Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in colour from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the form of magnetite (Fe
4, 72.4% Fe), hematite (Fe
3, 69.9% Fe), goethite (FeO(OH), 62.9% Fe), limonite (FeO(OH)·n(H2O), 55% Fe) or siderite (FeCO3, 48.2% Fe).
Ores containing very high quantities of hematite or magnetite (greater than about 60% iron) are known as "natural ore" or "direct shipping ore", meaning they can be fed directly into iron-making blast furnaces. Iron ore is the raw material used to make pig iron, which is one of the main raw materials to make steel—98% of the mined iron ore is used to make steel. Indeed, it has been argued that iron ore is "more integral to the global economy than any other commodity, except perhaps oil".
Metallic iron is virtually unknown on the surface of the Earth except as iron-nickel alloys from meteorites and very rare forms of deep mantle xenoliths. Iron metorites themselves are thought to have originated from stellar bodies larger than 1000 km in diameter. The origin of iron can be ultimately traced to formation through nuclear fusion in stars and most of the iron is thought to have originated in dying stars that are large enough to collapse or explode as supernovae. Although iron is the fourth most abundant element in the Earth's crust, comprising about 5%, the vast majority is bound in silicate or more rarely carbonate minerals (for more information, see iron cycle). The thermodynamic barriers to separating pure iron from these minerals are formidable and energy intensive, therefore all sources of iron used by human industry exploit comparatively rarer iron oxide minerals, primarily hematite.
Prior to the industrial revolution, most iron was obtained from widely available goethite or bog ore, for example during the American Revolution and the Napoleonic Wars. Prehistoric societies used laterite as a source of iron ore. Historically, much of the iron ore utilized by industrialized societies has been mined from predominantly hematite deposits with grades of around 70% Fe. These deposits are commonly referred to as "direct shipping ores" or "natural ores". Increasing iron ore demand, coupled with the depletion of high-grade hematite ores in the United States, after World War II led to development of lower-grade iron ore sources, principally the utilization of magnetite and taconite.
Iron-ore mining methods vary by the type of ore being mined. There are four main types of iron-ore deposits worked currently, depending on the mineralogy and geology of the ore deposits. These are magnetite, titanomagnetite, massive hematite and pisolitic ironstone deposits.
Banded iron formations (BIFs) are sedimentary rocks containing more than 15% iron composed predominantly of thinly bedded iron minerals and silica (as quartz). Banded iron formations occur exclusively in Precambrian rocks, and are commonly weakly to intensely metamorphosed. Banded iron formations may contain iron in carbonates (siderite or ankerite) or silicates (minnesotaite, greenalite, or grunerite), but in those mined as iron ores, oxides (magnetite or hematite) are the principal iron mineral. Banded iron formations are known as taconite within North America.
The mining involves moving tremendous amounts of ore and waste. The waste comes in two forms, non-ore bedrock in the mine (overburden or interburden locally known as mullock), and unwanted minerals which are an intrinsic part of the ore rock itself (gangue). The mullock is mined and piled in waste dumps, and the gangue is separated during the beneficiation process and is removed as tailings. Taconite tailings are mostly the mineral quartz, which is chemically inert. This material is stored in large, regulated water settling ponds.
The key economic parameters for magnetite ore being economic are the crystallinity of the magnetite, the grade of the iron within the banded iron formation host rock, and the contaminant elements which exist within the magnetite concentrate. The size and strip ratio of most magnetite resources is irrelevant as a banded iron formation can be hundreds of meters thick, extend hundreds of kilometers along strike, and can easily come to more than three billion or more tonnes of contained ore.
The typical grade of iron at which a magnetite-bearing banded iron formation becomes economic is roughly 25% iron, which can generally yield a 33% to 40% recovery of magnetite by weight, to produce a concentrate grading in excess of 64% iron by weight. The typical magnetite iron-ore concentrate has less than 0.1% phosphorus, 3–7% silica and less than 3% aluminium.
Currently magnetite iron ore is mined in Minnesota and Michigan in the U.S., Eastern Canada and Northern Sweden. Magnetite bearing banded iron formation is currently mined extensively in Brazil, which exports significant quantities to Asia, and there is a nascent and large magnetite iron-ore industry in Australia.
Direct-shipping iron-ore (DSO) deposits (typically composed of hematite) are currently exploited on all continents except Antarctica, with the largest intensity in South America, Australia and Asia. Most large hematite iron-ore deposits are sourced from altered banded iron formations and rarely igneous accumulations.
DSO deposits are typically rarer than the magnetite-bearing BIF or other rocks which form its main source or protolith rock, but are considerably cheaper to mine and process as they require less beneficiation due to the higher iron content. However, DSO ores can contain significantly higher concentrations of penalty elements, typically being higher in phosphorus, water content (especially pisolite sedimentary accumulations) and aluminum (clays within pisolites). Export grade DSO ores are generally in the 62–64% Fe range.
Occasionally granite and ultrapotassic igneous rocks segregate magnetite crystals and form masses of magnetite suitable for economic concentration. A few iron ore deposits, notably in Chile, are formed from volcanic flows containing significant accumulations of magnetite phenocrysts. Chilean magnetite iron ore deposits within the Atacama Desert have also formed alluvial accumulations of magnetite in streams leading from these volcanic formations.
Some magnetite skarn and hydrothermal deposits have been worked in the past as high-grade iron ore deposits requiring little beneficiation. There are several granite-associated deposits of this nature in Malaysia and Indonesia.
Another, minor, source of iron ores are magmatic accumulations in layered intrusions which contain a typically titanium-bearing magnetite often with vanadium. These ores form a niche market, with specialty smelters used to recover the iron, titanium and vanadium. These ores are beneficiated essentially similar to banded iron formation ores, but usually are more easily upgraded via crushing and screening. The typical titanomagnetite concentrate grades 57% Fe, 12% Ti and 0.5% V
For every 1 ton of iron ore concentrate produced approximately 2.5-3.0 tons of iron ore tailings will be discharged. Statistics show that there are 130 million tons of iron ore discharged every year. If for example the mine tailings contain an average of approximately 11% iron there would be approximately 1.41 million tons of iron wasted annually. These tailings are also high in other useful metals such as Cu, Ni, and Co and they can be used for road building materials like pavement and filler and building materials such as cement, low grade glass, and wall materials. While tailings are a relatively low grade ore, they are also inexpensive to collect as they don't have to be mined. Because of this companies such as Magnetation Inc. have started reclamation projects where they use iron ore tailings as a source of metallic iron.
The two main methods of recycling iron from iron ore tailings are magnetizing roasting and direct reduction. Magnetizing roasting uses temperatures between 700 and 900 °C for a time of under 1 hour to produce an iron concentrate (Fe3O4) to be used for iron smelting. For magnetizing roasting it is important to have a reducing atmosphere to prevent oxidization and the formation of Fe2O3 because it is harder to separate as it is less magnetic. Direct reduction uses hotter temperatures of over 1000 °C and longer times of 2–5 hours. Direct reduction is used to produce sponge iron (Fe) to be used for steel making. Direct reduction requires more energy as the temperatures are higher and the time is longer and it requires more reducing agent than magnetizing roasting.
The Lower-grade sources of iron ore generally require beneficiation, using techniques like crushing, milling, gravity or heavy media separation, screening, and silica froth flotation to improve the concentration of the ore and remove impurities. The results, high quality fine ore powders, are known as fines.
The grain size of the magnetite and its degree of commingling with the silica groundmass determine the grind size to which the rock must be comminuted to enable efficient magnetic separation to provide a high purity magnetite concentrate. This determines the energy inputs required to run a milling operation.
Mining of banded iron formations involves coarse crushing and screening, followed by rough crushing and fine grinding to comminute the ore to the point where the crystallized magnetite and quartz are fine enough that the quartz is left behind when the resultant powder is passed under a magnetic separator.
Generally most magnetite banded iron formation deposits must be ground to between 32 and 45 micrometers in order to produce a low-silica magnetite concentrate. Magnetite concentrate grades are generally in excess of 70% iron by weight and usually are low phosphorus, low aluminium, low titanium and low silica and demand a premium price.
One method relies on passing the finely crushed ore over a slurry containing magnetite or other agent such as ferrosilicon which increases its density. When the density of the slurry is properly calibrated, the hematite will sink and the silicate mineral fragments will float and can be removed.
Iron is the world's most commonly used metal - steel, of which iron ore is the key ingredient, representing almost 95% of all metal used per year. It is used primarily in structural engineering applications and in maritime purposes, automobiles, and general industrial applications (machinery).
Iron-rich rocks are common worldwide, but ore-grade commercial mining operations are dominated by the countries listed in the table aside. The major constraint to economics for iron ore deposits is not necessarily the grade or size of the deposits, because it is not particularly hard to geologically prove enough tonnage of the rocks exist. The main constraint is the position of the iron ore relative to market, the cost of rail infrastructure to get it to market and the energy cost required to do so.
Mining iron ore is a high volume low margin business, as the value of iron is significantly lower than base metals. It is highly capital intensive, and requires significant investment in infrastructure such as rail in order to transport the ore from the mine to a freight ship. For these reasons, iron ore production is concentrated in the hands of a few major players.
World production averages two billion metric tons of raw ore annually. The world's largest producer of iron ore is the Brazilian mining corporation Vale, followed by Anglo-Australian companies Rio Tinto Group and then BHP Billiton. A further Australian supplier, Fortescue Metals Group Ltd, has helped bring Australia's production to first in the world.
The seaborne trade in iron ore, that is, iron ore to be shipped to other countries, was 849m tonnes in 2004. Australia and Brazil dominate the seaborne trade, with 72% of the market. BHP, Rio and Vale control 66% of this market between them.
In Australia iron ore is won from three main sources: pisolite "channel iron deposit" ore derived by mechanical erosion of primary banded-iron formations and accumulated in alluvial channels such as at Pannawonica, Western Australia; and the dominant metasomatically-altered banded iron formation related ores such as at Newman, the Chichester Range, the Hamersley Range and Koolyanobbing, Western Australia. Other types of ore are coming to the fore recently, such as oxidised ferruginous hardcaps, for instance laterite iron ore deposits near Lake Argyle in Western Australia.
The total recoverable reserves of iron ore in India are about 9,602 million tonnes of hematite and 3,408 million tonnes of magnetite. Chhattisgarh, Madhya Pradesh, Karnataka, Jharkhand, Odisha, Goa, Maharashtra, Andhra Pradesh, Kerala, Rajasthan and Tamil Nadu are the principal Indian producers of iron ore. World consumption of iron ore grows 10% per annum on average with the main consumers being China, Japan, Korea, the United States and the European Union.
China is currently the largest consumer of iron ore, which translates to be the world's largest steel producing country. It is also the largest importer, buying 52% of the seaborne trade in iron ore in 2004. China is followed by Japan and Korea, which consume a significant amount of raw iron ore and metallurgical coal. In 2006, China produced 588 million tons of iron ore, with an annual growth of 38%.
Over the last 40 years, iron ore prices have been decided in closed-door negotiations between the small handful of miners and steelmakers which dominate both spot and contract markets. Traditionally, the first deal reached between these two groups sets a benchmark to be followed by the rest of the industry.
In recent years, however, this benchmark system has begun to break down, with participants along both demand and supply chains calling for a shift to short term pricing. Given that most other commodities already have a mature market-based pricing system, it is natural for iron ore to follow suit. To answer increasing market demands for more transparent pricing, a number of financial exchanges and/or clearing houses around the world have offered iron ore swaps clearing. The CME group, SGX (Singapore Exchange), London Clearing House (LCH.Clearnet), NOS Group and ICEX (Indian Commodities Exchange) all offer cleared swaps based on The Steel Index's (TSI) iron ore transaction data. The CME also offers a Platts-based swap, in addition to their TSI swap clearing. The ICE (Intercontinental Exchange) offers a Platts-based swap clearing service also. The swaps market has grown quickly, with liquidity clustering around TSI's pricing. By April 2011, over US$5.5 billion worth of iron ore swaps have been cleared basis TSI prices. By August 2012, in excess of one million tonnes of swaps trading per day was taking place regularly, basis TSI.
A relatively new development has also been the introduction of iron ore options, in addition to swaps. The CME group has been the venue most utilised for clearing of options written against TSI, with open interest at over 12,000 lots in August 2012.
Singapore Mercantile Exchange (SMX) has launched the world first global iron ore futures contract, based on the Metal Bulletin Iron Ore Index (MBIOI) which utilizes daily price data from a broad spectrum of industry participants and independent Chinese steel consultancy and data provider Shanghai Steelhome's widespread contact base of steel producers and iron ore traders across China. The futures contract has seen monthly volumes over 1.5 million tonnes after eight months of trading.
This move follows a switch to index-based quarterly pricing by the world's three largest iron ore miners - Vale, Rio Tinto and BHP - in early 2010, breaking a 40-year tradition of benchmark annual pricing.
The iron ore reserves at present seem quite vast, but some are starting to suggest that the math of continual exponential increase in consumption can even make this resource seem quite finite. For instance, Lester Brown of the Worldwatch Institute has suggested iron ore could run out within 64 years based on an extremely conservative extrapolation of 2% growth per year.
Geoscience Australia calculates that the country's "economic demonstrated resources" of iron currently amount to 24 gigatonnes, or 24 billion tonnes. The current production rate from the Pilbara region of Western Australia is approximately 430 million tonnes a year and rising. Gavin Mudd (Monash University) and Jonathon Law (CSIRO) expect it to be gone within 30 to 50 years (Mudd) and 56 years (Law). These estimates require on-going review to take into account shifting demand for lower grade iron ore and improving mining and recovery techniques (allowing deeper mining below the groundwater table).
In 2011, leading Pilbara-based iron ore miners – Rio Tinto, BHP Billiton and Fortescue Metals Group (FMG) – all announced significant capital investment in the development of existing and new mines and associated infrastructure (rail and port). Collectively this would amount to the production of 1,000 million tonnes per year (Mt/y) by 2020. Practically that would require a doubling of production capacity from a current production level of 470 Mt/y to 1,000 Mt/y (an increase of 530 Mt/y). These figures are based on the current production rates of Rio 300 Mt/y, BHP 240 Mt/y, FMG 55 Mt/y and Other 15 Mt/y increasing to Rio 360 Mt/y, BHP 356 Mt/y, FMG 155 Mt/y and Other 140 Mt/y (the latter 140 Mt/y is based on planned production from recent industry entrants Hancock, Atlas and Brockman through Port Hedland and API and others through the proposed Port of Anketell). In March 2014, Fortescue officially opened its 40 million-tonne per annum (mtpa) Kings Valley project, marking the completion of a US$9.2 billion expansion that increased its production capacity to 155 mtpa. The expansion included the construction of the greenfields Solomon Hub in the Hamersley Ranges, one of the world's largest iron ore developments comprising Kings Valley and the nearby 20 mtpa Firetail mine; an expansion of the Christmas Creek mine to 50 mtpa; and major extensions of Fortescue's world-class port and rail facilities.
A production rate of 1,000 Mt/y would require a significant increase in production from existing mines and the opening of a significant number of new mines. Further, a significant increase in the capacity of rail and port infrastructure would also be required. For example, Rio would be required to expand its port operations at Dampier and Cape Lambert by 140 Mt/y (from 220 Mt/y to 360 Mt/y). BHP would be required to expand its Port Hedland port operations by 180 Mt/y (from 180 Mt/y to 360 Mt/y). FMG would be required to expand its port operations at Port Hedland by 100 Mt/y (from 55 Mt/y to 155 Mt/y). That is an increase of 420 Mt/y in port capacity by the three majors Rio, BHP and FMG and about at least 110 Mt/y from the non-major producers. Based on the rule-of-thumb of 50 Mt/y per car dumper, reclaimer and ship-loader the new production would require approximately 10 new car dumpers, reclaimers and ship-loaders.
New rail capacity would also be required. Based on the rule-of-thumb of 100 Mt/y per rail line, increasing production by approximately 500 Mt/y would require five new single rail lines. One scenario is an extra rail line for all the majors: BHP (from double to triple track), Rio (double to triple track), FMG (single to double track) and at least two new lines. Hancock Prospecting has recently started production from its Roy Hill Iron Ore Mine located north of Newman. This project included the development of the Roy Hill deposit, the construction of a 344 km railway and a port facility with an annual throughput of 55 Mt and QR National to service non-major producers, as of December 2015 due to the falling iron ore price these plans have been suspended indefinitely.
A 1,000 Mt/y production rate needs to be further considered by proponents and government. Areas of further consideration include new port space at Anketell to service the West Pilbara mines, growth at Port Hedland (BHP has announced the development of an outer harbour at Port Hedland), rail rationalisation and the regulatory approval requirements for opening and maintaining a ground disturbance footprint that supports 1,000 Mt/y of production including, amongst other things, native title, aboriginal heritage and environmental protection outcomes.
In 2014 mines in the United States produced 57.5 million metric tons of iron ore with an estimated value of $5.1 billion. Iron mining in the United States is estimated to have accounted for 2% of the world’s iron ore output. In the United States there are 12 iron ore mines with 9 being open pit mines and 3 being reclamation operations. There were also 10 pelletizing plants, 9 concentration plants, 2 direct-reduced iron (DRI) plants and 1 iron nugget plant that where operating in 2014. In the United States the majority of iron ore mining is in the iron ranges around Lake Superior. These iron ranges occur in Minnesota and Michigan which combined accounted for 93% of the usable iron ore produced in the United States in 2014. Seven of the nine operational open pit mines in the United States are located in Minnesota as well as 2 of the 3 tailings reclamation operations. The other 2 active open pit mines were located in Michigan, in 2016 one of the 2 mines shut down. There have also been iron ore mines in Utah and Alabama however the last iron ore mine in Utah shut down in 2014 and the last iron ore mine in Alabama shut down in 1975.
In 2017 Canadian iron ore mines produced 49 million tons of iron ore in concentrate pellets and 13.6 million tons of crude steel. Of the 13.6 million tons of steel 7 million was exported, and 43.1 million tons of iron ore was exported at a value of $4.6 billion. Of the iron ore exported 38.5% of the volume was iron ore pellets with a value of $2.3 billion and 61.5% was iron ore concentrates with a value of $2.3 billion. The majority of Canada's iron ore comes from Nunavut and from Labrador along the Quebec and Newfoundland and Labrador border.
Brazil is the second largest producer of iron ore with Australia being the largest. In 2015 Brazil exported 397 million tons of usable iron ore. In December 2017 Brazil exported 346,497 metric tons of iron ore and from December 2007 to May 2018 they exported a monthly average of 139,299 metric tons.
Iron ores consist of oxygen and iron atoms bonded together into molecules. To convert it to metallic iron it must be smelted or sent through a direct reduction process to remove the oxygen. Oxygen-iron bonds are strong, and to remove the iron from the oxygen, a stronger elemental bond must be presented to attach to the oxygen. Carbon is used because the strength of a carbon-oxygen bond is greater than that of the iron-oxygen bond, at high temperatures. Thus, the iron ore must be powdered and mixed with coke, to be burnt in the smelting process.
However, it is not entirely as simple as that. Carbon monoxide is the primary ingredient of chemically stripping oxygen from iron. Thus, the iron and carbon smelting must be kept at an oxygen deficient (reducing) state to promote burning of carbon to produce CO not CO
The inclusion of even small amounts of some elements can have profound effects on the behavioral characteristics of a batch of iron or the operation of a smelter. These effects can be both good and bad, some catastrophically bad. Some chemicals are deliberately added such as flux which makes a blast furnace more efficient. Others are added because they make the iron more fluid, harder, or give it some other desirable quality. The choice of ore, fuel, and flux determine how the slag behaves and the operational characteristics of the iron produced. Ideally iron ore contains only iron and oxygen. In reality this is rarely the case. Typically, iron ore contains a host of elements which are often unwanted in modern steel.
2) is almost always present in iron ore. Most of it is slagged off during the smelting process. At temperatures above 1300 °C some will be reduced and form an alloy with the iron. The hotter the furnace, the more silicon will be present in the iron. It is not uncommon to find up to 1.5% Si in European cast iron from the 16th to 18th centuries.
The major effect of silicon is to promote the formation of grey iron. Grey iron is less brittle and easier to finish than white iron. It is preferred for casting purposes for this reason. Turner (1900, pp. 192–197) reported that silicon also reduces shrinkage and the formation of blowholes, lowering the number of bad castings.
Phosphorus (P) has four major effects on iron: increased hardness and strength, lower solidus temperature, increased fluidity, and cold shortness. Depending on the use intended for the iron, these effects are either good or bad. Bog ore often has a high phosphorus content (Gordon 1996, p. 57).
The strength and hardness of iron increases with the concentration of phosphorus. 0.05% phosphorus in wrought iron makes it as hard as medium carbon steel. High phosphorus iron can also be hardened by cold hammering. The hardening effect is true for any concentration of phosphorus. The more phosphorus, the harder the iron becomes and the more it can be hardened by hammering. Modern steel makers can increase hardness by as much as 30%, without sacrificing shock resistance by maintaining phosphorus levels between 0.07 and 0.12%. It also increases the depth of hardening due to quenching, but at the same time also decreases the solubility of carbon in iron at high temperatures. This would decrease its usefulness in making blister steel (cementation), where the speed and amount of carbon absorption is the overriding consideration.
The addition of phosphorus has a down side. At concentrations higher than 0.2% iron becomes increasingly cold short, or brittle at low temperatures. Cold short is especially important for bar iron. Although bar iron is usually worked hot, its uses often require it to be tough, bendable, and resistant to shock at room temperature. A nail that shattered when hit with a hammer or a carriage wheel that broke when it hit a rock would not sell well. High enough concentrations of phosphorus render any iron unusable (Rostoker & Bronson 1990, p. 22). The effects of cold shortness are magnified by temperature. Thus, a piece of iron that is perfectly serviceable in summer, might become extremely brittle in winter. There is some evidence that during the Middle Ages the very wealthy may have had a high phosphorus sword for summer and a low phosphorus sword for winter (Rostoker & Bronson 1990, p. 22).
Careful control of phosphorus can be of great benefit in casting operations. Phosphorus depresses the liquidus temperature, allowing the iron to remain molten for longer and increases fluidity. The addition of 1% can double the distance molten iron will flow (Rostoker & Bronson 1990, p. 22). The maximum effect, about 500 °C, is achieved at a concentration of 10.2% (Rostocker & Bronson 1990, p. 194). For foundry work Turner felt the ideal iron had 0.2–0.55% phosphorus. The resulting iron filled molds with fewer voids and also shrank less. In the 19th century some producers of decorative cast iron used iron with up to 5% phosphorus. The extreme fluidity allowed them to make very complex and delicate castings. But, they could not be weight bearing, as they had no strength (Turner 1900, pp. 202–204).
There are two remedies for high phosphorus iron. The oldest, and easiest, is avoidance. If the iron that the ore produced was cold short, one would search for a new source of iron ore. The second method involves oxidizing the phosphorus during the fining process by adding iron oxide. This technique is usually associated with puddling in the 19th century, and may not have been understood earlier. For instance Isaac Zane, the owner of Marlboro Iron Works did not appear to know about it in 1772. Given Zane's reputation for keeping abreast of the latest developments, the technique was probably unknown to the ironmasters of Virginia and Pennsylvania.
Phosphorus is a deleterious contaminant because it makes steel brittle, even at concentrations of as little as 0.6%. Phosphorus cannot be easily removed by fluxing or smelting, and so iron ores must generally be low in phosphorus to begin with.
Small amounts of aluminium (Al) are present in many ores including iron ore, sand and some limestones. The former can be removed by washing the ore prior to smelting. Until the introduction of brick lined furnaces, the amount of aluminium contamination was small enough that it did not have an effect on either the iron or slag. However, when brick began to be used for hearths and the interior of blast furnaces, the amount of aluminium contamination increased dramatically. This was due to the erosion of the furnace lining by the liquid slag.
Aluminium is difficult to reduce. As a result, aluminium contamination of the iron is not a problem. However, it does increase the viscosity of the slag (Kato & Minowa 1969, p. 37 and Rosenqvist 1983, p. 311). This will have a number of adverse effects on furnace operation. The thicker slag will slow the descent of the charge, prolonging the process. High aluminium will also make it more difficult to tap off the liquid slag. At the extreme this could lead to a frozen furnace.
There are a number of solutions to a high aluminium slag. The first is avoidance; don't use ore or a lime source with a high aluminium content. Increasing the ratio of lime flux will decrease the viscosity (Rosenqvist 1983, p. 311).
Sulfur (S) is a frequent contaminant in coal. It is also present in small quantities in many ores, but can be removed by calcining. Sulfur dissolves readily in both liquid and solid iron at the temperatures present in iron smelting. The effects of even small amounts of sulfur are immediate and serious. They were one of the first worked out by iron makers. Sulfur causes iron to be red or hot short (Gordon 1996, p. 7).
Hot short iron is brittle when hot. This was a serious problem as most iron used during the 17th and 18th century was bar or wrought iron. Wrought iron is shaped by repeated blows with a hammer while hot. A piece of hot short iron will crack if worked with a hammer. When a piece of hot iron or steel cracks the exposed surface immediately oxidizes. This layer of oxide prevents the mending of the crack by welding. Large cracks cause the iron or steel to break up. Smaller cracks can cause the object to fail during use. The degree of hot shortness is in direct proportion to the amount of sulfur present. Today iron with over 0.03% sulfur is avoided.
Hot short iron can be worked, but it has to be worked at low temperatures. Working at lower temperatures requires more physical effort from the smith or forgeman. The metal must be struck more often and harder to achieve the same result. A mildly sulfur contaminated bar can be worked, but it requires a great deal more time and effort.
In cast iron sulfur promotes the formation of white iron. As little as 0.5% can counteract the effects of slow cooling and a high silicon content (Rostoker & Bronson 1990, p. 21). White cast iron is more brittle, but also harder. It is generally avoided, because it is difficult to work, except in China where high sulfur cast iron, some as high as 0.57%, made with coal and coke, was used to make bells and chimes (Rostoker, Bronson & Dvorak 1984, p. 760). According to Turner (1900, pp. 200), good foundry iron should have less than 0.15% sulfur. In the rest of the world a high sulfur cast iron can be used for making castings, but will make poor wrought iron.
There are a number of remedies for sulfur contamination. The first, and the one most used in historic and prehistoric operations, is avoidance. Coal was not used in Europe (unlike China) as a fuel for smelting because it contains sulfur and therefore causes hot short iron. If an ore resulted in hot short metal, ironmasters looked for another ore. When mineral coal was first used in European blast furnaces in 1709 (or perhaps earlier), it was coked. Only with the introduction of hot blast from 1829 was raw coal used.
Sulfur can be removed from ores by roasting and washing. Roasting oxidizes sulfur to form sulfur dioxide which either escapes into the atmosphere or can be washed out. In warm climates it is possible to leave pyritic ore out in the rain. The combined action of rain, bacteria, and heat oxidize the sulfides to sulfuric acid and sulfates, which are water-soluble and leached out (Turner 1900, pp. 77). However, historically (at least), iron sulfide (iron pyrite FeS
2), though a common iron mineral, has not been used as an ore for the production of iron metal. Natural weathering was also used in Sweden. The same process, at geological speed, results in the gossan limonite ores.
The importance attached to low sulfur iron is demonstrated by the consistently higher prices paid for the iron of Sweden, Russia, and Spain from the 16th to 18th centuries. Today sulfur is no longer a problem. The modern remedy is the addition of manganese. But, the operator must know how much sulfur is in the iron because at least five times as much manganese must be added to neutralize it. Some historic irons display manganese levels, but most are well below the level needed to neutralize sulfur (Rostoker & Bronson 1990, p. 21).
Sulfide inclusion as manganese sulfide (MnS) can also be the cause of severe pitting corrosion problems in low-grade stainless steel such as AISI 304 steel. Under oxidizing conditions and in the presence of moisture, when sulfide oxidizes it produces thiosulfate anions as intermediate species and because thiosulfate anion has a higher equivalent electromobility than chloride anion due to its double negative electrical charge, it promotes the pit growth. Indeed, the positive electrical charges born by Fe2+ cations released in solution by Fe oxidation on the anodic zone inside the pit must be quickly compensated / neutralised by negative charges brought by the electrokinetic migration of anions in the capillary pit. Some of the electrochemical processes occurring in a capillary pit are the same than these encountered in capillary electrophoresis. Higher the anion electrokinetic migration rate, higher the rate of pitting corrosion. Electrokinetic transport of ions inside the pit can be the rate limiting step in the pit growth rate.
The Cacova Ierii mine is a large open pit mine in the north-western of Romania in Cluj County. Cacova Ierii represents one of the largest iron ore reserves in Romania having estimated reserves of 16.6 million tonnes of ore grading 42% iron metal. The mine has the capability to produce around 415,000 tonnes of iron ore/year.Dognecea mine
The Dognecea mine is a large open pit mine in the western of Romania in Caraş-Severin County, 23 km west of Reşiţa and 509 km north-west of the capital, Bucharest. Dognecea represents one of the largest iron ore reserves in Romania having estimated reserves of 9 million tonnes of ore. The mine produces around 10,000 tonnes of iron ore/year.Fortescue Metals Group
Fortescue Metals Group Ltd (Often referred to as FMG) is an Australian iron ore company. Fortescue is the fourth largest iron ore producer in the world after BHP Billiton, Rio Tinto, and Vale. The company has holdings of more than 87,000 km² in the Pilbara region of Western Australia, making it the largest tenement holder in the state, larger than both BHP Billiton and Rio Tinto.Ghelari mine
The Ghelari mine was a large open pit, also an underground iron ore mine in the western of Romania in Hunedoara County, 20 km south-west of Hunedoara and 411 km north-west of the capital, Bucharest. Ghelari represents one of the largest iron ore reserves in Romania having estimated reserves of 14 million tonnes of ore. The mine produced around 200,000 tonnes of iron ore/year.Iron Knob
Iron Knob is a town in the Australian state of South Australia on the Eyre Peninsula immediately south of the Eyre Highway. At the 2006 census, Iron Knob and the surrounding area had a population of 199. The town obtained its name from its proximity to large deposits of iron ore, most notably Iron Monarch which outcropped prominently from the relatively flat, surrounding landscape.Kudremukh Iron Ore Company
KIOCL Limited, formerly Kudremukh Iron Ore Company Limited is a Government of India enterprise with its head office and administrative activities in Bangalore. It has a pelletisation plant in Mangalore and had an iron ore mine in Kudremukh (Chikkamagaluru district). The Kudremukh mine, one of the largest iron ore mines in the world, was closed in 2006.
The captive mining took place at Kudremukh on the Western Ghats range. The mined ore was transported 110 km through slurry pipelines running through the districts of Udupi and Dakshina Kannada up to the pelletisation plant in Panambur, adjacent to the premises of the New Mangalore Port.
The pellet plant with a capacity of 3.5 million tons per annum was commissioned at Mangalore in 1987. The plant was stopped in 2011 but in 2014 the plant resumed producing and exporting pellets, running on ores supplied by NMDC Limited. The pellets have been shipped to countries like China, Iran, Japan, and Taiwan.
In 2017 there were plans to restart captive mining operations, now at Sanduru in Bellary district.Limonite
Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·nH2O, although this is not entirely accurate as the ratio of oxide to hydroxide can vary quite widely. Limonite is one of the three principal iron ores, the others being hematite and magnetite, and has been mined for the production of iron since at least 2500 BCE.List of countries by iron-ore exports
The following is a list of countries by iron ore exports. Data is for 2012 & 2016, in millions of United States dollars, as reported by The Observatory of Economic Complexity. Currently the top twenty countries (as of 2016) are listed.Lueta mine
The Lueta mine is a large open pit mine in central Romania in Harghita County, 36 km west of Miercurea Ciuc and 299 km north of the capital, Bucharest. Lueta represents one of the largest iron ore reserves in Romania having estimated reserves of 6 million tonnes of ore. The mine produces around 10,000 tonnes of iron ore/year.Mining industry of Nigeria
The mining of minerals in Nigeria accounts for only 0.3% of its GDP, due to the influence of its vast oil resources. The domestic mining industry is underdeveloped, leading to Nigeria having to import minerals that it could produce domestically, such as salt or iron ore. Rights to ownership of mineral resources is held by the Federal government of Nigeria, which grants titles to organizations to explore, mine, and sell mineral resources.
Organized mining began in 1903 when the Mineral Survey of the Northern Protectorates was created by the British colonial government. A year later, the Mineral Survey of the Southern Protectorates was founded. By the 1940s, Nigeria was a major producer of tin, columbite, and coal. The discovery of oil in 1956 hurt the mineral extraction industries, as government and industry both began to focus on this new resource. The Nigerian Civil War in the late 1960s led many expatriate mining experts to leave the country.
Mining regulation is handled by the Ministry of Solid Minerals Development, which oversees the management of all mineral resources. Mining law is codified in the Federal Minerals and Mining Act of 1999. Historically, Nigeria's mining industry was monopolized by state-owned public corporations. This led to a decline in productivity in almost all mineral industries. The Obasanjo administration began a process of selling off government-owned corporations to private investors in 1999.Ocna de Fier mine
The Ocna de Fier mine is a large open pit mine in the western of Romania in Caraş-Severin County, 25 km west of Reşiţa and 511 km north-west of the capital, Bucharest. Ocna de Fier represents the largest iron ore reserves in Romania having estimated reserves of 200 million tonnes of ore grading 25% iron metal. The mine produces around 10,000 tonnes of iron ore/year.Pilbara
The Pilbara () is a large, dry, thinly populated region in the north of Western Australia. It is known for its Aboriginal peoples; its ancient landscapes; the red earth; its vast mineral deposits, in particular iron ore; and as a global biodiversity hotspot for subterranean fauna.Rutland Railway Museum
Rutland Railway Museum, now trading as Rocks by Rail: The Living Ironstone Museum, is a heritage railway on part of a former Midland Railway mineral branch line. It is situated north east of Oakham, in Rutland, England.Siderite
Siderite is also the name of a type of iron meteorite.Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος sideros, “iron”. It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and manganese commonly substitute for the iron resulting in the siderite-smithsonite, siderite-magnesite and siderite-rhodochrosite solid solution series.Siderite has Mohs hardness of 3.75-4.25, a specific gravity of 3.96, a white streak and a vitreous lustre or pearly luster.
It crystallizes in the trigonal crystal system, and are rhombohedral in shape, typically with curved and striated faces. It also occurs in masses. Color ranges from yellow to dark brown or black, the latter being due to the presence of manganese.
Siderite is commonly found in hydrothermal veins, and is associated with barite, fluorite, galena, and others. It is also a common diagenetic mineral in shales and sandstones, where it sometimes forms concretions, which can encase three-dimensionally preserved fossils. In sedimentary rocks, siderite commonly forms at shallow burial depths and its elemental composition is often related to the depositional environment of the enclosing sediments. In addition, a number of recent studies have used the oxygen isotopic composition of sphaerosiderite (a type associated with soils) as a proxy for the isotopic composition of meteoric water shortly after deposition.Swedish iron-ore mining during World War II
Swedish iron ore was an important economic factor in the European theatre of World War II. Both the Allies and the Third Reich were keen on the control of the mining district in northernmost Sweden, surrounding the mining towns of Gällivare and Kiruna. The importance of this issue increased after other sources were cut off from Germany by the British sea blockade during the Battle of the Atlantic. Both the planned Anglo-French support of Finland in the Winter War, and the following German occupation of Denmark and Norway (Operation Weserübung) were to a large extent motivated by the wish to deny their respective enemies iron critical for wartime production of steel.Winston Churchill, then First Lord of the Admiralty, was particularly concerned about Swedish exports of iron ore to Germany, and pushed for the British government to take military action to end the trade. From the beginning of the war Churchill tried to persuade his cabinet colleagues to send a British fleet into the Baltic Sea to stop shipping reaching Germany from the two Swedish iron ore ports, Luleå and Oxelösund. The project was called Project Catherine and was planned by Admiral of the Fleet William Boyle, 12th Earl of Cork. However, events overtook this project and it was canceled. Later, when the Baltic ports froze over and the Germans began shipping the iron ore from the Norwegian port of Narvik, Churchill pushed for the Royal Navy to mine the west coast of Norway to prevent the Germans travelling inside neutral territorial waters to escape Allied Contraband Control measures.Tatanagar–Bilaspur section
The Tatanagar–Bilaspur section is part of the Howrah-Nagpur-Mumbai line and connects Tatanagar in the Indian state of Jharkhand and Bilaspur in Chhattisgarh. Part of one of the major trunk lines in the country, it passes through an industrial-mining area and handles high volumes of freight, particularly coal and iron ore.Teliuc mine
The Teliuc mine is a large open pit mine in the western of Romania in Hunedoara County, 15 km west of Hunedoara and 406 km north-west of the capital, Bucharest. Teliuc represents one of the largest iron ore reserves in Romania having estimated reserves of 3 million tonnes of ore. The mine produces around 100,000 tonnes of iron ore/year.Vale (company)
Vale S.A. (Portuguese pronunciation: [ˈvali]) is a Brazilian multinational corporation engaged in metals and mining and one of the largest logistics operators in Brazil.
Vale, formerly Companhia Vale do Rio Doce (the Sweet River Valley Company, referring to the Doce River), is the largest producer of iron ore and nickel in the world. Vale also produces manganese, ferroalloys, copper, bauxite, potash, kaolin, and cobalt, currently operating nine hydroelectricity plants, and a large network of railroads, ships, and ports used to transport its products.The company has had two catastrophic tailings dam failures in Brazil: Mariana, in 2015, and Brumadinho, in 2019; the Brumadinho dam disaster caused the company to lose its license to operate eight tailings dams in Minas Gerais, and its stock to lose nearly 25 percent in value.