4 and 0.7. Cells with a high fill factor have a low equivalent series resistance and a high equivalent shunt resistance, so less of the current produced by the cell is dissipated in internal losses.
Single p–n junction crystalline silicon devices are now approaching the theoretical limiting power efficiency of 33.16%, noted as the Shockley–Queisser limit in 1961. In the extreme, with an infinite number of layers, the corresponding limit is 86% using concentrated sunlight.
In 2014, three companies broke the record of 25.6% for a silicon solar cell. Panasonic's was the most efficient. The company moved the front contacts to the rear of the panel, eliminating shaded areas. In addition they applied thin silicon films to the (high quality silicon) wafer's front and back to eliminate defects at or near the wafer surface.
In 2015, a 4-junction GaInP/GaAs//GaInAsP/GaInAs solar cell achieved a new laboratory record efficiency of 46.1 percent (concentration ratio of sunlight = 312) in a French-German collaboration between the Fraunhofer Institute for Solar Energy Systems (Fraunhofer ISE), CEA-LETI and SOITEC.
In September 2015, Fraunhofer ISE announced the achievement of an efficiency above 20% for epitaxial wafer cells. The work on optimizing the atmospheric-pressure chemical vapor deposition (APCVD) in-line production chain was done in collaboration with NexWafe GmbH, a company spun off from Fraunhofer ISE to commercialize production.
For triple-junction thin-film solar cells, the world record is 13.6%, set in June 2015.
In 2017, a team of researchers at National Renewable Energy Laboratory (NREL), EPFL and CSEM (Switzerland) reported record one-sun efficiencies of 32.8% for dual-junction GaInP/GaAs solar cell devices. In addition, the dual-junction device was mechanically stacked with a Si solar cell, to achieve a record one-sun efficiency of 35.9% for triple-junction solar cells.
Solar cells are typically named after the semiconducting material they are made of. These materials must have certain characteristics in order to absorb sunlight. Some cells are designed to handle sunlight that reaches the Earth's surface, while others are optimized for use in space. Solar cells can be made of only one single layer of light-absorbing material (single-junction) or use multiple physical configurations (multi-junctions) to take advantage of various absorption and charge separation mechanisms.
Solar cells can be classified into first, second and third generation cells. The first generation cells—also called conventional, traditional or wafer-based cells—are made of crystalline silicon, the commercially predominant PV technology, that includes materials such as polysilicon and monocrystalline silicon. Second generation cells are thin film solar cells, that include amorphous silicon, CdTe and CIGS cells and are commercially significant in utility-scale photovoltaic power stations, building integrated photovoltaics or in small stand-alone power system. The third generation of solar cells includes a number of thin-film technologies often described as emerging photovoltaics—most of them have not yet been commercially applied and are still in the research or development phase. Many use organic materials, often organometallic compounds as well as inorganic substances. Despite the fact that their efficiencies had been low and the stability of the absorber material was often too short for commercial applications, there is a lot of research invested into these technologies as they promise to achieve the goal of producing low-cost, high-efficiency solar cells.
By far, the most prevalent bulk material for solar cells is crystalline silicon (c-Si), also known as "solar grade silicon". Bulk silicon is separated into multiple categories according to crystallinity and crystal size in the resulting ingot, ribbon or wafer. These cells are entirely based around the concept of a p-n junction. Solar cells made of c-Si are made from wafers between 160 and 240 micrometers thick.
Monocrystalline silicon (mono-Si) solar cells are more efficient and more expensive than most other types of cells. The corners of the cells look clipped, like an octagon, because the wafer material is cut from cylindrical ingots, that are typically grown by the Czochralski process. Solar panels using mono-Si cells display a distinctive pattern of small white diamonds.
Epitaxial wafers of crystalline silicon can be grown on a monocrystalline silicon "seed" wafer by chemical vapor deposition (CVD), and then detached as self-supporting wafers of some standard thickness (e.g., 250 µm) that can be manipulated by hand, and directly substituted for wafer cells cut from monocrystalline silicon ingots. Solar cells made with this "kerfless" technique can have efficiencies approaching those of wafer-cut cells, but at appreciably lower cost if the CVD can be done at atmospheric pressure in a high-throughput inline process. The surface of epitaxial wafers may be textured to enhance light absorption.
Polycrystalline silicon, or multicrystalline silicon (multi-Si) cells are made from cast square ingots—large blocks of molten silicon carefully cooled and solidified. They consist of small crystals giving the material its typical metal flake effect. Polysilicon cells are the most common type used in photovoltaics and are less expensive, but also less efficient, than those made from monocrystalline silicon.
Ribbon silicon is a type of polycrystalline silicon—it is formed by drawing flat thin films from molten silicon and results in a polycrystalline structure. These cells are cheaper to make than multi-Si, due to a great reduction in silicon waste, as this approach does not require sawing from ingots. However, they are also less efficient.
This form was developed in the 2000s and introduced commercially around 2009. Also called cast-mono, this design uses polycrystalline casting chambers with small "seeds" of mono material. The result is a bulk mono-like material that is polycrystalline around the outsides. When sliced for processing, the inner sections are high-efficiency mono-like cells (but square instead of "clipped"), while the outer edges are sold as conventional poly. This production method results in mono-like cells at poly-like prices.
Thin-film technologies reduce the amount of active material in a cell. Most designs sandwich active material between two panes of glass. Since silicon solar panels only use one pane of glass, thin film panels are approximately twice as heavy as crystalline silicon panels, although they have a smaller ecological impact (determined from life cycle analysis). 
Cadmium telluride is the only thin film material so far to rival crystalline silicon in cost/watt. However cadmium is highly toxic and tellurium (anion: "telluride") supplies are limited. The cadmium present in the cells would be toxic if released. However, release is impossible during normal operation of the cells and is unlikely during fires in residential roofs. A square meter of CdTe contains approximately the same amount of Cd as a single C cell nickel-cadmium battery, in a more stable and less soluble form.
Copper indium gallium selenide (CIGS) is a direct band gap material. It has the highest efficiency (~20%) among all commercially significant thin film materials (see CIGS solar cell). Traditional methods of fabrication involve vacuum processes including co-evaporation and sputtering. Recent developments at IBM and Nanosolar attempt to lower the cost by using non-vacuum solution processes.
Silicon thin-film cells are mainly deposited by chemical vapor deposition (typically plasma-enhanced, PE-CVD) from silane gas and hydrogen gas. Depending on the deposition parameters, this can yield amorphous silicon (a-Si or a-Si:H), protocrystalline silicon or nanocrystalline silicon (nc-Si or nc-Si:H), also called microcrystalline silicon.
Amorphous silicon is the most well-developed thin film technology to-date. An amorphous silicon (a-Si) solar cell is made of non-crystalline or microcrystalline silicon. Amorphous silicon has a higher bandgap (1.7 eV) than crystalline silicon (c-Si) (1.1 eV), which means it absorbs the visible part of the solar spectrum more strongly than the higher power density infrared portion of the spectrum. The production of a-Si thin film solar cells uses glass as a substrate and deposits a very thin layer of silicon by plasma-enhanced chemical vapor deposition (PECVD).
Protocrystalline silicon with a low volume fraction of nanocrystalline silicon is optimal for high open circuit voltage. Nc-Si has about the same bandgap as c-Si and nc-Si and a-Si can advantageously be combined in thin layers, creating a layered cell called a tandem cell. The top cell in a-Si absorbs the visible light and leaves the infrared part of the spectrum for the bottom cell in nc-Si.
The semiconductor material Gallium arsenide (GaAs) is also used for single-crystalline thin film solar cells. Although GaAs cells are very expensive, they hold the world's record in efficiency for a single-junction solar cell at 28.8%. GaAs is more commonly used in multijunction photovoltaic cells for concentrated photovoltaics (CPV, HCPV) and for solar panels on spacecrafts, as the industry favours efficiency over cost for space-based solar power. Based on the previous literature and some theoretical analysis, there are several reasons why GaAs has such high power conversion efficiency. First, GaAs bandgap is 1.43ev which is almost ideal for solar cells. Second, because Gallium is a by-product of the smelting of other metals, GaAs cells are relatively insensitive to heat and it can keep high efficiency when temperature is quite high. Third, GaAs has the wide range of design options. Using GaAs as active layer in solar cell, engineers can have multiple choices of other layers which can better generate electrons and holes in GaAs.
Multi-junction cells consist of multiple thin films, each essentially a solar cell grown on top of another, typically using metalorganic vapour phase epitaxy. Each layer has a different band gap energy to allow it to absorb electromagnetic radiation over a different portion of the spectrum. Multi-junction cells were originally developed for special applications such as satellites and space exploration, but are now used increasingly in terrestrial concentrator photovoltaics (CPV), an emerging technology that uses lenses and curved mirrors to concentrate sunlight onto small, highly efficient multi-junction solar cells. By concentrating sunlight up to a thousand times, High concentrated photovoltaics (HCPV) has the potential to outcompete conventional solar PV in the future.:21,26
Tandem solar cells based on monolithic, series connected, gallium indium phosphide (GaInP), gallium arsenide (GaAs), and germanium (Ge) p–n junctions, are increasing sales, despite cost pressures. Between December 2006 and December 2007, the cost of 4N gallium metal rose from about $350 per kg to $680 per kg. Additionally, germanium metal prices have risen substantially to $1000–1200 per kg this year. Those materials include gallium (4N, 6N and 7N Ga), arsenic (4N, 6N and 7N) and germanium, pyrolitic boron nitride (pBN) crucibles for growing crystals, and boron oxide, these products are critical to the entire substrate manufacturing industry.
A triple-junction cell, for example, may consist of the semiconductors: GaAs, Ge, and GaInP
2. Triple-junction GaAs solar cells were used as the power source of the Dutch four-time World Solar Challenge winners Nuna in 2003, 2005 and 2007 and by the Dutch solar cars Solutra (2005), Twente One (2007) and 21Revolution (2009). GaAs based multi-junction devices are the most efficient solar cells to date. On 15 October 2012, triple junction metamorphic cells reached a record high of 44%.
In 2016, a new approach was described for producing hybrid photovoltaic wafers combining the high efficiency of III-V multi-junction solar cells with the economies and wealth of experience associated with silicon. The technical complications involved in growing the III-V material on silicon at the required high temperatures, a subject of study for some 30 years, are avoided by epitaxial growth of silicon on GaAs at low temperature by plasma-enhanced chemical vapor deposition (PECVD).
Si single-junction solar cells have been widely studied for decades and are reaching their practical efficiency of ~26% under 1-sun conditions. Increasing this efficiency may require adding more cells with bandgap energy larger than 1.1 eV to the Si cell, allowing to convert short-wavelength photons for generation of additional voltage. A dual-junction solar cell with a band gap of 1.6–1.8 eV as a top cell can reduce thermalization loss, produce a high external radiative efficiency and achieve theoretical efficiencies over 45%. A tandem cell can be fabricated by growing the GaInP and Si cells. Growing them separately can overcome the 4% lattice constant mismatch between Si and the most common III–V layers that prevent direct integration into one cell. The two cells therefore are separated by a transparent glass slide so the lattice mismatch does not cause strain to the system. This creates a cell with four electrical contacts and two junctions that demonstrated an efficiency of 18.1%. With a ﬁll factor (FF) of 76.2%, the Si bottom cell reaches an efﬁciency of 11.7% (± 0.4) in the tandem device, resulting in a cumulative tandem cell efﬁciency of 29.8%. This efﬁciency exceeds the theoretical limit of 29.4% and the record experimental efﬁciency value of a Si 1-sun solar cell, and is also higher than the record-efﬁciency 1-sun GaAs device. However, using a GaAs substrate is expensive and not practical. Hence researchers try to make a cell with two electrical contact points and one junction, which does not need a GaAs substrate. This means there will be direct integration of GaInP and Si.
Perovskite solar cells are solar cells that include a perovskite-structured material as the active layer. Most commonly, this is a solution-processed hybrid organic-inorganic tin or lead halide based material. Efficiencies have increased from below 5% at their first usage in 2009 to over 20% in 2014, making them a very rapidly advancing technology and a hot topic in the solar cell field. Perovskite solar cells are also forecast to be extremely cheap to scale up, making them a very attractive option for commercialisation. So far most types of perovskite solar cells have not reached sufficient operational stability to be commercialised, although many research groups are investigating ways to solve this.
With a transparent rear side, bifacial solar cells can absorb light from both the front and rear sides. Hence, they can produce more electricity than conventional monofacial solar cells. The first patent of bifacial solar cells was filed by Japanese researcher Hiroshi Mori, in 1966. Later, it is said that Russia was the first to deploy bifacial solar cells in their space program in the 1970s. In 1976, the Institute for Solar Energy of the Technical University of Madrid, began a research program for the development of bifacial solar cells led by Prof. Antonio Luque. Based on 1977 US and Spanish patents by Luque, a practical bifacial cell was proposed with a front face as anode and a rear face as cathode; in previously reported proposals and attempts both faces were anodic and interconnection between cells was complicated and expensive. In 1980, Andrés Cuevas, a PhD student in Luque's team, demonstrated experimentally a 50% increase in output power of bifacial solar cells, relative to identically oriented and tilted monofacial ones, when a white background was provided. In 1981 the company Isofoton was founded in Málaga to produce the developed bifacial cells, thus becoming the first industrialization of this PV cell technology. With an initial production capacity of 300 kW/yr. of bifacial solar cells, early landmarks of Isofoton's production were the 20kWp power plant in San Agustín de Guadalix, built in 1986 for Iberdrola, and an off grid installation by 1988 also of 20kWp in the village of Noto Gouye Diama (Senegal) funded by the Spanish international aid and cooperation programs.
Due to the reduced manufacturing cost, companies have again started to produce commercial bifacial modules since 2010. By 2017, there were at least eight certified PV manufacturers providing bifacial modules in North America. It has been predicted by the International Technology Roadmap for Photovoltaics (ITRPV) that the global market share of bifacial technology will expand from less than 5% in 2016 to 30% in 2027.
Due to the significant interest in the bifacial technology, a recent study has investigated the performance and optimization of bifacial solar modules worldwide. The results indicate that, across the globe, ground-mounted bifacial modules can only offer ~10% gain in annual electricity yields compared to the monofacial counterparts for a ground albedo coefficient of 25% (typical for concrete and vegetation groundcovers). However, the gain can be increased to ~30% by elevating the module 1 m above the ground and enhancing the ground albedo coefficient to 50%. Sun et al. also derived a set of empirical equations that can optimize bifacial solar modules analytically.
An online simulation tool is available to model the performance of bifacial modules in any arbitrary location across the entire world. It can also optimize bifacial modules as a function of tilt angle, azimuth angle, and elevation above the ground.
Intermediate band photovoltaics in solar cell research provides methods for exceeding the Shockley–Queisser limit on the efficiency of a cell. It introduces an intermediate band (IB) energy level in between the valence and conduction bands. Theoretically, introducing an IB allows two photons with energy less than the bandgap to excite an electron from the valence band to the conduction band. This increases the induced photocurrent and thereby efficiency.
Luque and Marti first derived a theoretical limit for an IB device with one midgap energy level using detailed balance. They assumed no carriers were collected at the IB and that the device was under full concentration. They found the maximum efficiency to be 63.2%, for a bandgap of 1.95eV with the IB 0.71eV from either the valence or conduction band. Under one sun illumination the limiting efficiency is 47%.
Photon upconversion is the process of using two low-energy (e.g., infrared) photons to produce one higher energy photon; downconversion is the process of using one high energy photon (e.g.,, ultraviolet) to produce two lower energy photons. Either of these techniques could be used to produce higher efficiency solar cells by allowing solar photons to be more efficiently used. The difficulty, however, is that the conversion efficiency of existing phosphors exhibiting up- or down-conversion is low, and is typically narrow band.
One upconversion technique is to incorporate lanthanide-doped materials (Er3+
or a combination), taking advantage of their luminescence to convert infrared radiation to visible light. Upconversion process occurs when two infrared photons are absorbed by rare-earth ions to generate a (high-energy) absorbable photon. As example, the energy transfer upconversion process (ETU), consists in successive transfer processes between excited ions in the near infrared. The upconverter material could be placed below the solar cell to absorb the infrared light that passes through the silicon. Useful ions are most commonly found in the trivalent state. Er+
ions have been the most used. Er3+
ions absorb solar radiation around 1.54 µm. Two Er3+
ions that have absorbed this radiation can interact with each other through an upconversion process. The excited ion emits light above the Si bandgap that is absorbed by the solar cell and creates an additional electron–hole pair that can generate current. However, the increased efficiency was small. In addition, fluoroindate glasses have low phonon energy and have been proposed as suitable matrix doped with Ho3+
Dye-sensitized solar cells (DSSCs) are made of low-cost materials and do not need elaborate manufacturing equipment, so they can be made in a DIY fashion. In bulk it should be significantly less expensive than older solid-state cell designs. DSSC's can be engineered into flexible sheets and although its conversion efficiency is less than the best thin film cells, its price/performance ratio may be high enough to allow them to compete with fossil fuel electrical generation.
Typically a ruthenium metalorganic dye (Ru-centered) is used as a monolayer of light-absorbing material. The dye-sensitized solar cell depends on a mesoporous layer of nanoparticulate titanium dioxide to greatly amplify the surface area (200–300 m2/g TiO
2, as compared to approximately 10 m2/g of flat single crystal). The photogenerated electrons from the light absorbing dye are passed on to the n-type TiO
2 and the holes are absorbed by an electrolyte on the other side of the dye. The circuit is completed by a redox couple in the electrolyte, which can be liquid or solid. This type of cell allows more flexible use of materials and is typically manufactured by screen printing or ultrasonic nozzles, with the potential for lower processing costs than those used for bulk solar cells. However, the dyes in these cells also suffer from degradation under heat and UV light and the cell casing is difficult to seal due to the solvents used in assembly. The first commercial shipment of DSSC solar modules occurred in July 2009 from G24i Innovations.
Quantum dot solar cells (QDSCs) are based on the Gratzel cell, or dye-sensitized solar cell architecture, but employ low band gap semiconductor nanoparticles, fabricated with crystallite sizes small enough to form quantum dots (such as CdS, CdSe, Sb
3, PbS, etc.), instead of organic or organometallic dyes as light absorbers. Due to the toxicity associated with Cd and Pb based compounds there are also a series of "green" QD sensitizing materials in development (such as CuInS2, CuInSe2 and CuInSeS). QD's size quantization allows for the band gap to be tuned by simply changing particle size. They also have high extinction coefficients and have shown the possibility of multiple exciton generation.
In a QDSC, a mesoporous layer of titanium dioxide nanoparticles forms the backbone of the cell, much like in a DSSC. This TiO
2 layer can then be made photoactive by coating with semiconductor quantum dots using chemical bath deposition, electrophoretic deposition or successive ionic layer adsorption and reaction. The electrical circuit is then completed through the use of a liquid or solid redox couple. The efficiency of QDSCs has increased to over 5% shown for both liquid-junction and solid state cells, with a reported peak efficiency of 11.91%. In an effort to decrease production costs, the Prashant Kamat research group demonstrated a solar paint made with TiO
2 and CdSe that can be applied using a one-step method to any conductive surface with efficiencies over 1%. However, the absorption of quantum dots (QDs) in QDSCs is weak at room temperature. The plasmonic nanoparticles can be utilized to address the weak absorption of QDs (e.g., nanostars). Adding an external infrared pumping sources to excite intraband and interband transition of QDs is another solution.
Organic solar cells and polymer solar cells are built from thin films (typically 100 nm) of organic semiconductors including polymers, such as polyphenylene vinylene and small-molecule compounds like copper phthalocyanine (a blue or green organic pigment) and carbon fullerenes and fullerene derivatives such as PCBM.
They can be processed from liquid solution, offering the possibility of a simple roll-to-roll printing process, potentially leading to inexpensive, large-scale production. In addition, these cells could be beneficial for some applications where mechanical flexibility and disposability are important. Current cell efficiencies are, however, very low, and practical devices are essentially non-existent.
Energy conversion efficiencies achieved to date using conductive polymers are very low compared to inorganic materials. However, Konarka Power Plastic reached efficiency of 8.3% and organic tandem cells in 2012 reached 11.1%.
The active region of an organic device consists of two materials, one electron donor and one electron acceptor. When a photon is converted into an electron hole pair, typically in the donor material, the charges tend to remain bound in the form of an exciton, separating when the exciton diffuses to the donor-acceptor interface, unlike most other solar cell types. The short exciton diffusion lengths of most polymer systems tend to limit the efficiency of such devices. Nanostructured interfaces, sometimes in the form of bulk heterojunctions, can improve performance.
In 2011, MIT and Michigan State researchers developed solar cells with a power efficiency close to 2% with a transparency to the human eye greater than 65%, achieved by selectively absorbing the ultraviolet and near-infrared parts of the spectrum with small-molecule compounds. Researchers at UCLA more recently developed an analogous polymer solar cell, following the same approach, that is 70% transparent and has a 4% power conversion efficiency. These lightweight, flexible cells can be produced in bulk at a low cost and could be used to create power generating windows.
In 2013, researchers announced polymer cells with some 3% efficiency. They used block copolymers, self-assembling organic materials that arrange themselves into distinct layers. The research focused on P3HT-b-PFTBT that separates into bands some 16 nanometers wide.
Adaptive cells change their absorption/reflection characteristics depending to respond to environmental conditions. An adaptive material responds to the intensity and angle of incident light. At the part of the cell where the light is most intense, the cell surface changes from reflective to adaptive, allowing the light to penetrate the cell. The other parts of the cell remain reflective increasing the retention of the absorbed light within the cell.
In 2014, a system was developed that combined an adaptive surface with a glass substrate that redirect the absorbed to a light absorber on the edges of the sheet. The system also includes an array of fixed lenses/mirrors to concentrate light onto the adaptive surface. As the day continues, the concentrated light moves along the surface of the cell. That surface switches from reflective to adaptive when the light is most concentrated and back to reflective after the light moves along.
For the past years, researchers have been trying to reduce the price of solar cells while maximizing efficiency. Thin-film solar cell is a cost-effective second generation solar cell with much reduced thickness at the expense of light absorption efficiency. Efforts to maximize light absorption efficiency with reduced thickness have been made. Surface texturing is one of techniques used to reduce optical losses to maximize light absorbed. Currently, surface texturing techniques on silicon photovoltaics are drawing much attention. Surface texturing could be done in multiple ways. Etching single crystalline silicon substrate can produce randomly distributed square based pyramids on the surface using anisotropic etchants. Recent studies show that c-Si wafers could be etched down to form nano-scale inverted pyramids. Multicrystalline silicon solar cells, due to poorer crystallographic quality, are less effective than single crystal solar cells, but mc-Si solar cells are still being used widely due to less manufacturing difficulties. It is reported that multicrystalline solar cells can be surface-textured to yield solar energy conversion efficiency comparable to that of monocrystalline silicon cells, through isotropic etching or photolithography techniques. Incident light rays onto a textured surface do not reflect back out to the air as opposed to rays onto a flat surface. Rather some light rays are bounced back onto the other surface again due to the geometry of the surface. This process significantly improves light to electricity conversion efficiency, due to increased light absorption. This texture effect as well as the interaction with other interfaces in the PV module is a challenging optical simulation task. A particularly efficient method for modeling and optimization is the OPTOS formalism. In 2012, researchers at MIT reported that c-Si films textured with nanoscale inverted pyramids could achieve light absorption comparable to 30 times thicker planar c-Si. In combination with anti-reflective coating, surface texturing technique can effectively trap light rays within a thin film silicon solar cell. Consequently, required thickness for solar cells decreases with the increased absorption of light rays.
Solar cells are commonly encapsulated in a transparent polymeric resin to protect the delicate solar cell regions for coming into contact with moisture, dirt, ice, and other conditions expected either during operation or when used outdoors. The encapsulants are commonly made from polyvinyl acetate or glass. Most encapsulants are uniform in structure and composition, which increases light collection owing to light trapping from total internal reflection of light within the resin. Research has been conducted into structuring the encapsulant to provide further collection of light. Such encapsulants have included roughened glass surfaces, diffractive elements, prism arrays, air prisms, v-grooves, diffuse elements, as well as multi-directional waveguide arrays. Prism arrays show an overall 5% increase in the total solar energy conversion. Arrays of vertically aligned broadband waveguides provide a 10% increase at normal incidence, as well as wide-angle collection enhancement of up to 4%, with optimized structures yielding up to a 20% increase in short circuit current. Active coatings that convert infrared light into visible light have shown a 30% increase. Nanoparticle coatings inducing plasmonic light scattering increase wide-angle conversion efficiency up to 3%. Optical structures have also been created in encapsulation materials to effectively "cloak" the metallic front contacts.
Solar cells share some of the same processing and manufacturing techniques as other semiconductor devices. However, the stringent requirements for cleanliness and quality control of semiconductor fabrication are more relaxed for solar cells, lowering costs.
Polycrystalline silicon wafers are made by wire-sawing block-cast silicon ingots into 180 to 350 micrometer wafers. The wafers are usually lightly p-type-doped. A surface diffusion of n-type dopants is performed on the front side of the wafer. This forms a p–n junction a few hundred nanometers below the surface.
Anti-reflection coatings are then typically applied to increase the amount of light coupled into the solar cell. Silicon nitride has gradually replaced titanium dioxide as the preferred material, because of its excellent surface passivation qualities. It prevents carrier recombination at the cell surface. A layer several hundred nanometers thick is applied using PECVD. Some solar cells have textured front surfaces that, like anti-reflection coatings, increase the amount of light reaching the wafer. Such surfaces were first applied to single-crystal silicon, followed by multicrystalline silicon somewhat later.
A full area metal contact is made on the back surface, and a grid-like metal contact made up of fine "fingers" and larger "bus bars" are screen-printed onto the front surface using a silver paste. This is an evolution of the so-called "wet" process for applying electrodes, first described in a US patent filed in 1981 by Bayer AG. The rear contact is formed by screen-printing a metal paste, typically aluminium. Usually this contact covers the entire rear, though some designs employ a grid pattern. The paste is then fired at several hundred degrees Celsius to form metal electrodes in ohmic contact with the silicon. Some companies use an additional electro-plating step to increase efficiency. After the metal contacts are made, the solar cells are interconnected by flat wires or metal ribbons, and assembled into modules or "solar panels". Solar panels have a sheet of tempered glass on the front, and a polymer encapsulation on the back.
Solar cells are manufactured in volume in Japan, Germany, China, Taiwan, Malaysia and the United States, whereas Europe, China, the U.S., and Japan have dominated (94% or more as of 2013) in installed systems. Other nations are acquiring significant solar cell production capacity.
Global PV cell/module production increased by 10% in 2012 despite a 9% decline in solar energy investments according to the annual "PV Status Report" released by the European Commission's Joint Research Centre. Between 2009 and 2013 cell production has quadrupled.
Due to heavy government investment, China has become the dominant force in solar cell manufacturing. Chinese companies produced solar cells/modules with a capacity of ~23 GW in 2013 (60% of global production).
Solar cells degrade over time and lose their efficiency. Solar cells in extreme climates, such as desert or polar, are more prone to degradation due to exposure to harsh UV light and snow loads respectively. Usually, solar panels are given a lifespan of 25–30 years before they get decommissioned.
The International Renewable Energy Agency estimated that the amount of solar panel waste generated in 2016 was 43,500–250,000 metric tons. This number is estimated to increase substantially by 2030, reaching an estimated waste volume of 60–78 million metric tons in 2050.
In 2018, most decommissioned solar panels were sent to landfills. Recycling is limited because it is too expensive to process the low volume of solar panel waste. However, solar cells contain toxic materials like lead and cadmium which, when broken, could leach into the soil and contaminate the environment. With the volume of solar panel waste set to increase, the safety of disposing solar panels in landfills is becoming a big concern. Many manufacturers are turning to recycling solar panels instead.
The first solar panel recycling plant opened in Rousset, France in 2018. It was set to recycle 1300 tonnes of solar panel waste a year, and can increase its capacity to 4000 tonnes.
The 21 megawatt Blythe Photovoltaic Power Plant is a photovoltaic (PV) solar project in California. It is located in Blythe, California, in Riverside County about 200 miles (320 km) east of Los Angeles. Commercial operation began in December 2009. Electricity generated by the power plant is being sold to Southern California Edison under a 20-year power purchase agreement. Another 20 MW plant called NRG Solar Blythe II came online in April 2017.Copper indium gallium selenide solar cells
A copper indium gallium selenide solar cell (or CIGS cell, sometimes CI(G)S or CIS cell) is a thin-film solar cell used to convert sunlight into electric power. It is manufactured by depositing a thin layer of copper, indium, gallium and selenium on glass or plastic backing, along with electrodes on the front and back to collect current. Because the material has a high absorption coefficient and strongly absorbs sunlight, a much thinner film is required than of other semiconductor materials.
CIGS is one of three mainstream thin-film PV technologies, the other two being cadmium telluride and amorphous silicon. Like these materials, CIGS layers are thin enough to be flexible, allowing them to be deposited on flexible substrates. However, as all of these technologies normally use high-temperature deposition techniques, the best performance normally comes from cells deposited on glass, even though advances in low-temperature deposition of CIGS cells have erased much of this performance difference. CIGS outperforms polysilicon at the cell level, however its module efficiency is still lower, due to a less mature upscaling.Thin-film market share is stagnated at around 15 percent, leaving the rest of the PV market to conventional solar cells made of crystalline silicon. In 2013, the market share of CIGS alone was about 2 percent and all thin-film technologies combined fell below 10 percent. CIGS cells continue being developed, as they promise to reach silicon-like efficiencies, while maintaining their low costs, as is typical for thin-film technology. Prominent manufacturers of CIGS photovoltaics were the now-bankrupt companies Nanosolar and Solyndra. Current market leader is the Japanese company Solar Frontier, with Global Solar and GSHK Solar also producing solar modules free of any heavy metals such as cadmium and/or lead.Crystalline silicon
Crystalline silicon (c-Si) is the crystalline forms of silicon, either multicrystalline silicon (multi-Si) consisting of small crystals, or monocrystalline silicon (mono-Si), a continuous crystal. Crystalline silicon is the dominant semiconducting material used in photovoltaic technology for the production of solar cells. These cells are assembled into solar panels as part of a photovoltaic system to generate solar power from sunlight.
In electronics, crystalline silicon is typically the monocrystalline form of silicon, and is used for producing microchips. This silicon contains much lower impurity levels than those required for solar cells. Production of semiconductor grade silicon involves a chemical purification to produce hyperpure polysilicon followed by a recrystallization process to grow monocrystalline silicon. The cylindrical boules are then cut into wafers for further processing.
Solar cells made of crystalline silicon are often called conventional, traditional, or first generation solar cells, as they were developed in the 1950s and remained the most common type up to the present time. Because they are produced from 160–190 µm thick solar wafers—slices from bulks of solar grade silicon—they are sometimes called wafer-based solar cells.
Solar cells made from c-Si are single-junction cells and are generally more efficient than their rival technologies, which are the second-generation thin film solar cells, the most important being CdTe, CIGS, and amorphous silicon (a-Si). Amorphous silicon is an allotropic variant of silicon, and amorphous means "without shape" to describe its non-crystalline form.Dye-sensitized solar cell
A dye-sensitized solar cell (DSSC, DSC, DYSC or Grätzel cell) is a low-cost solar cell belonging to the group of thin film solar cells. It is based on a semiconductor formed between a photo-sensitized anode and an electrolyte, a photoelectrochemical system. The modern version of a dye solar cell, also known as the Grätzel cell, was originally co-invented in 1988 by Brian O'Regan and Michael Grätzel at UC Berkeley and this work was later developed by the aforementioned scientists at the École Polytechnique Fédérale de Lausanne until the publication of the first high efficiency DSSC in 1991. Michael Grätzel has been awarded the 2010 Millennium Technology Prize for this invention.The DSSC has a number of attractive features; it is simple to make using conventional roll-printing techniques, is semi-flexible and semi-transparent which offers a variety of uses not applicable to glass-based systems, and most of the materials used are low-cost. In practice it has proven difficult to eliminate a number of expensive materials, notably platinum and ruthenium, and the liquid electrolyte presents a serious challenge to making a cell suitable for use in all weather. Although its conversion efficiency is less than the best thin-film cells, in theory its price/performance ratio should be good enough to allow them to compete with fossil fuel electrical generation by achieving grid parity. Commercial applications, which were held up due to chemical stability problems, are forecast in the European Union Photovoltaic Roadmap to significantly contribute to renewable electricity generation by 2020.Flexible solar cell research
Flexible solar cell research is a research-level technology, an example of which was created at the Massachusetts Institute of Technology in which solar cells are manufactured by depositing photovoltaic material on flexible substrates, such as ordinary paper, using chemical vapor deposition technology. The technology for manufacturing solar cells on paper was developed by a group of researchers from the Massachusetts Institute of Technology with support from the National Science Foundation and the Eni-MIT Alliance Solar Frontiers Program.List of photovoltaics companies
This is a list of notable photovoltaics (PV) companies.
Grid-connected solar photovoltaics (PV) is the fastest growing energy technology in the world, growing from a cumulative installed capacity of 7.7 GW in 2007, to 320 GW in 2016. In 2016, 93% of the global PV cell manufacturing capacity utilizes crystalline silicon (cSi) technology, representing a commanding lead over rival forms of PV technology, such as cadmium telluride (CdTe), amorphous silicon (aSi), and copper indium gallium selenide (CIGS). In 2016, manufacturers in China and Taiwan met the majority of global PV module demand, accounting for 68% of all modules, followed by the rest of Asia at 14%. The United States and Canada manufactured 6%, and Europe manufactured a mere 4%.Photovoltaics companies include PV capital equipment producers, cell manufacturers, panel manufacturers and installers. The list does not include silicon manufacturing companies.Multi-junction solar cell
Multi-junction (MJ) solar cells are solar cells with multiple p–n junctions made of different semiconductor materials. Each material's p-n junction will produce electric current in response to different wavelengths of light. The use of multiple semiconducting materials allows the absorbance of a broader range of wavelengths, improving the cell's sunlight to electrical energy conversion efficiency.
Traditional single-junction cells have a maximum theoretical efficiency of 33.16%. Theoretically, an infinite number of junctions would have a limiting efficiency of 86.8% under highly concentrated sunlight.Currently, the best lab examples of traditional crystalline silicon (c-Si) solar cells have efficiencies between 20% and 25%, while lab examples of multi-junction cells have demonstrated performance over 46% under concentrated sunlight. Commercial examples of tandem cells are widely available at 30% under one-sun illumination, and improve to around 40% under concentrated sunlight. However, this efficiency is gained at the cost of increased complexity and manufacturing price. To date, their higher price and higher price-to-performance ratio have limited their use to special roles, notably in aerospace where their high power-to-weight ratio is desirable. In terrestrial applications, these solar cells are emerging in concentrator photovoltaics (CPV), with a growing number of installations around the world.Tandem fabrication techniques have been used to improve the performance of existing designs. In particular, the technique can be applied to lower cost thin-film solar cells using amorphous silicon, as opposed to conventional crystalline silicon, to produce a cell with about 10% efficiency that is lightweight and flexible. This approach has been used by several commercial vendors, but these products are currently limited to certain niche roles, like roofing materials.Nanocrystal solar cell
Nanocrystal solar cells are solar cells based on a substrate with a coating of nanocrystals. The nanocrystals are typically based on silicon, CdTe or CIGS and the substrates are generally silicon or various organic conductors. Quantum dot solar cells are a variant of this approach, but take advantage of quantum mechanical effects to extract further performance. Dye-sensitized solar cells are another related approach, but in this case the nano-structuring is part of the substrate.
Previous fabrication methods relied on expensive molecular beam epitaxy processes, but colloidal synthesis allows for cheaper manufacture. A thin film of nanocrystals is obtained by a process known as "spin-coating". This involves placing an amount of the quantum dot solution onto a flat substrate, which is then rotated very quickly. The solution spreads out uniformly, and the substrate is spun until the required thickness is achieved.
Quantum dot based photovoltaic cells based on dye-sensitized colloidal TiO2 films were investigated in 1991
and were found to exhibit promising efficiency of converting incident light energy to electrical energy, and to be incredibly encouraging due to the low cost of materials used. A single-nanocrystal (channel) architecture in which an array of single particles between the electrodes, each separated by ~1 exciton diffusion length, was proposed to improve the device efficiency and research on this type of solar cell is being conducted by groups at Stanford, Berkeley and the University of Tokyo.
Although research is still in its infancy, in the future nanocrystal photovoltaics may offer advantages such as flexibility (quantum dot-polymer composite photovoltaics)
lower costs, clean power generation and an efficiency of 65%, compared to around 20 to 25% for first-generation, crystalline silicon-based photovoltaics.It is argued that many measurements of the efficiency of the nanocrystal solar cell are incorrect and that nanocrystal solar cells are not suitable for large scale manufacturing.Recent research has experimented with lead selenide (PbSe) semiconductor, as well as with cadmium telluride photovoltaics (CdTe), which has already been well established in the production of second-generation thin film solar cells. Other materials are being researched as well.Organic solar cell
An organic solar cell or plastic solar cell is a type of photovoltaic that uses organic electronics, a branch of electronics that deals with conductive organic polymers or small organic molecules, for light absorption and charge transport to produce electricity from sunlight by the photovoltaic effect. Most organic photovoltaic cells are polymer solar cells.
The molecules used in organic solar cells are solution-processable at high throughput and are cheap, resulting in low production costs to fabricate a large volume. Combined with the flexibility of organic molecules, organic solar cells are potentially cost-effective for photovoltaic applications. Molecular engineering (e.g. changing the length and functional group of polymers) can change the band gap, allowing for electronic tunability. The optical absorption coefficient of organic molecules is high, so a large amount of light can be absorbed with a small amount of materials, usually on the order of hundreds of nanometers. The main disadvantages associated with organic photovoltaic cells are low efficiency, low stability and low strength compared to inorganic photovoltaic cells such as silicon solar cells.
Compared to silicon-based devices, polymer solar cells are lightweight (which is important for small autonomous sensors), potentially disposable and inexpensive to fabricate (sometimes using printed electronics), flexible, customizable on the molecular level and potentially have less adverse environmental impact. Polymer solar cells also have the potential to exhibit transparency, suggesting applications in windows, walls, flexible electronics, etc. An example device is shown in Fig. 1. The disadvantages of polymer solar cells are also serious: they offer about 1/3 of the efficiency of hard materials, and experience substantial photochemical degradation.Polymer solar cells inefficiency and stability problems, combined with their promise of low costs and increased efficiency made them a popular field in solar cell research. As of 2015, polymer solar cells were able to achieve over 10% efficiency via a tandem structure. In 2018, a record breaking efficiency for organic photovoltaics of 17.3% was reached via tandem structure.Perovskite solar cell
A perovskite solar cell is a type of solar cell which includes a perovskite structured compound, most commonly a hybrid organic-inorganic lead or tin halide-based material, as the light-harvesting active layer. Perovskite materials, such as methylammonium lead halides and all-inorganic cesium lead halide, are cheap to produce and simple to manufacture.
Solar cell efficiencies of devices using these materials have increased from 3.8% in 2009 to 23.3% in late 2018 in single-junction architectures, and, in silicon-based tandem cells, to 27.3%, exceeding the maximum efficiency achieved in single-junction silicon solar cells. Perovskite solar cells are therefore the fastest-advancing solar technology to date. With the potential of achieving even higher efficiencies and very low production costs, perovskite solar cells have become commercially attractive.Plasmonic solar cell
A plasmonic-enhanced solar cell is a type of solar cell (including thin-film, crystalline silicon, amorphous silicon, and other types of cells) that convert light into electricity with the assistance of plasmons.
The thickness varies from that of traditional silicon PV
, to less than 2 μm thick and theoretically could be as thin as 100 nm. They can use substrates which are cheaper than silicon, such as glass, plastic or steel. One of the challenges for thin film solar cells is that they do not absorb as much light as thicker solar cells made with materials with the same absorption coefficient. Methods for light trapping are important for thin film solar cells. Plasmonic-enhanced cells improve absorption by scattering light using metal nano-particles excited at their surface plasmon resonance. Interestingly, plasmonic core-shell nanoparticles located in the front of the thin film solar cells can aid weak absorption of Si solar cells in the near-infrared region—the fraction of light scattered into the substrate and the maximum optical path length enhancement can be as high as 0.999 and 3133. Incoming light at the plasmon resonance frequency induces electron oscillations at the surface of the nanoparticles. The oscillation electrons can then be captured by a conductive layer producing an electrical current. The voltage produced is dependent on the bandgap of the conductive layer and the potential of the electrolyte in contact with the nanoparticles. There is still considerable research necessary to enable the technology to reach its full potential and commercialization of plasmonic-enhanced solar cells.Quantum dot solar cell
A quantum dot solar cell (QDSC) is a solar cell design that uses quantum dots as the absorbing photovoltaic material. It attempts to replace bulk materials such as silicon, copper indium gallium selenide (CIGS) or cadmium telluride (CdTe). Quantum dots have bandgaps that are tunable across a wide range of energy levels by changing their size. In bulk materials, the bandgap is fixed by the choice of material(s). This property makes quantum dots attractive for multi-junction solar cells, where a variety of materials are used to improve efficiency by harvesting multiple portions of the solar spectrum.
As of 2016, efficiency exceeds 10%.Solar cell efficiency
Solar cell efficiency refers to the portion of energy in the form of sunlight that can be converted via photovoltaics into electricity.
The efficiency of the solar cells used in a photovoltaic system, in combination with latitude and climate, determines the annual energy output of the system. For example, a solar panel with 20% efficiency and an area of 1 m2 will produce 200 W at Standard Test Conditions, but it can produce more when the sun is high in the sky and will produce less in cloudy conditions or when the sun is low in the sky. In central Colorado, which receives annual insolation of 5.5 kWh/m2/day (230W/m2), such a panel can be expected to produce 400 kWh of energy per year. However, in Michigan, which receives only 3.8 kWh/m2/day, annual energy yield will drop to 280 kWh for the same panel. At more northerly European latitudes, yields are significantly lower: 175 kWh annual energy yield in southern England.
Several factors affect a cell's conversion efficiency value, including its reflectance efficiency, thermodynamic efficiency, charge carrier separation efficiency, charge carrier collection efficiency and conduction efficiency values. Because these parameters can be difficult to measure directly, other parameters are measured instead, including quantum efficiency, open-circuit voltage (VOC) ratio, and § Fill factor (described below). Reflectance losses are accounted for by the quantum efficiency value, as they affect "external quantum efficiency." Recombination losses are accounted for by the quantum efficiency, VOC ratio, and fill factor values. Resistive losses are predominantly accounted for by the fill factor value, but also contribute to the quantum efficiency and VOC ratio values.
As of December 2014, the world record for solar cell efficiency at 46.0% was achieved by using multi-junction concentrator solar cells, developed from collaboration efforts of Soitec, CEA-Leti, France together with Fraunhofer ISE, Germany. This is above the standard rating of 37.0% for a polycrystalline photovoltaic or thin-film solar cells.Solar cell phone charger
Solar cell phone chargers use solar panels to charge cell phone batteries. They are an alternative to conventional electrical cell phone chargers and in some cases can be plugged into an electrical outlet.There are also public solar chargers for mobile phones which can be installed permanently in public places such as streets, park and squares. The model which is according to European Commission proclaimed as the first in the world is the Strawberry Tree, public solar charger invented by Strawberry energy Company. This solar station won the first place at "EU Sustainable energy week (EUSEW) 2011" in the Consuming category.Some models of cell phones have a built in solar charger and are commercially available for GSM cellphone models.Solar cell phone chargers come in different shapes and configurations including folding (Goal Zero, Endless Sun Solar) and rotating types (Solio).They also come in the form of straps, with solar cells on the outer surface and a nickel metal hydride battery within. Current solar cell technology limit the effectiveness and practicality of phone solar chargers for everyday use. Phone charge times vary depending on the battery capacity installed which continues to increase, further extending the charge times of solar chargers. The fold-out design has proven to allow for higher charge current while maintaining a compact size and current designs are capable of charging a modern smartphone in 3 hours.
Solar chargers are also available for other cell phone accessories, such as bluetooth headsets and speaker phones.Solar cell research
There are currently many research groups active in the field of photovoltaics in universities and research institutions around the world. This research can be categorized into three areas: making current technology solar cells cheaper and/or more efficient to effectively compete with other energy sources; developing new technologies based on new solar cell architectural designs; and developing new materials to serve as more efficient energy converters from light energy into electric current or light absorbers and charge carriers.Solid-state electronics
Solid-state electronics means semiconductor electronics; electronic equipment using semiconductor devices such as semiconductor diodes, transistors, and integrated circuits (ICs). The term is also used for devices in which semiconductor electronics which have no moving parts replace devices with moving parts, such as the solid-state relay in which transistor switches are used in place of a moving-arm electromechanical relay, or the solid-state drive (SSD) a type of semiconductor memory used in computers to replace hard disk drives, which store data on a rotating disk.The term "solid state" became popular in the beginning of the semiconductor era in the 1960s to distinguish this new technology based on the transistor, in which the electronic action of devices occurred in a solid state, from previous electronic equipment that used vacuum tubes, in which the electronic action occurred in a gaseous state. A semiconductor device works by controlling an electric current consisting of electrons or holes moving within a solid crystalline piece of semiconducting material such as silicon, while the thermionic vacuum tubes it replaced worked by controlling current conducted by a gas of particles, electrons or ions, moving in a vacuum within a sealed tube. Although the first solid state electronic device was the cat's whisker detector, a crude semiconductor diode invented around 1904, solid state electronics really started with the invention of the transistor in 1947. Before that, all electronic equipment used vacuum tubes, because vacuum tubes were the only electronic components that could amplify—an essential capability in all electronics. The replacement of bulky, fragile, energy-wasting vacuum tubes by transistors in the 1960s and 1970s created a revolution not just in technology but in people's habits, making possible the first truly portable consumer electronics such as the transistor radio, cassette tape player, walkie-talkie and quartz watch, as well as the first practical computers and mobile phones.
Today, almost all electronics are solid-state except in some applications such as radio transmitters, in which vacuum tubes are still used, and some power industrial control circuits which use electromechanical devices such as relays. Additional examples of solid state electronic devices are the microprocessor chip, LED lamp, solar cell, charge coupled device (CCD) image sensor used in cameras, and semiconductor laser.Thin-film solar cell
A thin-film solar cell is a second generation solar cell that is made by depositing one or more thin layers, or thin film (TF) of photovoltaic material on a substrate, such as glass, plastic or metal. Thin-film solar cells are commercially used in several technologies, including cadmium telluride (CdTe), copper indium gallium diselenide (CIGS), and amorphous thin-film silicon (a-Si, TF-Si).
Film thickness varies from a few nanometers (nm) to tens of micrometers (µm), much thinner than thin-film's rival technology, the conventional, first-generation crystalline silicon solar cell (c-Si), that uses wafers of up to 200 µm thick. This allows thin film cells to be flexible, and lower in weight. It is used in building integrated photovoltaics and as semi-transparent, photovoltaic glazing material that can be laminated onto windows. Other commercial applications use rigid thin film solar panels (sandwiched between two panes of glass) in some of the world's largest photovoltaic power stations.
Thin-film technology has always been cheaper but less efficient than conventional c-Si technology. However, it has significantly improved over the years. The lab cell efficiency for CdTe and CIGS is now beyond 21 percent, outperforming multicrystalline silicon, the dominant material currently used in most solar PV systems. Accelerated life testing of thin film modules under laboratory conditions measured a somewhat faster degradation compared to conventional PV, while a lifetime of 20 years or more is generally expected. Despite these enhancements, market-share of thin-film never reached more than 20 percent in the last two decades and has been declining in recent years to about 9 percent of worldwide photovoltaic installations in 2013.Other thin-film technologies that are still in an early stage of ongoing research or with limited commercial availability are often classified as emerging or third generation photovoltaic cells and include organic, and dye-sensitized, as well as quantum dot, copper zinc tin sulfide, nanocrystal, micromorph, and perovskite solar cells.Third-generation photovoltaic cell
Third-generation photovoltaic cells are solar cells that are potentially able to overcome the Shockley–Queisser limit of 31–41% power efficiency for single bandgap solar cells. This includes a range of alternatives to cells made of semiconducting p-n junctions ("first generation") and thin film cells ("second generation"). Common third-generation systems include multi-layer ("tandem") cells made of amorphous silicon or gallium arsenide, while more theoretical developments include frequency conversion, (i.e. changing the frequencies of light that the cell cannot use to light frequencies that the cell can use - thus producing more power), hot-carrier effects and other multiple-carrier ejection techniques.Emerging photovoltaics include:
Copper zinc tin sulfide solar cell (CZTS), and derivates CZTSe and CZTSSe
Dye-sensitized solar cell, also known as "Grätzel cell"
Organic solar cell
Perovskite solar cell
Quantum dot solar cellThe achievements in the research of perovskite cells, especially, have received tremendous attention in the public as their research efficiencies recently soared above 20 percent. They also offer a wide spectrum of low-cost applications. In addition, another emerging technology, concentrator photovoltaics (CPV), uses high-efficient, multi-junction solar cells in combination with optical lenses and a tracking system.Timeline of solar cells
In the 19th century, it was observed that the sunlight striking certain materials generates detectable electric current - the photoelectric effect. This discovery has laid the foundation of solar cells. Solar cells have gone on to be used in many applications. They have historically been used in situations where electrical power from the grid was unavailable.