Promethium is a chemical element with symbol Pm and atomic number 61. All of its isotopes are radioactive; it is extremely rare, with only about 500-600 grams naturally occurring in Earth's crust at any given time, and one of only two such elements that are followed in the periodic table by elements with stable forms, a distinction shared with technetium. Chemically, promethium is a lanthanide. Promethium shows only one stable oxidation state of +3.
In 1902 Bohuslav Brauner suggested that there was a then-unknown element with properties intermediate between those of the known elements neodymium (60) and samarium (62); this was confirmed in 1914 by Henry Moseley who, having measured the atomic numbers of all the elements then known, found that atomic number 61 was missing. In 1926, two groups (one Italian and one American) claimed to have isolated a sample of element 61; both "discoveries" were soon proven to be false. In 1938, during a nuclear experiment conducted at Ohio State University, a few radioactive nuclides were produced that certainly were not radioisotopes of neodymium or samarium, but there was a lack of chemical proof that element 61 was produced, and the discovery was not generally recognized. Promethium was first produced and characterized at Oak Ridge National Laboratory in 1945 by the separation and analysis of the fission products of uranium fuel irradiated in a graphite reactor. The discoverers proposed the name "prometheum" (the spelling was subsequently changed), derived from Prometheus, the Titan in Greek mythology who stole fire from Mount Olympus and brought it down to humans, to symbolize "both the daring and the possible misuse of mankind's intellect". However, a sample of the metal was made only in 1963.
There are two possible sources for natural promethium: rare decays of natural europium-151 (producing promethium-147), and uranium (various isotopes). Practical applications exist only for chemical compounds of promethium-147, which are used in luminous paint, atomic batteries and thickness measurement devices, even though promethium-145 is the most stable promethium isotope. Because natural promethium is exceedingly scarce, it is typically synthesized by bombarding uranium-235 (enriched uranium) with thermal neutrons to produce promethium-147 as a fission product.
|Mass number||145 (most stable isotope)|
|Promethium in the periodic table|
|Atomic number (Z)||61|
|Electron configuration||[Xe] 4f5 6s2|
Electrons per shell
|2, 8, 18, 23, 8, 2|
|Phase at STP||solid|
|Melting point||1315 K (1042 °C, 1908 °F)|
|Boiling point||3273 K (3000 °C, 5432 °F)|
|Density (near r.t.)||7.26 g/cm3|
|Heat of fusion||7.13 kJ/mol|
|Heat of vaporization||289 kJ/mol|
|Oxidation states||+2, +3 (a mildly basic oxide)|
|Electronegativity||Pauling scale: 1.13 (?)|
|Atomic radius||empirical: 183 pm|
|Covalent radius||199 pm|
Spectral lines of promethium
|Natural occurrence||from decay|
|Crystal structure|| double hexagonal close-packed (dhcp)|
|Thermal expansion||9.0 µm/(m·K) (at r.t.)|
|Thermal conductivity||17.9 W/(m·K)|
|Electrical resistivity||est. 0.75 µΩ·m (at r.t.)|
|Young's modulus||α form: est. 46 GPa|
|Shear modulus||α form: est. 18 GPa|
|Bulk modulus||α form: est. 33 GPa|
|Poisson ratio||α form: est. 0.28|
|Discovery||Chien Shiung Wu, Emilio Segrè, Hans Bethe (1942)|
|First isolation||Charles D. Coryell, Jacob A. Marinsky, Lawrence E. Glendenin (1945)|
|Named by||Grace Mary Coryell (1945)|
|Main isotopes of promethium|
A promethium atom has 61 electrons, arranged in the configuration [Xe]4f56s2. In forming compounds, the atom loses its two outermost electrons and one of the 4f-electrons, which belongs to an open subshell. The element's atomic radius is the second largest among all the lanthanides but is only slightly greater than those of the neighboring elements. It is the most notable exception to the general trend of the contraction of lanthanide atoms with the increase of their atomic numbers (see lanthanide contraction). Many properties of promethium rely on its position among lanthanides and are intermediate between those of neodymium and samarium. For example, the melting point, the first three ionization energies, and the hydration energy are greater than those of neodymium and lower than those of samarium; similarly, the estimate for the boiling point, ionic (Pm3+) radius, and standard heat of formation of monatomic gas are greater than those of samarium and less than those of neodymium.
Promethium has a double hexagonal close packed (dhcp) structure and a hardness of 63 kg/mm2. This low-temperature alpha form converts into a beta, body-centered cubic (bcc) phase upon heating to 890 °C.
Promethium belongs to the cerium group of lanthanides and is chemically very similar to the neighboring elements. Because of its instability, chemical studies of promethium are incomplete. Even though a few compounds have been synthesized, they are not fully studied; in general, they tend to be pink or red in color. Treatment of acidic solutions containing Pm3+ ions with ammonia results in a gelatinous light-brown sediment of hydroxide, Pm(OH)3, which is insoluble in water. When dissolved in hydrochloric acid, a water-soluble yellow salt, PmCl3, is produced; similarly, when dissolved in nitric acid, a nitrate results, Pm(NO3)3. The latter is also well-soluble; when dried, it forms pink crystals, similar to Nd(NO3)3. The electron configuration for Pm3+ is [Xe] 4f4, and the color of the ion is pink. The ground state term symbol is 5I4. The sulfate is slightly soluble, like the other cerium group sulfates. Cell parameters have been calculated for its octahydrate; they lead to conclusion that the density of Pm2(SO4)3·8 H2O is 2.86 g/cm3. The oxalate, Pm2(C2O4)3·10 H2O, has the lowest solubility of all lanthanide oxalates.
Unlike the nitrate, the oxide is similar to the corresponding samarium salt and not the neodymium salt. As-synthesized, e.g. by heating the oxalate, it is a white or lavender-colored powder with disordered structure. This powder crystallizes in a cubic lattice upon heating to 600 °C. Further annealing at 800 °C and then at 1750 °C irreversibly transforms it to a monoclinic and hexagonal phases, respectively, and the last two phases can be interconverted by adjusting the annealing time and temperature.
|Formula||symmetry||space group||No||Pearson symbol||a (pm)||b (pm)||c (pm)||Z||density, |
Promethium forms only one stable oxidation state, +3, in the form of ions; this is in line with other lanthanides. According to its position in the periodic table, the element cannot be expected to form stable +4 or +2 oxidation states; treating chemical compounds containing Pm3+ ions with strong oxidizing or reducing agents showed that the ion is not easily oxidized or reduced.
|symmetry||space group||No||Pearson symbol||m.p. (°C)|
Promethium is the only lanthanide and one of only two elements among the first 83 that has no stable or long-lived (primordial) isotopes. This is a result of a rarely occurring effect of the liquid drop model and stabilities of neighbor element isotopes; it is also the least stable element of the first 84. The primary decay products are neodymium and samarium isotopes (promethium-146 decays to both, the lighter isotopes generally to neodymium via positron decay and electron capture, and the heavier isotopes to samarium via beta decay). Promethium nuclear isomers may decay to other promethium isotopes and one isotope (145Pm) has a very rare alpha decay mode to stable praseodymium-141.
The most stable isotope of the element is promethium-145, which has a specific activity of 940 Ci/g (35 TBq/g) and a half-life of 17.7 years via electron capture. Because it has 84 neutrons (two more than 82, which is a magic number which corresponds to a stable neutron configuration), it may emit an alpha particle (which has 2 neutrons) to form praseodymium-141 with 82 neutrons. Thus it is the only promethium isotope with an experimentally observed alpha decay. Its partial half-life for alpha decay is about 6.3×109 years, and the relative probability for a 145Pm nucleus to decay in this way is 2.8×10−7 %. Several other promethium isotopes (144Pm, 146Pm, 147Pm etc.) also have a positive energy release for alpha decay; their alpha decays are predicted to occur but have not been observed.
The element also has 18 nuclear isomers, with mass numbers of 133 to 142, 144, 148, 149, 152, and 154 (some mass numbers have more than one isomer). The most stable of them is promethium-148m, with a half-life of 43.1 days; this is longer than the half-lives of the ground states of all promethium isotopes, except for promethium-143 to 147. In fact, promethium-148m has a longer half-life than its ground state, promethium-148.
In 1934, Willard Libby reported that he had found weak beta activity in pure neodymium, which was attributed to a half-life over 1012 years. Almost 20 years later, it was claimed that the element occurs in natural neodymium in equilibrium in quantities below 10−20 grams of promethium per one gram of neodymium. However, these observations were disproved by newer investigations, because for all seven naturally occurring neodymium isotopes, any single beta decays (which can produce promethium isotopes) are forbidden by energy conservation. In particular, careful measurements of atomic masses show that the mass difference 150Nd-150Pm is negative (−87 keV), which absolutely prevents the single beta decay of 150Nd to 150Pm.
In 1965 Olavi Erämetsä separated out traces of 145Pm from a rare earth concentrate purified from apatite, resulting in an upper limit of 10−21 for the abundance of promethium in nature; this may have been produced by the natural nuclear fission of uranium, or by cosmic ray spallation of 146Nd.
Both isotopes of natural europium have larger mass excesses than sums of those of their potential alpha daughters plus that of an alpha particle; therefore, they (stable in practice) may alpha decay to promethium. Research at Laboratori Nazionali del Gran Sasso showed that europium-151 experimentally decays to promethium-147 with the half-life of 5×1018 years. It has been shown that europium is "responsible" for about 12 grams of promethium in the Earth's crust. Alpha decays for europium-153 have not been found yet, and its theoretically calculated half-life is so high (due to low energy of decay) that this process will probably not be observed in the near future.
Promethium can also be formed in nature as a product of spontaneous fission of uranium-238. Only trace amounts can be found in naturally occurring ores: a sample of pitchblende has been found to contain promethium at a concentration of four parts per quintillion (4×10−18) by mass. Uranium is thus "responsible" for 560 g of promethium in Earth's crust.
Promethium has also been identified in the spectrum of the star HR 465 in Andromeda; it also has been found in HD 101065 (Przybylski's star) and HD 965. Because of the short half-life of promethium isotopes, they should be formed near the surface of those stars.
In 1902, Czech chemist Bohuslav Brauner found out that the differences in properties between neodymium and samarium were the largest between any two consecutive lanthanides in the sequence then known; as a conclusion, he suggested there was an element with intermediate properties between them. This prediction was supported in 1914 by Henry Moseley who, having discovered that atomic number was an experimentally measurable property of elements, found that a few atomic numbers had no known corresponding elements: the gaps were 43, 61, 72, 75, 85, and 87. With the knowledge of a gap in the periodic table several groups started to search for the predicted element among other rare earths in the natural environment.
The first claim of a discovery was published by Luigi Rolla and Lorenzo Fernandes of Florence, Italy. After separating a mixture of a few rare earth elements nitrate concentrate from the Brazilian mineral monazite by fractionated crystallization, they yielded a solution containing mostly samarium. This solution gave x-ray spectra attributed to samarium and element 61. In honor of their city, they named element 61 "florentium". The results were published in 1926, but the scientists claimed that the experiments were done in 1924. Also in 1926, a group of scientists from the University of Illinois at Urbana–Champaign, Smith Hopkins and Len Yntema published the discovery of element 61. They named it "illinium," after the university. Both of these reported discoveries were shown to be erroneous because the spectrum line that "corresponded" to element 61 was identical to that of didymium; the lines thought to belong to element 61 turned out to belong to a few impurities (barium, chromium, and platinum).
In 1934, Josef Mattauch finally formulated the isobar rule. One of the indirect consequences of this rule was that element 61 was unable to form stable isotopes. From 1938, a nuclear experiment was conducted by H. B. Law et al. at Ohio State University. Nuclides were produced in 1941 which were not radioisotopes of neodymium or samarium, and the name "cyclonium" was proposed, but there was a lack of chemical proof that element 61 was produced and the discovery not largely recognized.
Promethium was first produced and characterized at Oak Ridge National Laboratory (Clinton Laboratories at that time) in 1945 by Jacob A. Marinsky, Lawrence E. Glendenin and Charles D. Coryell by separation and analysis of the fission products of uranium fuel irradiated in the graphite reactor; however, being too busy with military-related research during World War II, they did not announce their discovery until 1947. The original proposed name was "clintonium", after the laboratory where the work was conducted; however, the name "prometheum" was suggested by Grace Mary Coryell, the wife of one of the discoverers. It is derived from Prometheus, the Titan in Greek mythology who stole fire from Mount Olympus and brought it down to humans and symbolizes "both the daring and the possible misuse of the mankind intellect". The spelling was then changed to "promethium," as this was in accordance with most other metals.
In 1963, promethium(III) fluoride was used to make promethium metal. Provisionally purified from impurities of samarium, neodymium, and americium, it was put into a tantalum crucible which was located in another tantalum crucible; the outer crucible contained lithium metal (10 times excess compared to promethium). After creating a vacuum, the chemicals were mixed to produce promethium metal:
Today, promethium is still recovered from the byproducts of uranium fission; it can also be produced by bombarding 146Nd with neutrons, turning it into 147Nd which decays into 147Pm through beta decay with a half-life of 11 days.
The production methods for different isotopes vary, and only those for promethium-147 are given because it is the only isotope with industrial applications. Promethium-147 is produced in large quantities (compared to other isotopes) by bombarding uranium-235 with thermal neutrons. The output is relatively high, at 2.6% of the total product. Another way to produce promethium-147 is via neodymium-147, which decays to promethium-147 with a short half-life. Neodymium-147 can be obtained either by bombarding enriched neodymium-146 with thermal neutrons or by bombarding a uranium carbide target with energetic protons in a particle accelerator. Another method is to bombard uranium-238 with fast neutrons to cause fast fission, which, among multiple reaction products, creates promethium-147.
As early as the 1960s, Oak Ridge National Laboratory could produce 650 grams of promethium per year and was the world's only large-volume synthesis facility. Gram-scale production of promethium has been discontinued in the U.S. in the early 1980s, but will possibly be resumed after 2010 at the High Flux Isotope Reactor. Currently, Russia is the only country producing promethium-147 on a relatively large scale.
Most promethium is used only for research purposes, except for promethium-147, which can be found outside laboratories. It is obtained as the oxide or chloride, in milligram quantities. This isotope does not emit gamma rays, and its radiation has a relatively small penetration depth in matter and a relatively long half-life.
Some signal lights use a luminous paint, containing a phosphor that absorbs the beta radiation emitted by promethium-147 and emits light. This isotope does not cause aging of the phosphor, as alpha emitters do, and therefore the light emission is stable for a few years. Originally, radium-226 was used for the purpose, but it was later replaced by promethium-147 and tritium (hydrogen-3). Promethium may be favored over tritium for nuclear safety reasons.
In atomic batteries, the beta particles emitted by promethium-147 are converted into electric current by sandwiching a small promethium source between two semiconductor plates. These batteries have a useful lifetime of about five years. The first promethium-based battery was assembled in 1964 and generated "a few milliwatts of power from a volume of about 2 cubic inches, including shielding".
Promethium is also used to measure the thickness of materials by evaluating the amount of radiation from a promethium source that passes through the sample. It has possible future uses in portable X-ray sources, and as auxiliary heat or power sources for space probes and satellites (although the alpha emitter plutonium-238 has become standard for most space-exploration-related uses).
The element, like other lanthanides, has no biological role. Promethium-147 can emit X-rays during its beta decay, which are dangerous for all lifeforms. Interactions with tiny quantities of promethium-147 are not hazardous if certain precautions are observed. In general, gloves, footwear covers, safety glasses, and an outer layer of easily removed protective clothing should be used.
It is not known what human organs are affected by interaction with promethium; a possible candidate is the bone tissues. Sealed promethium-147 is not dangerous. However, if the packaging is damaged, then promethium becomes dangerous to the environment and humans. If radioactive contamination is found, the contaminated area should be washed with water and soap, but, even though promethium mainly affects the skin, the skin should not be abraded. If a promethium leak is found, the area should be identified as hazardous and evacuated, and emergency services must be contacted. No dangers from promethium aside from the radioactivity are known.
The abundance of elements in Earth's crust is shown in tabulated form with the estimated crustal abundance for each chemical element shown as parts per million (ppm) by mass (10,000 ppm = 1%). Note that the noble gases are not included, as they form no part of the solid crust. Also not included are certain elements with extremely low crustal concentrations: technetium (atomic number 43), promethium (61), and all elements with atomic numbers greater than 83 except thorium (90) and uranium (92).Features of the Marvel Universe
The comic book stories published by Marvel Comics since the 1940s have featured several noteworthy concepts besides its fictional characters, such as unique places and artifacts. There follows a list of those features.GY Andromedae
GY Andromedae (GY And) is an α2 Canum Venaticorum type variable star in the northern constellation Andromeda. Its brightness fluctuates in visual magnitude between 6.27m and 6.41m, making it a challenge to view with the naked eye even in good seeing conditions. The magnetic activity on this star shows an unusually long period of variability, cycling about once every 23 years. Based upon parallax measurements, this star is located at a distance of about 520 light-years (160 parsecs) from the Earth.This is classified as an Ap/Bp star, with a peculiar spectrum showing lines of chromium and europium that change in intensity over a period matching the variability cycle, although opposite in phase. Its most striking characteristic is the presence of the unstable element promethium in its emission spectrum. All isotopes of this element are radioactive with half lives of 17.7 years or less. The promethium in the outer envelope may be generated by the spontaneous fission of higher mass transuranic elements.Gringo (2018 film)
Gringo is a 2018 American crime comedy film directed by Nash Edgerton and written by Anthony Tambakis and Matthew Stone. The film stars David Oyelowo, Charlize Theron (who also produced), Joel Edgerton (Nash's brother), Amanda Seyfried, Thandie Newton, and Sharlto Copley, and follows a mild-mannered businessman who is sent to Mexico to deliver an experimental marijuana pill. When he is kidnapped by a drug cartel he must escape alongside a hired mercenary. The film marked Paris Jackson's film debut.
The film was released in the United States on March 9, 2018, by Amazon Studios and STXfilms.Hybrid (DC Comics)
The Hybrid are a fictional group of supervillains appearing in comic books published by DC Comics.Isotopes of promethium
Promethium (61Pm) is an artificial element, except in trace quantities as a product of spontaneous fission of 238U and 235U and alpha decay of 151Eu, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. It was first synthesized in 1945.
Thirty-eight radioisotopes have been characterized, with the most stable being 145Pm with a half-life of 17.7 years, 146Pm with a half-life of 5.53 years, and 147Pm with a half-life of 2.6234 years. All of the remaining radioactive isotopes have half-lives that are less than 365 days, and the majority of these have half-lives that are less than 30 seconds. This element also has 18 meta states with the most stable being 148mPm (t1/2 41.29 days), 152m2Pm (t1/2 13.8 minutes) and 152mPm (t1/2 7.52 minutes).
The isotopes of promethium range in atomic weight from 125.95752 u (126Pm) to 162.95368 u (163Pm). The primary decay mode for 146Pm and lighter isotopes is electron capture, and the primary mode for heavier isotopes is beta decay. The primary decay products before 146Pm are isotopes of neodymium, and the primary products after are isotopes of samarium.Jacob A. Marinsky
Jacob Akiba Marinsky (April 11, 1918 – September 1, 2005) was a chemist who was the co-discoverer of the element promethium.Luminous paint
Luminous paint or luminescent paint is paint that exhibits luminescence. In other words, it gives off visible light through fluorescence, phosphorescence, or radioluminescence. There are three types of luminous paints..Major actinide
Major actinides is a term used in the nuclear power industry that refers to the plutonium and uranium present in used nuclear fuel, as opposed to the minor actinides neptunium, americium, curium, berkelium, and californium.Promethium(III) chloride
Promethium(III) chloride is a chemical compound of promethium and chlorine with the formula PmCl3.Promethium(III) fluoride
Promethium(III) fluoride or promethium trifluoride is the chemical compound of promethium and fluorine with the formula PmF3.
Promethium(III) fluoride is sparingly soluble in water. It reacts with metallic lithium to yield lithium fluoride and metallic promethium:
Promethium(III) oxide is a compound with the formula Pm2O3. It is the most common form of promethium.Promethium (disambiguation)
Promethium is a chemical element with symbol Pm and atomic number 61.
Promethium may also refer to:
Promethium, a fictional petroleum-based fossil fuel as well as a refined napalm-like substance in Warhammer 40,000
Promethium, the name of the Mechanic Empire's queen in the fictional universe of Leiji Matsumoto
Promethium, a fictional metal in stories published by DC Comics
Promethium (Marvel Comics), a fictional, magical metal in the stories published by Marvel ComicsQueen Millennia
Queen Millennia (Japanese: 新竹取物語 1000年女王, Hepburn: Shin Taketori Monogatari: Sennen Joō, lit. "The New Tale of the Bamboo Cutter: Millennium Queen") is a manga series by Leiji Matsumoto which was serialized from 28 January 1980
through 11 May 1983 in both the Sankei Shimbun and Nishinippon Sports newspapers. The manga series was adapted into a 42-episode anime television series by Toei Dōga and broadcast on the Fuji TV network from 16 April 1981 through 25 March 1982. An anime film was released on 13 March 1982 shortly before the TV series ended.The anime series was combined by Harmony Gold and Carl Macek with episodes from the 1978 Matsumoto series, Space Pirate Captain Harlock, and shown from 1985 to 1986 in the United States as the 65-episode Captain Harlock and the Queen of a Thousand Years. The series was broadcast in Germany on Tele 5 during 1992 and on Mangas in France in 2004.Radioluminescence
Radioluminescence is the phenomenon by which light is produced in a material by bombardment with ionizing radiation such as alpha particles, beta particles, or gamma rays. Radioluminescence is used as a low level light source for night illumination of instruments or signage. Radioluminescent paint used to be used for clock hands and instrument dials, enabling them to be read in the dark. Radioluminescence is also sometimes seen around high-power radiation sources, such as nuclear reactors and radioisotopes.Rare-earth element
A rare-earth element (REE) or rare-earth metal (REM), as defined by IUPAC, is one of a set of seventeen chemical elements in the periodic table, specifically the fifteen lanthanides, as well as scandium and yttrium. Scandium and yttrium are considered rare-earth elements because they tend to occur in the same ore deposits as the lanthanides and exhibit similar chemical properties. Rarely, a broader definition that includes actinides may be used, since the actinides share some mineralogical, chemical, and physical (especially electron shell configuration) characteristics.The 17 rare-earth elements are cerium (Ce), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), holmium (Ho), lanthanum (La), lutetium (Lu), neodymium (Nd), praseodymium (Pr), promethium (Pm), samarium (Sm), scandium (Sc), terbium (Tb), thulium (Tm), ytterbium (Yb), and yttrium (Y).
Despite their name, rare-earth elements are – with the exception of the radioactive promethium – relatively plentiful in Earth's crust, with cerium being the 25th most abundant element at 68 parts per million, more abundant than copper. However, because of their geochemical properties, rare-earth elements are typically dispersed and not often found concentrated in rare-earth minerals; as a result economically exploitable ore deposits are less common. The first rare-earth mineral discovered (1787) was gadolinite, a mineral composed of cerium, yttrium, iron, silicon, and other elements. This mineral was extracted from a mine in the village of Ytterby in Sweden; four of the rare-earth elements bear names derived from this single location.Synthetic radioisotope
A synthetic radioisotope is a radionuclide that is not found in nature: no natural process or mechanism exists which produces it, or it is so unstable that it decays away in a very short period of time. Examples include technetium-95 and promethium-146. Many of these are found in, and harvested from, spent nuclear fuel assemblies. Some must be manufactured in particle accelerators.Thulium
Thulium is a chemical element with symbol Tm and atomic number 69. It is the thirteenth and third-last element in the lanthanide series. Like the other lanthanides, the most common oxidation state is +3, seen in its oxide, halides and other compounds; because it occurs so late in the series, however, the +2 oxidation state is also stabilized by the nearly full 4f shell that results. In aqueous solution, like compounds of other late lanthanides, soluble thulium compounds form coordination complexes with nine water molecules.
In 1879, the Swedish chemist Per Teodor Cleve separated from the rare earth oxide erbia another two previously unknown components, which he called holmia and thulia; these were the oxides of holmium and thulium, respectively. A relatively pure sample of thulium metal was first obtained in 1911.
Thulium is the second-least abundant of the lanthanides, after radioactively unstable promethium which is only found in trace quantities on Earth. It is an easily workable metal with a bright silvery-gray luster. It is fairly soft and slowly tarnishes in air. Despite its high price and rarity, thulium is used as the radiation source in portable X-ray devices, and in some solid-state lasers. It has no significant biological role and is not particularly toxic.