Ion

An ion (/ˈaɪɒn, -ən/)[1] is an atom or molecule that has a net electrical charge. Since the charge of the electron (considered "negative" by convention) is equal and opposite to that of the proton (considered "positive" by convention), the net charge of an ion is non-zero due to its total number of electrons being unequal to its total number of protons. A cation is a positively charged ion, with fewer electrons than protons, while an anion is negatively charged, with more electrons than protons. Because of their opposite electric charges, cations and anions attract each other and readily form ionic compounds.

Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a medium, such as a gas, "ion pairs" are created by ion collisions, where each generated pair consists of a free electron and a positive ion.[2] Ions are also created by chemical interactions, such as the dissolution of a salt in liquids, or by other means, such as passing a direct current through a conducting solution, dissolving an anode via ionization.

History of discovery

The word ion comes from the Greek word ἰόν, ion, "going", the present participle of ἰέναι, ienai, "to go". This term was introduced (after a suggestion by William Whewell[3]) by English physicist and chemist Michael Faraday in 1834 for the then-unknown species that goes from one electrode to the other through an aqueous medium.[4][5] Faraday did not know the nature of these species, but he knew that since metals dissolved into and entered a solution at one electrode and new metal came forth from a solution at the other electrode; that some kind of substance has moved through the solution in a current. This conveys matter from one place to the other. In correspondence with Faraday, Whewell also coined the words anode and cathode, as well as anion and cation as ions that are attracted to the respective electrodes.[3]

Svante Arrhenius put forth, in his 1884 dissertation, his explanation of the fact that solid crystalline salts dissociate into paired charged particles when dissolved, for which he would win the 1903 Nobel Prize in Chemistry.[6] Arrhenius' explanation was that in forming a solution, the salt dissociates into Faraday's ions. Arrhenius proposed that ions formed even in the absence of an electric current.[7][8][9]

Characteristics

Ions in their gas-like state are highly reactive and will rapidly interact with ions of opposite charge to give neutral molecules or ionic salts. Ions are also produced in the liquid or solid state when salts interact with solvents (for example, water) to produce solvated ions, which are more stable, for reasons involving a combination of energy and entropy changes as the ions move away from each other to interact with the liquid. These stabilized species are more commonly found in the environment at low temperatures. A common example is the ions present in seawater, which are derived from dissolved salts.

As charged objects, ions are attracted to opposite electric charges (positive to negative, and vice versa) and repelled by like charges. When they move, their trajectories can be deflected by a magnetic field.

Electrons, due to their smaller mass and thus larger space-filling properties as matter waves, determine the size of atoms and molecules that possess any electrons at all. Thus, anions (negatively charged ions) are larger than the parent molecule or atom, as the excess electron(s) repel each other and add to the physical size of the ion, because its size is determined by its electron cloud. Cations are smaller than the corresponding parent atom or molecule due to the smaller size of the electron cloud. One particular cation (that of hydrogen) contains no electrons, and thus consists of a single proton - very much smaller than the parent hydrogen atom.

Anions and cations

Ions
Hydrogen atom (center) contains a single proton and a single electron. Removal of the electron gives a cation (left), whereas addition of an electron gives an anion (right). The hydrogen anion, with its loosely held two-electron cloud, has a larger radius than the neutral atom, which in turn is much larger than the bare proton of the cation. Hydrogen forms the only charge-+1 cation that has no electrons, but even cations that (unlike hydrogen) still retain one or more electrons are still smaller than the neutral atoms or molecules from which they are derived.

Since the electric charge on a proton is equal in magnitude to the charge on an electron, the net electric charge on an ion is equal to the number of protons in the ion minus the number of electrons.

An anion (−) (/ˈæn.aɪ.ən/), from the Greek word ἄνω (ánō), meaning "up",[10] is an ion with more electrons than protons, giving it a net negative charge (since electrons are negatively charged and protons are positively charged).[11]

A cation (+) (/ˈkæt.aɪ.ən/), from the Greek word κάτω (káto), meaning "down",[12] is an ion with fewer electrons than protons, giving it a positive charge.[13]

There are additional names used for ions with multiple charges. For example, an ion with a −2 charge is known as a dianion and an ion with a +2 charge is known as a dication. A zwitterion is a neutral molecule with positive and negative charges at different locations within that molecule.[14]

Cations and anions are measured by their ionic radius and they differ in relative size: "Cations are small, most of them less than 10−10 m (10−8 cm) in radius. But most anions are large, as is the most common Earth anion, oxygen. From this fact it is apparent that most of the space of a crystal is occupied by the anion and that the cations fit into the spaces between them."[15]

A cation has radius less than 0.8 × 10−10 m (0.8 Å) while an anion has radius greater than 1.3 × 10−10 m (1.3 Å).[16]

Natural occurrences

Ions are ubiquitous in nature and are responsible for diverse phenomena from the luminescence of the Sun to the existence of the Earth's ionosphere. Atoms in their ionic state may have a different colour from neutral atoms, and thus light absorption by metal ions gives the colour of gemstones. In both inorganic and organic chemistry (including biochemistry), the interaction of water and ions is extremely important; an example is the energy that drives breakdown of adenosine triphosphate (ATP). The following sections describe contexts in which ions feature prominently; these are arranged in decreasing physical length-scale, from the astronomical to the microscopic.

Related technology

Ions can be non-chemically prepared using various ion sources, usually involving high voltage or temperature. These are used in a multitude of devices such as mass spectrometers, optical emission spectrometers, particle accelerators, ion implanters, and ion engines.

As reactive charged particles, they are also used in air purification by disrupting microbes, and in household items such as smoke detectors.

As signalling and metabolism in organisms are controlled by a precise ionic gradient across membranes, the disruption of this gradient contributes to cell death. This is a common mechanism exploited by natural and artificial biocides, including the ion channels gramicidin and amphotericin (a fungicide).

Inorganic dissolved ions are a component of total dissolved solids, a widely-known indicator of water quality.

Detection of ionizing radiation

Ion chamber operation
Schematic of an ion chamber, showing drift of ions. Electrons drift faster than positive ions due to their much smaller mass.[2]
Electron avalanche
Avalanche effect between two electrodes. The original ionization event liberates one electron, and each subsequent collision liberates a further electron, so two electrons emerge from each collision: the ionizing electron and the liberated electron.

The ionizing effect of radiation on a gas is extensively used for the detection of radiation such as alpha, beta, gamma and X-rays. The original ionization event in these instruments results in the formation of an "ion pair"; a positive ion and a free electron, by ion impact by the radiation on the gas molecules. The ionization chamber is the simplest of these detectors, and collects all the charges created by direct ionization within the gas through the application of an electric field.[2]

The Geiger–Müller tube and the proportional counter both use a phenomenon known as a Townsend avalanche to multiply the effect of the original ionizing event by means of a cascade effect whereby the free electrons are given sufficient energy by the electric field to release further electrons by ion impact.

Chemistry

Denoting the charged state

Ions notation
Equivalent notations for an iron atom (Fe) that lost two electrons, referred to as ferrous.

When writing the chemical formula for an ion, its net charge is written in superscript immediately after the chemical structure for the molecule/atom. The net charge is written with the magnitude before the sign; that is, a doubly charged cation is indicated as 2+ instead of +2. However, the magnitude of the charge is omitted for singly charged molecules/atoms; for example, the sodium cation is indicated as Na+ and not Na1+.

An alternative (and acceptable) way of showing a molecule/atom with multiple charges is by drawing out the signs multiple times, this is often seen with transition metals. Chemists sometimes circle the sign; this is merely ornamental and does not alter the chemical meaning. All three representations of Fe2+
shown in the figure, are thus equivalent.

Ions notation2
Mixed Roman numerals and charge notations for the uranyl ion. The oxidation state of the metal is shown as superscripted Roman numerals, whereas the charge of the entire complex is shown by the angle symbol together with the magnitude and sign of the net charge.

Monatomic ions are sometimes also denoted with Roman numerals; for example, the Fe2+
example seen above is occasionally referred to as Fe(II) or FeII. The Roman numeral designates the formal oxidation state of an element, whereas the superscripted numerals denote the net charge. The two notations are, therefore, exchangeable for monatomic ions, but the Roman numerals cannot be applied to polyatomic ions. However, it is possible to mix the notations for the individual metal centre with a polyatomic complex, as shown by the uranyl ion example.

Sub-classes

If an ion contains unpaired electrons, it is called a radical ion. Just like uncharged radicals, radical ions are very reactive. Polyatomic ions containing oxygen, such as carbonate and sulfate, are called oxyanions. Molecular ions that contain at least one carbon to hydrogen bond are called organic ions. If the charge in an organic ion is formally centred on a carbon, it is termed a carbocation (if positively charged) or carbanion (if negatively charged).

Formation

Formation of monatomic ions

Monatomic ions are formed by the gain or loss of electrons to the valence shell (the outer-most electron shell) in an atom. The inner shells of an atom are filled with electrons that are tightly bound to the positively charged atomic nucleus, and so do not participate in this kind of chemical interaction. The process of gaining or losing electrons from a neutral atom or molecule is called ionization.

Atoms can be ionized by bombardment with radiation, but the more usual process of ionization encountered in chemistry is the transfer of electrons between atoms or molecules. This transfer is usually driven by the attaining of stable ("closed shell") electronic configurations. Atoms will gain or lose electrons depending on which action takes the least energy.

For example, a sodium atom, Na, has a single electron in its valence shell, surrounding 2 stable, filled inner shells of 2 and 8 electrons. Since these filled shells are very stable, a sodium atom tends to lose its extra electron and attain this stable configuration, becoming a sodium cation in the process

Na → Na+
+
e

On the other hand, a chlorine atom, Cl, has 7 electrons in its valence shell, which is one short of the stable, filled shell with 8 electrons. Thus, a chlorine atom tends to gain an extra electron and attain a stable 8-electron configuration, becoming a chloride anion in the process:

Cl +
e
Cl

This driving force is what causes sodium and chlorine to undergo a chemical reaction, wherein the "extra" electron is transferred from sodium to chlorine, forming sodium cations and chloride anions. Being oppositely charged, these cations and anions form ionic bonds and combine to form sodium chloride, NaCl, more commonly known as table salt.

Na+
+ Cl
→ NaCl

Formation of polyatomic and molecular ions

Nitrate-ion-elpot
An electrostatic potential map of the nitrate ion (NO
3
). The 3-dimensional shell represents a single arbitrary isopotential.

Polyatomic and molecular ions are often formed by the gaining or losing of elemental ions such as a proton, H+
, in neutral molecules. For example, when ammonia, NH
3
, accepts a proton, H+
—a process called protonation—it forms the ammonium ion, NH+
4
. Ammonia and ammonium have the same number of electrons in essentially the same electronic configuration, but ammonium has an extra proton that gives it a net positive charge.

Ammonia can also lose an electron to gain a positive charge, forming the ion NH+
3
. However, this ion is unstable, because it has an incomplete valence shell around the nitrogen atom, making it a very reactive radical ion.

Due to the instability of radical ions, polyatomic and molecular ions are usually formed by gaining or losing elemental ions such as H+
, rather than gaining or losing electrons. This allows the molecule to preserve its stable electronic configuration while acquiring an electrical charge.

Ionization potential

The energy required to detach an electron in its lowest energy state from an atom or molecule of a gas with less net electric charge is called the ionization potential, or ionization energy. The nth ionization energy of an atom is the energy required to detach its nth electron after the first n − 1 electrons have already been detached.

Each successive ionization energy is markedly greater than the last. Particularly great increases occur after any given block of atomic orbitals is exhausted of electrons. For this reason, ions tend to form in ways that leave them with full orbital blocks. For example, sodium has one valence electron in its outermost shell, so in ionized form it is commonly found with one lost electron, as Na+
. On the other side of the periodic table, chlorine has seven valence electrons, so in ionized form it is commonly found with one gained electron, as Cl
. Caesium has the lowest measured ionization energy of all the elements and helium has the greatest.[17] In general, the ionization energy of metals is much lower than the ionization energy of nonmetals, which is why, in general, metals will lose electrons to form positively charged ions and nonmetals will gain electrons to form negatively charged ions.

Ionic bonding

Ionic bonding is a kind of chemical bonding that arises from the mutual attraction of oppositely charged ions. Ions of like charge repel each other, and ions of opposite charge attract each other. Therefore, ions do not usually exist on their own, but will bind with ions of opposite charge to form a crystal lattice. The resulting compound is called an ionic compound, and is said to be held together by ionic bonding. In ionic compounds there arise characteristic distances between ion neighbours from which the spatial extension and the ionic radius of individual ions may be derived.

The most common type of ionic bonding is seen in compounds of metals and nonmetals (except noble gases, which rarely form chemical compounds). Metals are characterized by having a small number of electrons in excess of a stable, closed-shell electronic configuration. As such, they have the tendency to lose these extra electrons in order to attain a stable configuration. This property is known as electropositivity. Non-metals, on the other hand, are characterized by having an electron configuration just a few electrons short of a stable configuration. As such, they have the tendency to gain more electrons in order to achieve a stable configuration. This tendency is known as electronegativity. When a highly electropositive metal is combined with a highly electronegative nonmetal, the extra electrons from the metal atoms are transferred to the electron-deficient nonmetal atoms. This reaction produces metal cations and nonmetal anions, which are attracted to each other to form a salt.

Common ions

Common cations[18]
Common name Formula Historic name
Simple cations
Aluminium Al3+
Barium Ba2+
Beryllium Be2+
Calcium Ca2+
Chromium(III) Cr3+
Copper(I) Cu+ cuprous
Copper(II) Cu2+ cupric
Hydrogen H+
Iron(II) Fe2+ ferrous
Iron(III) Fe3+ ferric
Lead(II) Pb2+ plumbous
Lead(IV) Pb4+ plumbic
Lithium Li+
Magnesium Mg2+
Manganese(II) Mn2+
Mercury(II) Hg2+ mercuric
Potassium K+ kalic
Silver Ag+ argentous
Sodium Na+ natric
Strontium Sr2+
Tin(II) Sn2+ stannous
Tin(IV) Sn4+ stannic
Zinc Zn2+
Polyatomic cations
Ammonium NH+
4
Hydronium H3O+
Mercury(I) Hg2+
2
mercurous
Common anions[18]
Formal name Formula Alt. name
Simple anions
Azide N
3
Bromide Br
Chloride Cl
Fluoride F
Hydride H
Iodide I
Nitride N3−
Oxide O2−
Sulfide S2−
Oxoanions (Polyatomic ions)[18]
Carbonate CO2−
3
Chlorate ClO
3
Chromate CrO2−
4
Dichromate Cr
2
O2−
7
Dihydrogen phosphate H
2
PO
4
Hydrogen carbonate HCO
3
bicarbonate
Hydrogen sulfate HSO
4
bisulfate
Hydrogen sulfite HSO
3
bisulfite
Hydroxide OH
Hypochlorite ClO
Monohydrogen phosphate HPO2−
4
Nitrate NO
3
Nitrite NO
2
Perchlorate ClO
4
Permanganate MnO
4
Peroxide O2−
2
Phosphate PO3−
4
Sulfate SO2−
4
Sulfite SO2−
3
Superoxide O
2
Thiosulfate S
2
O2−
3
Silicate SiO4−
4
Metasilicate SiO2−
3
Aluminium silicate AlSiO
4
Anions from organic acids
Acetate CH
3
COO
ethanoate
Formate HCOO
methanoate
Oxalate C
2
O2−
4
ethanedioate
Cyanide CN

See also

References

  1. ^ "Ion" entry in Collins English Dictionary.
  2. ^ a b c Knoll, Glenn F (1999). Radiation detection and measurement (3rd ed.). New York: Wiley. ISBN 978-0-471-07338-3.
  3. ^ a b Frank A. J. L. James (ed.). The Correspondence of Michael Faraday, Vol. 2: 1832-1840. p. 183. ISBN 9780863412493.
  4. ^ Michael Faraday (1791-1867). UK: BBC.
  5. ^ "Online etymology dictionary". Retrieved 2011-01-07.
  6. ^ "The Nobel Prize in Chemistry 1903". www.nobelprize.org.
  7. ^ Harris, William; Levey, Judith, eds. (1975). The New Columbia Encyclopedia (4th ed.). New York City: Columbia University. p. 155. ISBN 978-0-231-03572-9.
  8. ^ Goetz, Philip W. (1992). McHenry, Charles (ed.). The New Encyclopædia Britannica. Chicago: Encyclopaedia Britannica Inc. 1 (15 ed.). Chicago: Encyclopædia Britannica, Inc. p. 587. Bibcode:1991neb..book.....G. ISBN 978-0-85229-553-3.
  9. ^ Cillispie, Charles, ed. (1970). Dictionary of Scientific Biography (1 ed.). New York City: Charles Scribner's Sons. pp. 296–302. ISBN 978-0-684-10112-5.
  10. ^ Oxford University Press (2013). "Oxford Reference: OVERVIEW anion". oxfordreference.com.
  11. ^ University of Colorado Boulder (November 21, 2013). "Atoms and Elements, Isotopes and Ions". colorado.edu.
  12. ^ Oxford University Press (2013). "Oxford Reference: OVERVIEW cation". oxfordreference.com.
  13. ^ Douglas W. Haywick, Ph.D.; University of South Alabama (2007–2008). "Elemental Chemistry" (PDF). usouthal.edu.
  14. ^ Purdue University (November 21, 2013). "Amino Acids". purdue.edu.
  15. ^ Frank Press & Raymond Siever (1986) Earth, 14th edition, p. 63, W.H. Freeman and Company ISBN 0-7167-1743-3
  16. ^ Linus Pauling (1960) Nature of the Chemical Bond, p. 544, at Google Books
  17. ^ Chemical elements listed by ionization energy. Lenntech.com
  18. ^ a b c "Common Ions and Their Charges" (PDF).
Acetate

An acetate is a salt formed by the combination of acetic acid with an alkaline, earthy, metallic or nonmetallic and other base. "Acetate" also describes the conjugate base or ion (specifically, the negatively charged ion called an anion) typically found in aqueous solution and written with the chemical formula C2H3O−2. The neutral molecules formed by the combination of the acetate ion and a positive ion (called a cation) are also commonly called "acetates" (hence, acetate of lead, acetate of aluminum, etc.). The simplest of these is hydrogen acetate (called acetic acid) with corresponding salts, esters, and the polyatomic anion CH3CO−2, or CH3COO−.

Most of the approximately 5 billion kilograms of acetic acid produced annually in industry are used in the production of acetates, which usually take the form of polymers. In nature, acetate is the most common building block for biosynthesis. For example, the fatty acids are produced by connecting the two carbon atoms from acetate to a growing fatty acid.

Bicarbonate

In inorganic chemistry, bicarbonate (IUPAC-recommended nomenclature: hydrogencarbonate) is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula HCO−3.

Bicarbonate serves a crucial biochemical role in the physiological pH buffering system.The term "bicarbonate" was coined in 1814 by the English chemist William Hyde Wollaston. The prefix "bi" in "bicarbonate" comes from an outdated naming system and is based on the observation that there is twice as much carbonate (CO2−3) per sodium ion in sodium bicarbonate (NaHCO3) and other bicarbonates than in sodium carbonate (Na2CO3) and other carbonates. The name lives on as a trivial name.

Chloride

The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts such as sodium chloride are often very soluble in water. It is an essential electrolyte located in all body fluids responsible for maintaining acid/base balance, transmitting nerve impulses and regulating fluid in and out of cells. Less frequently, the word chloride may also form part of the "common" name of chemical compounds in which one or more chlorine atoms are covalently bonded. For example, methyl chloride, with the standard name chloromethane (see IUPAC books) is an organic compound with a covalent C−Cl bond in which the chlorine is not an anion.

Coordination complex

In chemistry, a coordination complex consists of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those of transition metals, are coordination complexes. A coordination complex whose centre is a metal atom is called a metal complex.

Helium hydride ion

The helium hydride ion or hydridohelium(1+) ion is a cation (positively charged ion) with chemical formula HeH+. It consists of a helium atom bonded to a hydrogen atom, with one electron removed. It is the lightest heteronuclear ion, and is believed to be one of the first compounds formed in the Universe after the Big Bang.The ion was first produced in a laboratory in 1925. It is stable in isolation, but extremely reactive, and cannot be prepared in bulk, because it would react with any other molecule with which it came in contact. Noted as the strongest known acid, its occurrence in the interstellar medium has been conjectured since the 1970s, and it was finally detected in April 2019.

Hydrogen ion

A hydrogen ion is created when a hydrogen atom loses or gains an electron. A positively charged hydrogen ion (or proton) can readily combine with other particles and therefore is only seen isolated when it is in a gaseous state or a nearly particle-free space. Due to its extremely high charge density of approximately 2×1010 times that of a sodium ion, the bare hydrogen ion cannot exist freely in solution as it readily hydrates, i.e., bonds quickly. The hydrogen ion is recommended by IUPAC as a general term for all ions of hydrogen and its isotopes.

Depending on the charge of the ion, two different classes can be distinguished: positively charged ions and negatively charged ions.

Ion Life

Ion Life is an American digital broadcast television network that is owned by Ion Media.

Originally from its February 2007 launch, Ion Life had primarily featured lifestyle programming, consisting of shows pertaining to subjects such as health and wellness, cooking, home decor and travel. In 2019 with expanded cable carriage, Ion Media switched the network's schedule to match the main format of Ion Television, featuring day-long marathons of one series per day, along with a late-night block of paid programming.

Ion Life is carried mainly as a digital multicast service on Ion Media Networks-owned stations as well as select Ion Television affiliates (and is primarily placed on the third subchannel); its base national feed is also available on select cable and satellite providers. In a few select markets, Ion Life has main channel placement, allowing it must-carry coverage on local cable and satellite services.

Ion Television

Ion Television is an American free-to-air television network that is owned by Ion Media. The network first began broadcasting on August 31, 1998 as Pax TV (commonly referred to as Pax; stylized as PAX), focusing primarily on family-oriented entertainment programming; it rebranded as i: Independent Television on July 1, 2005, converting into a general entertainment network featuring mainly recent and older acquired programs; the network adopted its current identity as Ion Television on January 29, 2007.

Ion Television is available throughout most of the United States through its group of 62 owned-and-operated stations, as well as through distribution on cable and satellite providers; since 2014, the network has also increased affiliate distribution in several markets through the digital subchannels of local television stations owned by companies such as NBCUniversal Owned Television Stations and Nexstar Media Group where the network is unable to maintain a main channel affiliation with or own a standalone station, for the same purpose as the distribution of Ion's main network feed via cable and satellite. The network's stations cover all of the top 20 U.S. markets and 37 of the top 50 markets. Ion's owned-and-operated stations cover 64.8% of the United States population, by far the most of any U.S. station ownership group; it is able to circumvent the legal limit of covering 39% of the population because all of its stations operate on the UHF television band, which is subject to a discount (which in the digital age has proven controversial with other broadcast groups and FCC rulings between presidential administrations, though not with Ion itself) in regard to that limit.

Ion channel

Ion channels are pore-forming membrane proteins that allow ions to pass through the channel pore. Their functions include establishing a resting membrane potential, shaping action potentials and other electrical signals by gating the flow of ions across the cell membrane, controlling the flow of ions across secretory and epithelial cells, and regulating cell volume. Ion channels are present in the membranes of all excitable cells. Ion channels are one of the two classes of ionophoric proteins, the other being ion transporters.The study of ion channels often involves biophysics, electrophysiology, and pharmacology, while using techniques including voltage clamp, patch clamp, immunohistochemistry, X-ray crystallography, fluoroscopy, and RT-PCR. Their classification as molecules is referred to as channelomics.

Ion thruster

An ion thruster or ion drive is a form of electric propulsion used for spacecraft propulsion. It creates thrust by accelerating cations by utilizing electricity. The term refers strictly to gridded electrostatic ion thrusters, and is often incorrectly loosely applied to all electric propulsion systems including electromagnetic plasma thrusters.An ion thruster ionizes a neutral gas by extracting some electrons out of atoms, creating a cloud of positive ions. These thrusters rely mainly on electrostatics as ions are accelerated by the Coulomb force along an electric field. Temporarily stored electrons are finally reinjected by a neutralizer in the cloud of ions after it has passed through the electrostatic grid, so the gas becomes neutral again and can freely disperse in space without any further electrical interaction with the thruster. Electromagnetic thrusters on the contrary use the Lorentz force to accelerate all species (free electrons as well as positive and negative ions) in the same direction whatever their electric charge, and are specifically referred as plasma propulsion engines, where the electric field is not in the direction of the acceleration.Ion thrusters in operational use have an input power need of 1–7 kW, exhaust velocity 20–50 km/s, thrust 25–250 millinewtons and efficiency 65–80% though experimental versions have achieved 100 kW, 5N.The Deep Space 1 spacecraft, powered by an ion thruster, changed velocity by 4.3 km/s while consuming less than 74 kilograms of xenon. The Dawn spacecraft broke the record, with a velocity change of 10 km/s.Applications include control of the orientation and position of orbiting satellites (some satellites have dozens of low-power ion thrusters) and use as a main propulsion engine for low-mass robotic space vehicles (such as Deep Space 1 and Dawn).Ion thrust engines are practical only in the vacuum of space and cannot take vehicles through the atmosphere because ion engines do not work in the presence of ions outside the engine. Additionally, the engine's minuscule thrust cannot overcome any significant air resistance. Spacecraft rely on conventional chemical rockets to initially reach orbit.

Ligand-gated ion channel

Ligand-gated ion channels (LICs, LGIC), also commonly referred to as ionotropic receptors, are a group of transmembrane ion-channel proteins which open to allow ions such as Na+, K+, Ca2+, and/or Cl− to pass through the membrane in response to the binding of a chemical messenger (i.e. a ligand), such as a neurotransmitter.When a presynaptic neuron is excited, it releases a neurotransmitter from vesicles into the synaptic cleft. The neurotransmitter then binds to receptors located on the postsynaptic neuron. If these receptors are ligand-gated ion channels, a resulting conformational change opens the ion channels, which leads to a flow of ions across the cell membrane. This, in turn, results in either a depolarization, for an excitatory receptor response, or a hyperpolarization, for an inhibitory response.

These receptor proteins are typically composed of at least two different domains: a transmembrane domain which includes the ion pore, and an extracellular domain which includes the ligand binding location (an allosteric binding site). This modularity has enabled a 'divide and conquer' approach to finding the structure of the proteins (crystallising each domain separately). The function of such receptors located at synapses is to convert the chemical signal of presynaptically released neurotransmitter directly and very quickly into a postsynaptic electrical signal. Many LICs are additionally modulated by allosteric ligands, by channel blockers, ions, or the membrane potential. LICs are classified into three superfamilies which lack evolutionary relationship: cys-loop receptors, ionotropic glutamate receptors and ATP-gated channels.

Lithium-ion battery

A lithium-ion battery or Li-ion battery (abbreviated as LIB) is a type of rechargeable battery, first proposed by chemist M Stanley Whittingham at Exxon in the 1970s. Today lithium-ion batteries are commonly used for portable electronics and electric vehicles and are growing in popularity for military and aerospace applications.In the batteries lithium ions move from the negative electrode to the positive electrode during discharge and back when charging. Li-ion batteries use an intercalated lithium compound as one electrode material, compared to the metallic lithium used in a non-rechargeable lithium battery. The batteries have a high energy density, no memory effect (other than LFP cells) and low self-discharge. They can however be a safety hazard since they contain a flammable electrolyte, and if damaged or incorrectly charged can lead to explosions and fires. Samsung were forced to recall Galaxy Note handsets following lithium-ion fires, and have been several incidents involving batteries on Boeing 787s.

Chemistry, performance, cost and safety characteristics vary across LIB types. Handheld electronics mostly use LIBs based on lithium cobalt oxide (LiCoO2), which offers high energy density but presents safety risks, especially when damaged. Lithium iron phosphate (LiFePO4), lithium ion manganese oxide battery (LiMn2O4, Li2MnO3, or LMO), and lithium nickel manganese cobalt oxide (LiNiMnCoO2 or NMC) offer lower energy density but longer lives and less likelihood of fire or explosion. Such batteries are widely used for electric tools, medical equipment, and other roles. NMC in particular is a leading contender for automotive applications.

Research areas for lithium-ion batteries include life extension, energy density, safety, cost reduction, and charging speed, among others. Research has also been under way for aqueous lithium-ion batteries, which have demonstrated fewer potential safety hazards due to their use of non-flammable electrolytes.

Lithium polymer battery

A lithium polymer battery, or more correctly lithium-ion polymer battery (abbreviated as LiPo, LIP, Li-poly, lithium-poly and others), is a rechargeable battery of lithium-ion technology using a polymer electrolyte instead of a liquid electrolyte. High conductivity semisolid (gel) polymers form this electrolyte. These batteries provide higher specific energy than other lithium battery types and are used in applications where weight is a critical feature, like mobile devices and radio-controlled aircraft.

Mass spectrometry

Mass spectrometry (MS) is an analytical technique that ionizes chemical species and sorts the ions into a spectrum based on their mass-to-charge ratio. In simpler terms, a mass spectrum measures the masses within a sample. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures.

A mass spectrum is a plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical structures of molecules and other chemical compounds.

In a typical MS procedure, a sample, which may be solid, liquid, or gas, is ionized, for example by bombarding it with electrons. This may cause some of the sample's molecules to break into charged fragments. These ions are then separated according to their mass-to-charge ratio, typically by accelerating them and subjecting them to an electric or magnetic field: ions of the same mass-to-charge ratio will undergo the same amount of deflection. The ions are detected by a mechanism capable of detecting charged particles, such as an electron multiplier. Results are displayed as spectra of the relative abundance of detected ions as a function of the mass-to-charge ratio. The atoms or molecules in the sample can be identified by correlating known masses (e.g. an entire molecule) to the identified masses or through a characteristic fragmentation pattern.

PH

In chemistry, pH () is a scale used to specify how acidic or basic a water-based solution is. Acidic solutions have a lower pH, while basic solutions have a higher pH. At room temperature (25 °C), pure water is neither acidic nor basic and has a pH of 7.

The pH scale is logarithmic and approximates the negative of the base 10 logarithm of the molar concentration (measured in units of moles per liter) of hydrogen ions in a solution. More precisely it is the negative of the base 10 logarithm of the activity of the hydrogen ion. At 25 °C, solutions with a pH less than 7 are acidic and solutions with a pH greater than 7 are basic. The neutral value of the pH depends on the temperature, being lower than 7 if the temperature increases. Contrary to popular belief, the pH value can be less than 0 or greater than 14 for very strong acids and bases respectively.The pH scale is traceable to a set of standard solutions whose pH is established by international agreement. Primary pH standard values are determined using a concentration cell with transference, by measuring the potential difference between a hydrogen electrode and a standard electrode such as the silver chloride electrode. The pH of aqueous solutions can be measured with a glass electrode and a pH meter, or a color-changing indicator. Measurements of pH are important in chemistry, agronomy, medicine, water treatment, and many other applications.

Phosphate

A phosphate is a chemical derivative of phosphoric acid. The phosphate ion (PO3−4) is an inorganic chemical, the conjugate base that can form many different salts. In organic chemistry, a phosphate, or organophosphate, is an ester of phosphoric acid. Of the various phosphoric acids and phosphates, organic phosphates are important in biochemistry and biogeochemistry (and, consequently, in ecology), and inorganic phosphates are mined to obtain phosphorus for use in agriculture and industry. At elevated temperatures in the solid state, phosphates can condense to form pyrophosphates.

In biology, adding phosphates to—and removing them from—proteins in cells are both pivotal in the regulation of metabolic processes. Referred to as phosphorylation and dephosphorylation, respectively, they are important ways that energy is stored and released in living systems.

Qubo

Qubo ( KEW-boh; stylized as qubo) is an American free-to-air children's entertainment programming service. Qubo consists of a 24-hour television network, alternately known as Qubo Channel (which is available as a digital terrestrial television on owned-and-operated stations and some affiliates of corporate sister Ion Television, and on some pay television providers), a video on demand service, and the branding of a weekly programming block on Ion Television under the name "Qubo Kids Corner".

Sodium

Sodium is a chemical element with symbol Na (from Latin natrium) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table, because it has a single electron in its outer shell, which it readily donates, creating a positively charged ion—the Na+ cation. Its only stable isotope is 23Na. The free metal does not occur in nature, and must be prepared from compounds. Sodium is the sixth most abundant element in the Earth's crust and exists in numerous minerals such as feldspars, sodalite, and rock salt (NaCl). Many salts of sodium are highly water-soluble: sodium ions have been leached by the action of water from the Earth's minerals over eons, and thus sodium and chlorine are the most common dissolved elements by weight in the oceans.

Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful sodium compounds, sodium hydroxide (lye) is used in soap manufacture, and sodium chloride (edible salt) is a de-icing agent and a nutrient for animals including humans.

Sodium is an essential element for all animals and some plants. Sodium ions are the major cation in the extracellular fluid (ECF) and as such are the major contributor to the ECF osmotic pressure and ECF compartment volume. Loss of water from the ECF compartment increases the sodium concentration, a condition called hypernatremia. Isotonic loss of water and sodium from the ECF compartment decreases the size of that compartment in a condition called ECF hypovolemia.

By means of the sodium-potassium pump, living human cells pump three sodium ions out of the cell in exchange for two potassium ions pumped in; comparing ion concentrations across the cell membrane, inside to outside, potassium measures about 40:1, and sodium, about 1:10. In nerve cells, the electrical charge across the cell membrane enables transmission of the nerve impulse—an action potential—when the charge is dissipated; sodium plays a key role in that activity.

Sulfate

The sulfate or sulphate (see spelling differences) ion is a polyatomic anion with the empirical formula SO2−4. Sulfate is the spelling recommended by IUPAC, but sulphate is used in British English. Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many are prepared from that acid.

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