Group 10 element

Group 10, numbered by current IUPAC style, is the group of chemical elements in the periodic table that consists of nickel (Ni), palladium (Pd), platinum (Pt), and perhaps also the chemically uncharacterized darmstadtium (Ds). All are d-block transition metals. All known isotopes of darmstadtium are radioactive with short half-lives, and are not known to occur in nature; only minute quantities have been synthesized in laboratories.

Like other groups, the members of this group show patterns in electron configuration, especially in the outermost shells, although for this group they are particularly weak, with palladium being an exceptional case. The relativistic stabilization of the 7s orbital is the explanation to the predicted electron configuration of darmstadtium, which, unusually for this group, conforms to that predicted by the Aufbau principle.

Group 10 in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
group 9  group 11
IUPAC group number 10
Name by element nickel group
CAS group number
(US, pattern A-B-A)
part of VIIIB
old IUPAC number
(Europe, pattern A-B)
part of VIII

↓ Period
4
A piece of nickel, about 3 cm in size
Nickel (Ni)
28 Transition metal
5
Palladium crystal
Palladium (Pd)
46 Transition metal
6
Platinum nugget
Platinum (Pt)
78 Transition metal
7 Darmstadtium (Ds)
110 unknown chemical properties

Legend

primordial element
synthetic element
Atomic number color:
black=solid

Chemistry

Z Element No. of electrons per shell
28 nickel 2, 8, 16, 2
46 palladium 2, 8, 18, 18
78 platinum 2, 8, 18, 32, 17, 1
110 darmstadtium 2, 8, 18, 32, 32, 16, 2 (predicted)

Darmstadtium has not been isolated in pure form, and its properties have not been conclusively observed; only nickel, palladium, and platinum have had their properties experimentally confirmed. All three elements are typical silvery-white transition metals, hard, and refractory, with high melting and boiling points.

Properties

Group 10 metals are white to light grey in color, and possess a high luster, a resistance to tarnish (oxidation) at STP, are highly ductile, and enter into oxidation states of +2 and +4, with +1 being seen in special conditions. The existence of a +3 state is debated, as the state could be an illusory state created by +2 and +4 states. Theory suggests that group 10 metals may produce a +6 oxidation state under precise conditions, but this remains to be proven conclusively in the laboratory other than for platinum.

Applications

The group 10 metals share several uses. These include:

Biological role and toxicity

Nickel has an important role in the biochemistry of organisms, as part of the active center of enzymes. None of the other group 10 elements have a known biological role, but platinum compounds have widely been used as anticancer drugs. Darmstadtium is very toxic because of its radioactivity.

See also

Heck reaction

The Heck reaction (also called the Mizoroki-Heck reaction) is the chemical reaction of an unsaturated halide (or triflate) with an alkene in the presence of a base and a palladium catalyst (or palladium nanomaterial-based catalyst) to form a substituted alkene. It is named after Tsutomu Mizoroki and Richard F. Heck. Heck was awarded the 2010 Nobel Prize in Chemistry, which he shared with Ei-ichi Negishi and Akira Suzuki, for the discovery and development of this reaction. This reaction was the first example of a carbon-carbon bond-forming reaction that followed a Pd(0)/Pd(II) catalytic cycle, the same catalytic cycle that is seen in other Pd(0)-catalyzed cross-coupling reactions. The Heck reaction as a way to substitute alkenes.

Index of chemistry articles

Chemistry (from Egyptian kēme (chem), meaning "earth") is the physical science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions.Below is a list of chemistry-related articles. Chemical compounds are listed separately at list of organic compounds, list of inorganic compounds or list of biomolecules.

Periodic table forms
Sets of elements
Elements
History
See also
Group 10 elements

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