A proton is a subatomic particle, symbol
, with a positive electric charge of +1e elementary charge and a mass slightly less than that of a neutron. Protons and neutrons, each with masses of approximately one atomic mass unit, are collectively referred to as "nucleons".
One or more protons are present in the nucleus of every atom; they are a necessary part of the nucleus. The number of protons in the nucleus is the defining property of an element, and is referred to as the atomic number (represented by the symbol Z). Since each element has a unique number of protons, each element has its own unique atomic number.
The word proton is Greek for "first", and this name was given to the hydrogen nucleus by Ernest Rutherford in 1920. In previous years, Rutherford had discovered that the hydrogen nucleus (known to be the lightest nucleus) could be extracted from the nuclei of nitrogen by atomic collisions. Protons were therefore a candidate to be a fundamental particle, and hence a building block of nitrogen and all other heavier atomic nuclei.
In the modern Standard Model of particle physics, protons are hadrons, and like neutrons, the other nucleon (particles present in atomic nuclei), are composed of three quarks. Although protons were originally considered fundamental or elementary particles, they are now known to be composed of three valence quarks: two up quarks of charge +2/e and one down quark of charge –1/e. The rest masses of quarks contribute only about 1% of a proton's mass, however. The remainder of a proton's mass is due to quantum chromodynamics binding energy, which includes the kinetic energy of the quarks and the energy of the gluon fields that bind the quarks together. Because protons are not fundamental particles, they possess a physical size, though not a definite one; the root mean square charge radius of a proton is about 0.84–0.87 fm or 0.84×10−15 to 0.87×10−15 m.
At sufficiently low temperatures, free protons will bind to electrons. However, the character of such bound protons does not change, and they remain protons. A fast proton moving through matter will slow by interactions with electrons and nuclei, until it is captured by the electron cloud of an atom. The result is a protonated atom, which is a chemical compound of hydrogen. In vacuum, when free electrons are present, a sufficiently slow proton may pick up a single free electron, becoming a neutral hydrogen atom, which is chemically a free radical. Such "free hydrogen atoms" tend to react chemically with many other types of atoms at sufficiently low energies. When free hydrogen atoms react with each other, they form neutral hydrogen molecules (H2), which are the most common molecular component of molecular clouds in interstellar space.
|Composition||2 up quarks (u), 1 down quark (d)|
|Interactions||Gravity, electromagnetic, weak, strong|
|Theorized||William Prout (1815)|
|Discovered||Observed as H+ by Eugen Goldstein (1886). Identified in other nuclei (and named) by Ernest Rutherford (1917–1920).|
|Mean lifetime||> 2.1×1029 years (stable)|
|Electric charge||+1 e|
|Charge radius||0.8751(61) fm|
|Electric dipole moment||< 5.4×10−24 e⋅cm|
|Electric polarizability||1.20(6)×10−3 fm3|
|Magnetic moment||1.4106067873(97)×10−26 J⋅T−1|
|Magnetic polarizability||1.9(5)×10−4 fm3|
|Condensed||I(JP) = 1/(1/+)|
|Unsolved problem in physics:|
How do the quarks and gluons carry the spin of protons?(more unsolved problems in physics)
Protons are spin-½ fermions and are composed of three valence quarks, making them baryons (a sub-type of hadrons). The two up quarks and one down quark of a proton are held together by the strong force, mediated by gluons.:21–22 A modern perspective has a proton composed of the valence quarks (up, up, down), the gluons, and transitory pairs of sea quarks. Protons have a positive charge distribution which decays approximately exponentially, with a mean square radius of about 0.8 fm.
Protons and neutrons are both nucleons, which may be bound together by the nuclear force to form atomic nuclei. The nucleus of the most common isotope of the hydrogen atom (with the chemical symbol "H") is a lone proton. The nuclei of the heavy hydrogen isotopes deuterium and tritium contain one proton bound to one and two neutrons, respectively. All other types of atomic nuclei are composed of two or more protons and various numbers of neutrons.
The concept of a hydrogen-like particle as a constituent of other atoms was developed over a long period. As early as 1815, William Prout proposed that all atoms are composed of hydrogen atoms (which he called "protyles"), based on a simplistic interpretation of early values of atomic weights (see Prout's hypothesis), which was disproved when more accurate values were measured.:39–42
In 1886, Eugen Goldstein discovered canal rays (also known as anode rays) and showed that they were positively charged particles (ions) produced from gases. However, since particles from different gases had different values of charge-to-mass ratio (e/m), they could not be identified with a single particle, unlike the negative electrons discovered by J. J. Thomson. Wilhelm Wien in 1898 identified the hydrogen ion as particle with highest charge-to-mass ratio in ionized gases.
Following the discovery of the atomic nucleus by Ernest Rutherford in 1911, Antonius van den Broek proposed that the place of each element in the periodic table (its atomic number) is equal to its nuclear charge. This was confirmed experimentally by Henry Moseley in 1913 using X-ray spectra.
In 1917 (in experiments reported in 1919), Rutherford proved that the hydrogen nucleus is present in other nuclei, a result usually described as the discovery of protons. Rutherford had earlier learned to produce hydrogen nuclei as a type of radiation produced as a product of the impact of alpha particles on nitrogen gas, and recognize them by their unique penetration signature in air and their appearance in scintillation detectors. These experiments were begun when Rutherford had noticed that, when alpha particles were shot into air (mostly nitrogen), his scintillation detectors showed the signatures of typical hydrogen nuclei as a product. After experimentation Rutherford traced the reaction to the nitrogen in air, and found that when alphas were produced into pure nitrogen gas, the effect was larger. Rutherford determined that this hydrogen could have come only from the nitrogen, and therefore nitrogen must contain hydrogen nuclei. One hydrogen nucleus was being knocked off by the impact of the alpha particle, producing oxygen-17 in the process. This was the first reported nuclear reaction, 14N + α → 17O + p. (This reaction would later be observed happening directly in a cloud chamber in 1925).
Rutherford knew hydrogen to be the simplest and lightest element and was influenced by Prout's hypothesis that hydrogen was the building block of all elements. Discovery that the hydrogen nucleus is present in all other nuclei as an elementary particle led Rutherford to give the hydrogen nucleus a special name as a particle, since he suspected that hydrogen, the lightest element, contained only one of these particles. He named this new fundamental building block of the nucleus the proton, after the neuter singular of the Greek word for "first", πρῶτον. However, Rutherford also had in mind the word protyle as used by Prout. Rutherford spoke at the British Association for the Advancement of Science at its Cardiff meeting beginning 24 August 1920. Rutherford was asked by Oliver Lodge for a new name for the positive hydrogen nucleus to avoid confusion with the neutral hydrogen atom. He initially suggested both proton and prouton (after Prout). Rutherford later reported that the meeting had accepted his suggestion that the hydrogen nucleus be named the "proton", following Prout's word "protyle". The first use of the word "proton" in the scientific literature appeared in 1920.
In a July 2017 paper, researchers measured the mass of a proton to be 1.007276466583+15
−29 atomic mass units (the values in parentheses being the statistical and systematic uncertainties, respectively), which is lower than measurements from the CODATA 2014 value by three standard deviations.
|Unsolved problem in physics:|
Are protons fundamentally stable? Or do they decay with a finite lifetime as predicted by some extensions to the standard model?(more unsolved problems in physics)
The free proton (a proton not bound to nucleons or electrons) is a stable particle that has not been observed to break down spontaneously to other particles. Free protons are found naturally in a number of situations in which energies or temperatures are high enough to separate them from electrons, for which they have some affinity. Free protons exist in plasmas in which temperatures are too high to allow them to combine with electrons. Free protons of high energy and velocity make up 90% of cosmic rays, which propagate in vacuum for interstellar distances. Free protons are emitted directly from atomic nuclei in some rare types of radioactive decay. Protons also result (along with electrons and antineutrinos) from the radioactive decay of free neutrons, which are unstable.
The spontaneous decay of free protons has never been observed, and protons are therefore considered stable particles according to the Standard Model. However, some grand unified theories (GUTs) of particle physics predict that proton decay should take place with lifetimes between 1031 to 1036 years and experimental searches have established lower bounds on the mean lifetime of a proton for various assumed decay products.
Experiments at the Super-Kamiokande detector in Japan gave lower limits for proton mean lifetime of 6.6×1033 years for decay to an antimuon and a neutral pion, and 8.2×1033 years for decay to a positron and a neutral pion. Another experiment at the Sudbury Neutrino Observatory in Canada searched for gamma rays resulting from residual nuclei resulting from the decay of a proton from oxygen-16. This experiment was designed to detect decay to any product, and established a lower limit to a proton lifetime of 2.1×1029 years.
However, protons are known to transform into neutrons through the process of electron capture (also called inverse beta decay). For free protons, this process does not occur spontaneously but only when energy is supplied. The equation is:
The process is reversible; neutrons can convert back to protons through beta decay, a common form of radioactive decay. In fact, a free neutron decays this way, with a mean lifetime of about 15 minutes.
In quantum chromodynamics, the modern theory of the nuclear force, most of the mass of protons and neutrons is explained by special relativity. The mass of a proton is about 80–100 times greater than the sum of the rest masses of the quarks that make it up, while the gluons have zero rest mass. The extra energy of the quarks and gluons in a region within a proton, as compared to the rest energy of the quarks alone in the QCD vacuum, accounts for almost 99% of the mass. The rest mass of a proton is, thus, the invariant mass of the system of moving quarks and gluons that make up the particle, and, in such systems, even the energy of massless particles is still measured as part of the rest mass of the system.
Two terms are used in referring to the mass of the quarks that make up protons: current quark mass refers to the mass of a quark by itself, while constituent quark mass refers to the current quark mass plus the mass of the gluon particle field surrounding the quark.:285–286 :150–151 These masses typically have very different values. As noted, most of a proton's mass comes from the gluons that bind the current quarks together, rather than from the quarks themselves. While gluons are inherently massless, they possess energy—to be more specific, quantum chromodynamics binding energy (QCBE)—and it is this that contributes so greatly to the overall mass of protons (see mass in special relativity). A proton has a mass of approximately 938 MeV/c2, of which the rest mass of its three valence quarks contributes only about 9.4 MeV/c2; much of the remainder can be attributed to the gluons' QCBE. 
The internal dynamics of protons are complicated, because they are determined by the quarks' exchanging gluons, and interacting with various vacuum condensates. Lattice QCD provides a way of calculating the mass of a proton directly from the theory to any accuracy, in principle. The most recent calculations claim that the mass is determined to better than 4% accuracy, even to 1% accuracy (see Figure S5 in Dürr et al.). These claims are still controversial, because the calculations cannot yet be done with quarks as light as they are in the real world. This means that the predictions are found by a process of extrapolation, which can introduce systematic errors. It is hard to tell whether these errors are controlled properly, because the quantities that are compared to experiment are the masses of the hadrons, which are known in advance.
These recent calculations are performed by massive supercomputers, and, as noted by Boffi and Pasquini: "a detailed description of the nucleon structure is still missing because ... long-distance behavior requires a nonperturbative and/or numerical treatment..." More conceptual approaches to the structure of protons are: the topological soliton approach originally due to Tony Skyrme and the more accurate AdS/QCD approach that extends it to include a string theory of gluons, various QCD-inspired models like the bag model and the constituent quark model, which were popular in the 1980s, and the SVZ sum rules, which allow for rough approximate mass calculations. These methods do not have the same accuracy as the more brute-force lattice QCD methods, at least not yet.
|Unsolved problem in physics:|
What is the true charge radius of a proton?(more unsolved problems in physics)
The problem of defining a radius for an atomic nucleus (proton) is similar to the problem of atomic radius, in that neither atoms nor their nuclei have definite boundaries. However, the nucleus can be modeled as a sphere of positive charge for the interpretation of electron scattering experiments: because there is no definite boundary to the nucleus, the electrons "see" a range of cross-sections, for which a mean can be taken. The qualification of "rms" (for "root mean square") arises because it is the nuclear cross-section, proportional to the square of the radius, which is determining for electron scattering.
The internationally accepted value of a proton's charge radius is 0.8768 fm (see orders of magnitude for comparison to other sizes). This value is based on measurements involving a proton and an electron (namely, electron scattering measurements and complex calculation involving scattering cross section based on Rosenbluth equation for momentum-transfer cross section), and studies of the atomic energy levels of hydrogen and deuterium.
However, in 2010 an international research team published a proton charge radius measurement via the Lamb shift in muonic hydrogen (an exotic atom made of a proton and a negatively charged muon). As a muon is 200 times heavier than an electron, its de Broglie wavelength is correspondingly shorter. This smaller atomic orbital is much more sensitive to the proton's charge radius, so allows more precise measurement. Their measurement of the root-mean-square charge radius of a proton is "0.84184(67) fm, which differs by 5.0 standard deviations from the CODATA value of 0.8768(69) fm". In January 2013, an updated value for the charge radius of a proton—0.84087(39) fm—was published. The precision was improved by 1.7 times, increasing the significance of the discrepancy to 7σ. The 2014 CODATA adjustment slightly reduced the recommended value for the proton radius (computed using electron measurements only) to 0.8751(61) fm, but this leaves the discrepancy at 5.6σ.
The international research team that obtained this result at the Paul Scherrer Institut in Villigen includes scientists from the Max Planck Institute of Quantum Optics, Ludwig-Maximilians-Universität, the Institut für Strahlwerkzeuge of Universität Stuttgart, and the University of Coimbra, Portugal. The team is now attempting to explain the discrepancy, and re-examining the results of both previous high-precision measurements and complex calculations involving scattering cross section. If no errors are found in the measurements or calculations, it could be necessary to re-examine the world's most precise and best-tested fundamental theory: quantum electrodynamics. The proton radius remains a puzzle as of 2017. Perhaps the discrepancy is due to new physics, or the explanation may be an ordinary physics effect that has been missed.
The radius is linked to the form factor and momentum transfer cross section. The atomic form factor G modifies the cross section corresponding to point-like proton.
The atomic form factor is related to the wave function density of the target:
The form factor can be split in electric and magnetic form factors. These can be further written as linear combinations of Dirac and Pauli form factors.
Since the proton is composed of quarks confined by gluons, an equivalent pressure which acts on the quarks can be defined. This allows calculation of their distribution as a function of distance from the centre using Compton scattering of high-energy electrons (DVCS, for deeply virtual Compton scattering). The pressure is maximum at the centre, about 1035 Pa which is greater than the pressure inside a neutron star. It is positive (repulsive) to a radial distance of about 0.6 fm, negative (attractive) at greater distances, and very weak beyond about 2 fm.
Although protons have affinity for oppositely charged electrons, this is a relatively low-energy interaction and so free protons must lose sufficient velocity (and kinetic energy) in order to become closely associated and bound to electrons. High energy protons, in traversing ordinary matter, lose energy by collisions with atomic nuclei, and by ionization of atoms (removing electrons) until they are slowed sufficiently to be captured by the electron cloud in a normal atom.
However, in such an association with an electron, the character of the bound proton is not changed, and it remains a proton. The attraction of low-energy free protons to any electrons present in normal matter (such as the electrons in normal atoms) causes free protons to stop and to form a new chemical bond with an atom. Such a bond happens at any sufficiently "cold" temperature (i.e., comparable to temperatures at the surface of the Sun) and with any type of atom. Thus, in interaction with any type of normal (non-plasma) matter, low-velocity free protons are attracted to electrons in any atom or molecule with which they come in contact, causing the proton and molecule to combine. Such molecules are then said to be "protonated", and chemically they often, as a result, become so-called Brønsted acids.
In chemistry, the number of protons in the nucleus of an atom is known as the atomic number, which determines the chemical element to which the atom belongs. For example, the atomic number of chlorine is 17; this means that each chlorine atom has 17 protons and that all atoms with 17 protons are chlorine atoms. The chemical properties of each atom are determined by the number of (negatively charged) electrons, which for neutral atoms is equal to the number of (positive) protons so that the total charge is zero. For example, a neutral chlorine atom has 17 protons and 17 electrons, whereas a Cl− anion has 17 protons and 18 electrons for a total charge of −1.
All atoms of a given element are not necessarily identical, however, as the number of neutrons may vary to form different isotopes, and energy levels may differ forming different nuclear isomers. For example, there are two stable isotopes of chlorine: 35
with 35 − 17 = 18 neutrons and 37
with 37 − 17 = 20 neutrons.
In chemistry, the term proton refers to the hydrogen ion, H+
. Since the atomic number of hydrogen is 1, a hydrogen ion has no electrons and corresponds to a bare nucleus, consisting of a proton (and 0 neutrons for the most abundant isotope protium 1
). The proton is a "bare charge" with only about 1/64,000 of the radius of a hydrogen atom, and so is extremely reactive chemically. The free proton, thus, has an extremely short lifetime in chemical systems such as liquids and it reacts immediately with the electron cloud of any available molecule. In aqueous solution, it forms the hydronium ion, H3O+, which in turn is further solvated by water molecules in clusters such as [H5O2]+ and [H9O4]+.
The transfer of H+
in an acid–base reaction is usually referred to as "proton transfer". The acid is referred to as a proton donor and the base as a proton acceptor. Likewise, biochemical terms such as proton pump and proton channel refer to the movement of hydrated H+
Also in chemistry, the term "proton NMR" refers to the observation of hydrogen-1 nuclei in (mostly organic) molecules by nuclear magnetic resonance. This method uses the spin of the proton, which has the value one-half. The name refers to examination of protons as they occur in protium (hydrogen-1 atoms) in compounds, and does not imply that free protons exist in the compound being studied.
Because the Solar Wind Spectrometer made continuous measurements, it was possible to measure how the Earth's magnetic field affects arriving solar wind particles. For about two-thirds of each orbit, the Moon is outside of the Earth's magnetic field. At these times, a typical proton density was 10 to 20 per cubic centimeter, with most protons having velocities between 400 and 650 kilometers per second. For about five days of each month, the Moon is inside the Earth's geomagnetic tail, and typically no solar wind particles were detectable. For the remainder of each lunar orbit, the Moon is in a transitional region known as the magnetosheath, where the Earth's magnetic field affects the solar wind but does not completely exclude it. In this region, the particle flux is reduced, with typical proton velocities of 250 to 450 kilometers per second. During the lunar night, the spectrometer was shielded from the solar wind by the Moon and no solar wind particles were measured.
Protons also have extrasolar origin from galactic cosmic rays, where they make up about 90% of the total particle flux. These protons often have higher energy than solar wind protons, and their intensity is far more uniform and less variable than protons coming from the Sun, the production of which is heavily affected by solar proton events such as coronal mass ejections.
Research has been performed on the dose-rate effects of protons, as typically found in space travel, on human health. To be more specific, there are hopes to identify what specific chromosomes are damaged, and to define the damage, during cancer development from proton exposure. Another study looks into determining "the effects of exposure to proton irradiation on neurochemical and behavioral endpoints, including dopaminergic functioning, amphetamine-induced conditioned taste aversion learning, and spatial learning and memory as measured by the Morris water maze. Electrical charging of a spacecraft due to interplanetary proton bombardment has also been proposed for study. There are many more studies that pertain to space travel, including galactic cosmic rays and their possible health effects, and solar proton event exposure.
CPT-symmetry puts strong constraints on the relative properties of particles and antiparticles and, therefore, is open to stringent tests. For example, the charges of a proton and antiproton must sum to exactly zero. This equality has been tested to one part in 108. The equality of their masses has also been tested to better than one part in 108. By holding antiprotons in a Penning trap, the equality of the charge-to-mass ratio of protons and antiprotons has been tested to one part in 6×109. The magnetic moment of antiprotons has been measured with error of 8×10−3 nuclear Bohr magnetons, and is found to be equal and opposite to that of a proton.
2014 CODATA recommended values
An acid is a molecule or ion capable of donating a hydron (proton or hydrogen ion H+), or, alternatively, capable of forming a covalent bond with an electron pair (a Lewis acid).The first category of acids is the proton donors or Brønsted acids. In the special case of aqueous solutions, proton donors form the hydronium ion H3O+ and are known as Arrhenius acids. Brønsted and Lowry generalized the Arrhenius theory to include non-aqueous solvents. A Brønsted or Arrhenius acid usually contains a hydrogen atom bonded to a chemical structure that is still energetically favorable after loss of H+.
Aqueous Arrhenius acids have characteristic properties which provide a practical description of an acid. Acids form aqueous solutions with a sour taste, can turn blue litmus red, and react with bases and certain metals (like calcium) to form salts. The word acid is derived from the Latin acidus/acēre meaning sour. An aqueous solution of an acid has a pH less than 7 and is colloquially also referred to as 'acid' (as in 'dissolved in acid'), while the strict definition refers only to the solute. A lower pH means a higher acidity, and thus a higher concentration of positive hydrogen ions in the solution. Chemicals or substances having the property of an acid are said to be acidic.
Common aqueous acids include hydrochloric acid (a solution of hydrogen chloride which is found in gastric acid in the stomach and activates digestive enzymes), acetic acid (vinegar is a dilute aqueous solution of this liquid), sulfuric acid (used in car batteries), and citric acid (found in citrus fruits). As these examples show, acids (in the colloquial sense) can be solutions or pure substances, and can be derived from acids (in the strict sense) that are solids, liquids, or gases. Strong acids and some concentrated weak acids are corrosive, but there are exceptions such as carboranes and boric acid.
The second category of acids are Lewis acids, which form a covalent bond with an electron pair. An example is boron trifluoride (BF3), whose boron atom has a vacant orbital which can form a covalent bond by sharing a lone pair of electrons on an atom in a base, for example the nitrogen atom in ammonia (NH3). Lewis considered this as a generalization of the Brønsted definition, so that an acid is a chemical species that accepts electron pairs either directly or by releasing protons (H+) into the solution, which then accept electron pairs. However, hydrogen chloride, acetic acid, and most other Brønsted-Lowry acids cannot form a covalent bond with an electron pair and are therefore not Lewis acids. Conversely, many Lewis acids are not Arrhenius or Brønsted-Lowry acids. In modern terminology, an acid is implicitly a Brønsted acid and not a Lewis acid, since chemists almost always refer to a Lewis acid explicitly as a Lewis acid.Antiproton
, (pronounced p-bar) is the antiparticle of the proton. Antiprotons are stable, but they are typically short-lived, since any collision with a proton will cause both particles to be annihilated in a burst of energy.
The existence of the antiproton with −1 electric charge, opposite to the +1 electric charge of the proton, was predicted by Paul Dirac in his 1933 Nobel Prize lecture. Dirac received the Nobel Prize for his previous 1928 publication of his Dirac equation that predicted the existence of positive and negative solutions to the Energy Equation () of Einstein and the existence of the positron, the antimatter analog to the electron, with positive charge and opposite spin.
The antiproton was first experimentally confirmed in 1955 at the Bevatron particle accelerator by University of California, Berkeley physicists Emilio Segrè and Owen Chamberlain, for which they were awarded the 1959 Nobel Prize in Physics. In terms of valence quarks, an antiproton consists of two up antiquarks and one down antiquark (uud). The properties of the antiproton that have been measured all match the corresponding properties of the proton, with the exception that the antiproton has electric charge and magnetic moment that are the opposites of those in the proton. The questions of how matter is different from antimatter, and the relevance of antimatter in explaining how our universe survived the Big Bang, remain open problems—open, in part, due to the relative scarcity of antimatter in today's universe.Atomic number
The atomic number or proton number (symbol Z) of a chemical element is the number of protons found in the nucleus of an atom. It is identical to the charge number of the nucleus. The atomic number uniquely identifies a chemical element. In an uncharged atom, the atomic number is also equal to the number of electrons.
The sum of the atomic number Z and the number of neutrons, N, gives the mass number A of an atom. Since protons and neutrons have approximately the same mass (and the mass of the electrons is negligible for many purposes) and the mass defect of nucleon binding is always small compared to the nucleon mass, the atomic mass of any atom, when expressed in unified atomic mass units (making a quantity called the "relative isotopic mass"), is within 1% of the whole number A.
Atoms with the same atomic number Z but different neutron numbers N, and hence different atomic masses, are known as isotopes. A little more than three-quarters of naturally occurring elements exist as a mixture of isotopes (see monoisotopic elements), and the average isotopic mass of an isotopic mixture for an element (called the relative atomic mass) in a defined environment on Earth, determines the element's standard atomic weight. Historically, it was these atomic weights of elements (in comparison to hydrogen) that were the quantities measurable by chemists in the 19th century.
The conventional symbol Z comes from the German word Zahl meaning number, which, before the modern synthesis of ideas from chemistry and physics, merely denoted an element's numerical place in the periodic table, whose order is approximately, but not completely, consistent with the order of the elements by atomic weights. Only after 1915, with the suggestion and evidence that this Z number was also the nuclear charge and a physical characteristic of atoms, did the word Atomzahl (and its English equivalent atomic number) come into common use in this context.Base (chemistry)
In chemistry, bases are substances that, in aqueous solution, release hydroxide (OH−) ions, are slippery to the touch, can taste bitter if an alkali, change the color of indicators (e.g., turn red litmus paper blue), react with acids to form salts, promote certain chemical reactions (base catalysis), accept protons from any proton donor or contain completely or partially displaceable OH− ions. Examples of bases are the hydroxides of the alkali metals and the alkaline earth metals (NaOH, Ca(OH)2, etc.—see alkali hydroxide and alkaline earth hydroxide).
These particular substances produce hydroxide ions (OH−) in aqueous solutions, and are thus classified as Arrhenius bases.
For a substance to be classified as an Arrhenius base, it must produce hydroxide ions in an aqueous solution. Arrhenius believed that in order to do so, the base must contain hydroxide in the formula. This makes the Arrhenius model limited, as it cannot explain the basic properties of aqueous solutions of ammonia (NH3) or its organic derivatives (amines). There are also bases that do not contain a hydroxide ion but nevertheless react with water, resulting in an increase in the concentration of the hydroxide ion. An example of this is the reaction between ammonia and water to produce ammonium and hydroxide. In this reaction ammonia is the base because it accepts a proton from the water molecule. Ammonia and other bases similar to it usually have the ability to form a bond with a proton due to the unshared pair of electrons that they possess. In the more general Brønsted–Lowry acid–base theory, a base is a substance that can accept hydrogen cations (H+)—otherwise known as protons. In the Lewis model, a base is an electron pair donor.In water, by altering the autoionization equilibrium, bases yield solutions in which the hydrogen ion activity is lower than it is in pure water, i.e., the water has a pH higher than 7.0 at standard conditions. A soluble base is called an alkali if it contains and releases OH− ions quantitatively. However, it is important to realize that basicity is not the same as alkalinity. Metal oxides, hydroxides, and especially alkoxides are basic, and conjugate bases of weak acids are weak bases.
Bases can be thought of as the chemical opposite of acids. However, some strong acids are able to act as bases. Bases and acids are seen as opposites because the effect of an acid is to increase the hydronium (H3O+) concentration in water, whereas bases reduce this concentration. A reaction between an acid and a base is called neutralization. In a neutralization reaction, an aqueous solution of a base reacts with an aqueous solution of an acid to produce a solution of water and salt in which the salt separates into its component ions. If the aqueous solution is saturated with a given salt solute, any additional such salt precipitates out of the solution.
The notion of a base as a concept in chemistry was first introduced by the French chemist Guillaume François Rouelle in 1754. He noted that acids, which at that time were mostly volatile liquids (like acetic acid), turned into solid salts only when combined with specific substances. Rouelle considered that such a substance serves as a "base" for the salt, giving the salt a "concrete or solid form".Beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta ray (fast energetic electron or positron) is emitted from an atomic nucleus. For example, beta decay of a neutron transforms it into a proton by the emission of an electron accompanied by an antineutrino, or conversely a proton is converted into a neutron by the emission of a positron (positron emission) with a neutrino, thus changing the nuclide type. Neither the beta particle nor its associated (anti-)neutrino exist within the nucleus prior to beta decay, but are created in the decay process. By this process, unstable atoms obtain a more stable ratio of protons to neutrons. The probability of a nuclide decaying due to beta and other forms of decay is determined by its nuclear binding energy. The binding energies of all existing nuclides form what is called the nuclear band or valley of stability. For either electron or positron emission to be energetically possible, the energy release (see below) or Q value must be positive.
Beta decay is a consequence of the weak force, which is characterized by relatively lengthy decay times. Nucleons are composed of up quarks and down quarks, and the weak force allows a quark to change type by the exchange of a W boson and the creation of an electron/antineutrino or positron/neutrino pair. For example, a neutron, composed of two down quarks and an up quark, decays to a proton composed of a down quark and two up quarks. Decay times for many nuclides that are subject to beta decay can be thousands of years.
Electron capture is sometimes included as a type of beta decay, because the basic nuclear process, mediated by the weak force, is the same. In electron capture, an inner atomic electron is captured by a proton in the nucleus, transforming it into a neutron, and an electron neutrino is released.Briz (rocket stage)
The Briz-K, Briz-KM and Briz-M (Russian: Бриз-К, КM and M meaning Breeze-K, KM and M) are Russian liquid-propellant rocket orbit insertion upper stages manufactured by Khrunichev State Research and Production Space Center and used on the Proton-M, Angara A5 or Rokot, one of Russia's smaller launchers.Electron transport chain
An electron transport chain (ETC) is a series of complexes that transfer electrons from electron donors to electron acceptors via redox (both reduction and oxidation occurring simultaneously) reactions, and couples this electron transfer with the transfer of protons (H+ ions) across a membrane. This creates an electrochemical proton gradient that drives the synthesis of adenosine triphosphate (ATP), a molecule that stores energy chemically in the form of highly strained bonds. The molecules of the chain include peptides, enzymes (which are proteins or protein complexes), and others. The final acceptor of electrons in the electron transport chain during aerobic respiration is molecular oxygen although a variety of acceptors other than oxygen such as sulfate exist in anaerobic respiration.
Electron transport chains are used for extracting energy via redox reactions from sunlight in photosynthesis or, such as in the case of the oxidation of sugars, cellular respiration. In eukaryotes, an important electron transport chain is found in the inner mitochondrial membrane where it serves as the site of oxidative phosphorylation through the action of ATP synthase. It is also found in the thylakoid membrane of the chloroplast in photosynthetic eukaryotes. In bacteria, the electron transport chain is located in their cell membrane.
In chloroplasts, light drives the conversion of water to oxygen and NADP+ to NADPH with transfer of H+ ions across chloroplast membranes. In mitochondria, it is the conversion of oxygen to water, NADH to NAD+ and succinate to fumarate that are required to generate the proton gradient.
Electron transport chains are major sites of premature electron leakage to oxygen, generating superoxide and potentially resulting in increased oxidative stress.
The electron transport chain consists of a spatially separated series of redox reactions in which electrons are transferred from a donor molecule to an acceptor molecule. The underlying force driving these reactions is the Gibbs free energy of the reactants and products. The Gibbs free energy is the energy available ("free") to do work. Any reaction that decreases the overall Gibbs free energy of a system is thermodynamically spontaneous.
The function of the electron transport chain is to produce a transmembrane proton electrochemical gradient as a result of the redox reactions. If protons flow back through the membrane, they enable mechanical work, such as rotating bacterial flagella. ATP synthase, an enzyme highly conserved among all domains of life, converts this mechanical work into chemical energy by producing ATP, which powers most cellular reactions.
A small amount of ATP is available from substrate-level phosphorylation, for example, in glycolysis. In most organisms the majority of ATP is generated in electron transport chains.Large Hadron Collider
The Large Hadron Collider (LHC) is the world's largest and most powerful particle collider and the largest machine in the world. It was built by the European Organization for Nuclear Research (CERN) between 1998 and 2008 in collaboration with over 10,000 scientists and hundreds of universities and laboratories, as well as more than 100 countries. It lies in a tunnel 27 kilometres (17 mi) in circumference and as deep as 175 metres (574 ft) beneath the France–Switzerland border near Geneva.
First collisions were achieved in 2010 at an energy of 3.5 teraelectronvolts (TeV) per beam, about four times the previous world record. After upgrades it reached 6.5 TeV per beam (13 TeV total collision energy, the present world record). At the end of 2018, it entered a two-year shutdown period for further upgrades.
The collider has four crossing points, around which are positioned seven detectors, each designed for certain kinds of research. The LHC primarily collides proton beams, but it can also use beams of heavy ions: Lead–lead collisions and proton-lead collisions are typically done for one month per year. The aim of the LHC's detectors is to allow physicists to test the predictions of different theories of particle physics, including measuring the properties of the Higgs boson and searching for the large family of new particles predicted by supersymmetric theories, as well as other unsolved questions of physics.Neutron
The neutron is a subatomic particle, symbol n or n0, with no net electric charge and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behave similarly within the nucleus, and each has a mass of approximately one atomic mass unit, they are both referred to as nucleons. Their properties and interactions are described by nuclear physics.
The chemical and nuclear properties of the nucleus are determined by the number of protons, called the atomic number, and the number of neutrons, called the neutron number. The atomic mass number is the total number of nucleons. For example, carbon has atomic number 6, and its abundant carbon-12 isotope has 6 neutrons, whereas its rare carbon-13 isotope has 7 neutrons. Some elements occur in nature with only one stable isotope, such as fluorine. Other elements occur with many stable isotopes, such as tin with ten stable isotopes.
Within the nucleus, protons and neutrons are bound together through the nuclear force. Neutrons are required for the stability of nuclei, with the exception of the single-proton hydrogen atom. Neutrons are produced copiously in nuclear fission and fusion. They are a primary contributor to the nucleosynthesis of chemical elements within stars through fission, fusion, and neutron capture processes.
The neutron is essential to the production of nuclear power. In the decade after the neutron was discovered by James Chadwick in 1932, neutrons were used to induce many different types of nuclear transmutations. With the discovery of nuclear fission in 1938, it was quickly realized that, if a fission event produced neutrons, each of these neutrons might cause further fission events, in a cascade known as a nuclear chain reaction. These events and findings led to the first self-sustaining nuclear reactor (Chicago Pile-1, 1942) and the first nuclear weapon (Trinity, 1945).
Free neutrons, while not directly ionizing atoms, cause ionizing radiation. As such they can be a biological hazard, depending upon dose. A small natural "neutron background" flux of free neutrons exists on Earth, caused by cosmic ray showers, and by the natural radioactivity of spontaneously fissionable elements in the Earth's crust. Dedicated neutron sources like neutron generators, research reactors and spallation sources produce free neutrons for use in irradiation and in neutron scattering experiments.Nuclear magnetic resonance spectroscopy
Nuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic technique to observe local magnetic fields around atomic nuclei. The sample is placed in a magnetic field and the NMR signal is produced by excitation of the nuclei sample with radio waves into nuclear magnetic resonance, which is detected with sensitive radio receivers. The intramolecular magnetic field around an atom in a molecule changes the resonance frequency, thus giving access to details of the electronic structure of a molecule and its individual functional groups. As the fields are unique or highly characteristic to individual compounds, in modern organic chemistry practice, NMR spectroscopy is the definitive method to identify monomolecular organic compounds. Similarly, biochemists use NMR to identify proteins and other complex molecules. Besides identification, NMR spectroscopy provides detailed information about the structure, dynamics, reaction state, and chemical environment of molecules. The most common types of NMR are proton and carbon-13 NMR spectroscopy, but it is applicable to any kind of sample that contains nuclei possessing spin.
NMR spectra are unique, well-resolved, analytically tractable and often highly predictable for small molecules. Different functional groups are obviously distinguishable, and identical functional groups with differing neighboring substituents still give distinguishable signals. NMR has largely replaced traditional wet chemistry tests such as color reagents or typical chromatography for identification. A disadvantage is that a relatively large amount, 2–50 mg, of a purified substance is required, although it may be recovered through a workup. Preferably, the sample should be dissolved in a solvent, because NMR analysis of solids requires a dedicated magic angle spinning machine and may not give equally well-resolved spectra. The timescale of NMR is relatively long, and thus it is not suitable for observing fast phenomena, producing only an averaged spectrum. Although large amounts of impurities do show on an NMR spectrum, better methods exist for detecting impurities, as NMR is inherently not very sensitive - though at higher frequencies, sensitivity is higher.
Correlation spectroscopy is a development of ordinary NMR. In two-dimensional NMR, the emission is centered around a single frequency, and correlated resonances are observed. This allows identifying the neighboring substituents of the observed functional group, allowing unambiguous identification of the resonances. There are also more complex 3D and 4D methods and a variety of methods designed to suppress or amplify particular types of resonances. In nuclear Overhauser effect (NOE) spectroscopy, the relaxation of the resonances is observed. As NOE depends on the proximity of the nuclei, quantifying the NOE for each nucleus allows for construction of a three-dimensional model of the molecule.
NMR spectrometers are relatively expensive; universities usually have them, but they are less common in private companies. Modern NMR spectrometers have a very strong, large and expensive liquid helium-cooled superconducting magnet, because resolution directly depends on magnetic field strength. Less expensive machines using permanent magnets and lower resolution are also available, which still give sufficient performance for certain application such as reaction monitoring and quick checking of samples. There are even benchtop nuclear magnetic resonance spectrometers. NMR can be observed in magnetic fields less than a millitesla. Low-resolution NMR produces broader peaks which can easily overlap one another causing issues in resolving complex structures. The use of higher strength magnetic fields result in clear resolution of the peaks and is the standard in industry.Omeprazole
Omeprazole, sold under the brand names Prilosec and Losec among others, is a medication used in the treatment of gastroesophageal reflux disease, peptic ulcer disease, and Zollinger–Ellison syndrome. It is also used to prevent upper gastrointestinal bleeding in people who are at high risk. Omeprazole is a proton-pump inhibitor (PPI) and its effectiveness is similar to other PPIs. It can be taken by mouth or by injection into a vein.Common side effects include nausea, vomiting, headaches, and increased intestinal gas. Serious side effects may include Clostridium difficile colitis, an increased risk of pneumonia, an increased risk of bone fractures, and the potential of masking stomach cancer. It is unclear if it is safe for use in pregnancy. It works by blocking the release of stomach acid.Omeprazole was patented in 1978 and approved for medical use in 1988. It is on the World Health Organization's List of Essential Medicines, which lists the most effective and safe medicines needed in a health system. It is available as a generic medication. The wholesale cost in the developing world as of 2014 is US$0.01 to US$0.07 per dose. In the United States, it costs on average US$0.50 per pill. In 2016, it was the seventh most prescribed medication in the United States, with more than 70 million prescriptions.PROTON Holdings
PROTON Holdings Berhad (PHB; informally Proton) is a Malaysian automotive company and automobile corporation active in automobile design, manufacturing, distribution and sales. Proton was established in 1983 as Malaysia's sole national badged car company until the advent of Perodua in 1993. The company is headquartered in Shah Alam, Selangor, and operates additional facilities at Proton City, Perak. 'Proton' is a Bahasa Malaysia acronym for Perusahaan Otomobil Nasional (National Automobile Company).
Proton was originally a manufacturer of rebadged Mitsubishi Motors (MMC) products in the 1980s and 1990s. Proton produced its first indigenously designed (though Mitsubishi-engined), non-badge engineered car in the year 2000, and elevated Malaysia as the 11th country in the world with the capability to design cars from the ground up. Since the 2000s, Proton has produced a mix of locally engineered and badge engineered vehicles. Proton cars are currently sold in at least 15 countries, the majority of which are in Asia.
Proton was originally owned in majority by HICOM, with minority stakes being held by Mitsubishi Group members. By 2005, Mitsubishi had divested their stake in Proton to Khazanah Nasional, and in 2012, Proton was fully acquired by DRB-HICOM.
Proton has been the owner of Lotus Cars since 1996. In May 2017, DRB-HICOM announced plans to sell a 49.9% stake in Proton and a 51% stake in Lotus to Geely Automobile Holdings. The deal was signed in June 2017, and since then, Lotus ceased to be a unit of Proton.On 29 September 2017, DRB-HICOM announced changes to the board of PROTON Holdings Berhad. Following the signing of a Definitive Agreement with China's Zejiang Geely Holding Group Limited on 23 June 2017, the Chinese carmaker acquired 49.9% equity in Proton. The announcement on 29 September saw a new board of directors put in place in PROTON Holdings, Proton Edar (the local distribution arm) and Perusahaan Otomobil Nasional Sdn Bhd (PONSB).
Three nominees from Geely Holding joined the boards; Daniel Donghui Li, the Executive VP and CFO of Geely Holding; Dr Nathan Yuning, the Executive VP of International Business of Geely Holding, and Feng Qing Feng, the Group VP and CTO at HK-listed Geely Auto. DRB-HICOM are represented by Dato' Sri Syed Faisal Albar, who chairs the boards, and Amalanathan Thomas and Shaharul Farez Hassan. Both are part of the senior management team at DRB-HICOM.
Also named on the same day was Dr Li Chunrong, who joins PONSB as CEO. Dr Li is the third foreigner to head Proton. Between 188 and 1993, the early years of Proton, two different Japanese nominees of their-then partners, Mitsubishi Motors Corporation, helmed the carmaker.
Proton, predominantly reliant on its domestic market, is presently undergoing a transformation process as part of a long-term turnaround plan, with hopes of returning to profitability and regaining an international presence.
Proton's tie up with Geely is expected to put the company back on track with the introduction of the much-awaited SUV named Boyue touted to go on sale by end of 2018.Proton-K
The Proton-K, also designated Proton 8K82K after its GRAU index, 8K82K, was a Russian, previously Soviet, carrier rocket derived from the earlier Proton. It was built by Khrunichev, and launched from sites 81 and 200 at the Baikonur Cosmodrome in Kazakhstan.
The maiden flight on 10 March 1967 carried a Soyuz 7K-L1 as part of the Zond program. During the so-called "Moon Race" these Proton/Soyuz/Zond flights consisted of several uncrewed test flights of Soyuz spacecraft to highly elliptical or circumlunar orbits with the unrealized aim of landing Soviet cosmonauts on the Moon.
It was retired from service in favour of the modernised Proton-M, making its 311th and final launch on 30 March 2012.Proton-M
The Proton-M, (Протон-М) GRAU index 8K82M or 8K82KM, is a Russian heavy-lift launch vehicle derived from the Soviet-developed Proton. It is built by Khrunichev, and launched from sites 81 and 200 at the Baikonur Cosmodrome in Kazakhstan. Commercial launches are marketed by International Launch Services (ILS), and generally use Site 200/39. The first Proton-M launch occurred on 7 April 2001.Proton-pump inhibitor
Proton-pump inhibitors (PPIs) are a group of drugs whose main action is a pronounced and long-lasting reduction of stomach acid production. Within the class of medications, there is no clear evidence that one agent works better than another.They are the most potent inhibitors of acid secretion available. This group of drugs followed and largely superseded another group of medications with similar effects, but a different mode of action, called H2-receptor antagonists.
PPIs are among the most widely sold drugs in the world, and the first one, omeprazole, is on the WHO Model List of Essential Medicines. The cost between different agents varies significantly.Proton (rocket family)
Proton (Russian: Протон) (formal designation: UR-500) is an expendable launch system used for both commercial and Russian government space launches. The first Proton rocket was launched in 1965. Modern versions of the launch system are still in use as of 2019, making it one of the most successful heavy boosters in the history of spaceflight. All Protons are built at the Khrunichev State Research and Production Space Center factory in Moscow, transported to the Baikonur Cosmodrome, brought to the launch pad horizontally, and raised into vertical position for launch.As with many Soviet rockets, the names of recurring payloads became associated with the Proton. The moniker "Proton" originates from a series of similarly named scientific satellites, which were among the rocket's first payloads. During the Cold War, it was designated the D-1/D-1e or SL-12/SL-13 by Western intelligence agencies.
Launch capacity to low Earth orbit is about 22.8 tonnes (50,000 lb). Geostationary transfer capacity is about 6.3 tonnes (14,000 lb). Commercial launches are marketed by International Launch Services (ILS).
The rocket is intended to be retired before 2030.As of June 2018, production on the Proton rocket is ceasing as the new Angara launch vehicle comes on line and becomes operational. No new launch service contracts for Proton are likely to be signed.Proton nuclear magnetic resonance
Proton nuclear magnetic resonance (proton NMR, hydrogen-1 NMR, or 1H NMR) is the application of nuclear magnetic resonance in NMR spectroscopy with respect to hydrogen-1 nuclei within the molecules of a substance, in order to determine the structure of its molecules. In samples where natural hydrogen (H) is used, practically all the hydrogen consists of the isotope 1H (hydrogen-1; i.e. having a proton for a nucleus).
Simple NMR spectra are recorded in solution, and solvent protons must not be allowed to interfere. Deuterated (deuterium = 2H, often symbolized as D) solvents especially for use in NMR are preferred, e.g. deuterated water, D2O, deuterated acetone, (CD3)2CO, deuterated methanol, CD3OD, deuterated dimethyl sulfoxide, (CD3)2SO, and deuterated chloroform, CDCl3. However, a solvent without hydrogen, such as carbon tetrachloride, CCl4 or carbon disulfide, CS2, may also be used.
Historically, deuterated solvents were supplied with a small amount (typically 0.1%) of tetramethylsilane (TMS) as an internal standard for calibrating the chemical shifts of each analyte proton. TMS is a tetrahedral molecule, with all protons being chemically equivalent, giving one single signal, used to define a chemical shift = 0 ppm. It is volatile, making sample recovery easy as well. Modern spectrometers are able to reference spectra based on the residual proton in the solvent (e.g. the CHCl3, 0.01% in 99.99% CDCl3). Deuterated solvents are now commonly supplied without TMS.
Deuterated solvents permit the use of deuterium frequency-field lock (also known as deuterium lock or field lock) to offset the effect of the natural drift of the NMR's magnetic field . In order to provide deuterium lock, the NMR constantly monitors the deuterium signal resonance frequency from the solvent and makes changes to the to keep the resonance frequency constant. Additionally, the deuterium signal may be used to accurately define 0 ppm as the resonant frequency of the lock solvent and the difference between the lock solvent and 0 ppm (TMS) are well known.
Proton NMR spectra of most organic compounds are characterized by chemical shifts in the range +14 to -4 ppm and by spin-spin coupling between protons. The integration curve for each proton reflects the abundance of the individual protons.
Simple molecules have simple spectra. The spectrum of ethyl chloride consists of a triplet at 1.5 ppm and a quartet at 3.5 ppm in a 3:2 ratio. The spectrum of benzene consists of a single peak at 7.2 ppm due to the diamagnetic ring current.
Together with carbon-13 NMR, proton NMR is a powerful tool for molecular structure characterization.Proton therapy
In the field of medical procedures, proton therapy, or proton radiotherapy, is a type of particle therapy that uses a beam of protons to irradiate diseased tissue, most often in the treatment of cancer. The chief advantage of proton therapy over other types of external beam radiotherapy is that as a charged particle the dose is deposited over a narrow range of depth, and there is minimal entry, exit, or scattered radiation dose.Proton–proton chain reaction
The proton–proton chain reaction is one of two known sets of nuclear fusion reactions by which stars convert hydrogen to helium. It dominates in stars with masses less than or equal to that of the Sun's, whereas the CNO cycle, the other known reaction, is suggested by theoretical models to dominate in stars with masses greater than about 1.3 times that of the Sun's.In general, proton–proton fusion can occur only if the kinetic energy (i.e. temperature) of the protons is high enough to overcome their mutual electrostatic or Coulomb repulsion.In the Sun, deuterium-producing events are rare. Diprotons are the much more common result of proton–proton reactions within the star, and diprotons almost immediately decay back into two protons. Since the conversion of hydrogen to helium is slow, the complete conversion of the hydrogen in the core of the Sun is calculated to take more than ten billion years.Although often called the "proton-proton chain reaction", it is not a chain reaction in the normal sense of the word (at least not Branch I — in Branches II and III helium, which is the product, also serves as a catalyst). It does not produce particles that go on to induce the reaction to continue (such as neutrons given off during fission). In fact, the rate is self-limiting because the heat produced tends toward reducing the density. It is however a chain (like a decay chain) and a reaction, or more accurately a branched chain of reactions starting with two protons coming together and yielding deuterium.