Group 11 element

Group 11, by modern IUPAC numbering,[1] is a group of chemical elements in the periodic table, consisting of copper (Cu), silver (Ag), and gold (Au). Roentgenium (Rg) is also placed in this group in the periodic table, although no chemical experiments have yet been carried out to confirm that it behaves like the heavier homologue to gold. Group 11 is also known as the coinage metals, due to their former usage. They were most likely the first three elements discovered.[2] Copper, silver, and gold all occur naturally in elemental form.

Group 11 in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
group 10  group 12
IUPAC group number 11
Name by element copper group
Trivial name coinage metals
CAS group number
(US, pattern A-B-A)
IB
old IUPAC number
(Europe, pattern A-B)
IB

↓ Period
4
Native copper
Copper (Cu)
29 Transition metal
5
Silver dendritic crystal
Silver (Ag)
47 Transition metal
6
Gold crystals
Gold (Au)
79 Transition metal
7 Roentgenium (Rg)
111 unknown chemical properties

Legend
primordial element
synthetic element
Atomic number color:
black=solid

History

All the elements of the group except roentgenium have been known since prehistoric times, as all of them occur in metallic form in nature and no extraction metallurgy is necessary to produce them.

Roentgenium was made in 1994 by bombarding nickel-64 atoms into bismuth-209 to make roentgenium-272.[3]

Characteristics

Like other groups, the members of this family show patterns in electron configuration, especially in the outermost shells, resulting in trends in chemical behavior, although roentgenium is probably an exception:

Z Element No. of electrons/shell
29 copper 2, 8, 18, 1
47 silver 2, 8, 18, 18, 1
79 gold 2, 8, 18, 32, 18, 1
111 roentgenium 2, 8, 18, 32, 32, 18, 1 (predicted)

All Group 11 elements are relatively inert, corrosion-resistant metals. Copper and gold are colored.

These elements have low electrical resistivity so they are used for wiring. Copper is the cheapest and most widely used. Bond wires for integrated circuits are usually gold. Silver and silver-plated copper wiring are found in some special applications.

Occurrence

Copper occurs in its native form in Chile, China, Mexico, Russia and the USA. Various natural ores of copper are: copper pyrites (CuFeS2), cuprite or ruby copper (Cu2O), copper glance (Cu2S), malachite, (Cu(OH)2CuCO3), and azurite (Cu(OH)22CuCO3).

Copper pyrite is the principal ore, and yields nearly 76% of the world production of copper.

Production

Silver is found in native form, as an alloy with gold (electrum), and in ores containing sulfur, arsenic, antimony or chlorine. Ores include argentite (Ag2S), chlorargyrite (AgCl) which includes horn silver, and pyrargyrite (Ag3SbS3). Silver is extracted using the Parkes process.

Applications

These metals, especially silver, have unusual properties that make them essential for industrial applications outside of their monetary or decorative value. They are all excellent conductors of electricity. The most conductive of all metals are silver, copper and gold in that order. Silver is also the most thermally conductive element, and the most light reflecting element. Silver also has the unusual property that the tarnish that forms on silver is still highly electrically conductive.

Copper is used extensively in electrical wiring and circuitry. Gold contacts are sometimes found in precision equipment for their ability to remain corrosion-free. Silver is used widely in mission-critical applications as electrical contacts, and is also used in photography (because silver nitrate reverts to metal on exposure to light), agriculture, medicine, audiophile and scientific applications.

Gold, silver, and copper are quite soft metals and so are easily damaged in daily use as coins. Precious metal may also be easily abraded and worn away through use. In their numismatic functions these metals must be alloyed with other metals to afford coins greater durability. The alloying with other metals makes the resulting coins harder, less likely to become deformed and more resistant to wear.

Gold coins: Gold coins are typically produced as either 90% gold (e.g. with pre-1933 US coins), or 22 carat (91.66%) gold (e.g. current collectible coins and Krugerrands), with copper and silver making up the remaining weight in each case. Bullion gold coins are being produced with up to 99.999% gold (in the Canadian Gold Maple Leaf series).

Silver coins: Silver coins are typically produced as either 90% silver – in the case of pre 1965 US minted coins (which were circulated in many countries), or sterling silver (92.5%) coins for pre-1920 British Commonwealth and other silver coinage, with copper making up the remaining weight in each case. Old European coins were commonly produced with 83.5% silver. Modern silver bullion coins are often produced with purity varying between 99.9% to 99.999%.

Copper coins: Copper coins are often of quite high purity, around 97%, and are usually alloyed with small amounts of zinc and tin.

Inflation has caused the face value of coins to fall below the hard currency value of the historically used metals. This had led to most modern coins being made of base metalscopper nickel (around 80:20, silver in color) is popular as are nickel-brass (copper (75), nickel (5) and zinc (20), gold in color), manganese-brass (copper, zinc, manganese, and nickel), bronze, or simple plated steel.

Biological role and toxicity

Copper, although toxic in excessive amounts, is essential for life. Copper is shown to have antimicrobial properties which make it useful for hospital doorknobs to keep diseases from being spread. Eating food in copper containers is known to increase the risk of copper toxicity.

Elemental gold and silver have no known toxic effects or biological use, although gold salts can be toxic to liver and kidney tissue.[4][5] Like copper, silver also has antimicrobial properties. The prolonged use of preparations containing gold or silver can also lead to the accumulation of these metals in body tissue; the results are the irreversible but apparently harmless pigmentation conditions known as chrysiasis and argyria respectively.

Due to being short lived and radioactive, roentgenium has no biological use but it is likely extremely harmful due to its radioactivity.

References

  1. ^ Fluck, E. (1988). "New Notations in the Periodic Table" (PDF). Pure Appl. Chem. IUPAC. 60 (3): 431–436. doi:10.1351/pac198860030431. Retrieved 24 March 2012.
  2. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 1173. ISBN 978-0-08-037941-8.
  3. ^ Hofmann, S.; Ninov, V.; Heßberger, F.P.; Armbruster, P.; Folger, H.; Münzenberg, G.; Schött, H. J.; Popeko, A. G.; Yeremin, A. V.; Andreyev, A. N.; Saro, S.; Janik, R.; Leino, M. (1995). "The new element 111". Zeitschrift für Physik A. 350 (4): 281–282. Bibcode:1995ZPhyA.350..281H. doi:10.1007/BF01291182.
  4. ^ Wright, I. H.; Vesey, C. J. (1986). "Acute poisoning with gold cyanide". Anaesthesia. 41 (79): 936–939. doi:10.1111/j.1365-2044.1986.tb12920.x. PMID 3022615.
  5. ^ Wu, Ming-Ling; Tsai, Wei-Jen; Ger, Jiin; Deng, Jou-Fang; Tsay, Shyh-Haw; Yang, Mo-Hsiung. (2001). "Cholestatic Hepatitis Caused by Acute Gold Potassium Cyanide Poisoning". Clinical Toxicology. 39 (7): 739–743. doi:10.1081/CLT-100108516. PMID 11778673.
Alkali metal

The alkali metals are a group (column) in the periodic table consisting of the chemical elements lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). This group lies in the s-block of the periodic table of elements as all alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of group trends in properties in the periodic table, with elements exhibiting well-characterised homologous behaviour.

The alkali metals are all shiny, soft, highly reactive metals at standard temperature and pressure and readily lose their outermost electron to form cations with charge +1. They can all be cut easily with a knife due to their softness, exposing a shiny surface that tarnishes rapidly in air due to oxidation by atmospheric moisture and oxygen (and in the case of lithium, nitrogen). Because of their high reactivity, they must be stored under oil to prevent reaction with air, and are found naturally only in salts and never as the free elements. Caesium, the fifth alkali metal, is the most reactive of all the metals. In the modern IUPAC nomenclature, the alkali metals comprise the group 1 elements, excluding hydrogen (H), which is nominally a group 1 element but not normally considered to be an alkali metal as it rarely exhibits behaviour comparable to that of the alkali metals. All the alkali metals react with water, with the heavier alkali metals reacting more vigorously than the lighter ones.

All of the discovered alkali metals occur in nature as their compounds: in order of abundance, sodium is the most abundant, followed by potassium, lithium, rubidium, caesium, and finally francium, which is very rare due to its extremely high radioactivity; francium occurs only in the minutest traces in nature as an intermediate step in some obscure side branches of the natural decay chains. Experiments have been conducted to attempt the synthesis of ununennium (Uue), which is likely to be the next member of the group, but they have all met with failure. However, ununennium may not be an alkali metal due to relativistic effects, which are predicted to have a large influence on the chemical properties of superheavy elements; even if it does turn out to be an alkali metal, it is predicted to have some differences in physical and chemical properties from its lighter homologues.

Most alkali metals have many different applications. One of the best-known applications of the pure elements is the use of rubidium and caesium in atomic clocks, of which caesium atomic clocks are the most accurate and precise representation of time. A common application of the compounds of sodium is the sodium-vapour lamp, which emits light very efficiently. Table salt, or sodium chloride, has been used since antiquity. Lithium finds use as a psychiatric medication and as an anode in lithium batteries. Sodium and potassium are also essential elements, having major biological roles as electrolytes, and although the other alkali metals are not essential, they also have various effects on the body, both beneficial and harmful.

Congener (chemistry)

In chemistry, congeners are related chemical substances "related to each other by origin, structure, or function".

Gold

Gold is a chemical element with symbol Au (from Latin: aurum) and atomic number 79, making it one of the higher atomic number elements that occur naturally. In its purest form, it is a bright, slightly reddish yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal and a group 11 element. It is one of the least reactive chemical elements and is solid under standard conditions. Gold often occurs in free elemental (native) form, as nuggets or grains, in rocks, in veins, and in alluvial deposits. It occurs in a solid solution series with the native element silver (as electrum) and also naturally alloyed with copper and palladium. Less commonly, it occurs in minerals as gold compounds, often with tellurium (gold tellurides).

Gold is resistant to most acids, though it does dissolve in aqua regia, a mixture of nitric acid and hydrochloric acid, which forms a soluble tetrachloroaurate anion. Gold is insoluble in nitric acid, which dissolves silver and base metals, a property that has long been used to refine gold and to confirm the presence of gold in metallic objects, giving rise to the term acid test. Gold also dissolves in alkaline solutions of cyanide, which are used in mining and electroplating. Gold dissolves in mercury, forming amalgam alloys, but this is not a chemical reaction.

A relatively rare element, gold is a precious metal that has been used for coinage, jewelry, and other arts throughout recorded history. In the past, a gold standard was often implemented as a monetary policy, but gold coins ceased to be minted as a circulating currency in the 1930s, and the world gold standard was abandoned for a fiat currency system after 1971.

A total of 186,700 tonnes of gold exists above ground, as of 2015. The world consumption of new gold produced is about 50% in jewelry, 40% in investments, and 10% in industry. Gold's high malleability, ductility, resistance to corrosion and most other chemical reactions, and conductivity of electricity have led to its continued use in corrosion resistant electrical connectors in all types of computerized devices (its chief industrial use). Gold is also used in infrared shielding, colored-glass production, gold leafing, and tooth restoration. Certain gold salts are still used as anti-inflammatories in medicine. As of 2017, the world's largest gold producer by far was China with 440 tonnes per year.

Period 6 element

A period 6 element is one of the chemical elements in the sixth row (or period) of the periodic table of the elements, including the lanthanides. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The sixth period contains 32 elements, tied for the most with period 7, beginning with caesium and ending with radon. Lead is currently the last stable element; all subsequent elements are radioactive. For bismuth, however, its only primordial isotope, 209Bi, has a half-life of more than 1019 years, over a billion times longer than the current age of the universe. As a rule, period 6 elements fill their 6s shells first, then their 4f, 5d, and 6p shells, in that order; however, there are exceptions, such as gold.

Periodic table forms
Sets of elements
Elements
History
See also
Group 11 elements

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