The Goldschmidt classification, developed by Victor Goldschmidt (1888-1947), is a geochemical classification which groups the chemical elements within the Earth according to their preferred host phases into lithophile (rock-loving), siderophile (iron-loving), chalcophile (ore-loving or chalcogen-loving), and atmophile (gas-loving) or volatile (the element, or a compound in which it occurs, is liquid or gaseous at ambient surface conditions).
Some elements have affinities to more than one phase. The main affinity is given in the table below and a discussion of each group follows that table.
The trace radioactive elements (namely Tc, Pm, Po, At, Rn, Fr, Ra, Ac, Pa, Np, and Pu) are shown as synthetic, because their occurrence in nature is fleeting and is entirely dependent on their long-lived parents Th and U, and they are not very mobile. For instance, polonium's chemistry would predict it to be a chalcophile, but in actuality it tends to occur instead as a lithophile along with its parent uranium. (Even radon, which is a gas, does not usually have time to travel very far from the original uranium source before decaying.) When needed, these elements are typically produced synthetically in nuclear reactors instead of using the tedious and laborious process of extraction from uranium ores.
Lithophile elements are those that remain on or close to the surface because they combine readily with oxygen, forming compounds that do not sink into the core. The lithophile elements include: Al, B, Ba, Be, Br, Ca, Cl, Cr, Cs, F, I, Hf, K, Li, Mg, Na, Nb, O, P, Rb, Sc, Si, Sr, Ta, Th, Ti, U, V, Y, Zr, W and the lanthanides.
Lithophile elements mainly consist of the highly reactive metals of the s- and f-blocks. They also include a small number of reactive nonmetals, and the more reactive metals of the d-block such as titanium, zirconium and vanadium. Lithophile derives from "lithos" which means "rock", and "phile" which means "love".
Most lithophile elements form very stable ions with an electron configuration of a noble gas (sometimes with additional f-electrons). The few that do not, such as silicon, phosphorus and boron, form extremely strong covalent bonds with oxygen – often involving pi bonding. Their strong affinity for oxygen causes lithophile elements to associate very strongly with silica, forming relatively low-density minerals that thus float to the crust. The more soluble minerals formed by the alkali metals tend to concentrate in seawater or extremely arid regions where they can crystallise. The less soluble lithophile elements are concentrated on ancient continental shields where all soluble minerals have been weathered.
Because of their strong affinity for oxygen, most lithophile elements are enriched in the Earth's crust relative to their abundance in the solar system. The most reactive s- and f-block metals, which form either saline or metallic hydrides, are known to be extraordinarily enriched on Earth as a whole relative to their solar abundances. This is because during the earliest stages of the Earth's formation the reaction that controlled the stable form of each chemical element was its ability to form compounds with hydrogen. Under these conditions, the s- and f-block metals were strongly enriched during the formation of the Earth. The most enriched elements are rubidium, strontium and barium, which between them account for over 50 percent by mass of all elements heavier than iron in the Earth's crust.
The nonmetallic lithophiles – phosphorus and the halogens – exist on Earth as ionic salts with s-block metals in pegmatites and seawater. With the exception of fluorine, whose hydride forms hydrogen bonds and is therefore of relatively low volatility, these elements have had their concentrations on Earth significantly reduced through escape of volatile hydrides during the Earth's formation. Although they are present in the Earth's crust in concentrations quite close to their solar abundances, phosphorus and the heavier halogens are probably significantly depleted on Earth as a whole relative to their solar abundances.
Several transition metals, including chromium, molybdenum, iron and manganese, show both lithophile and siderophile characteristics and can be found in both these two layers. Although these metals form strong bonds with oxygen and are never found in the Earth's crust in the free state, metallic forms of these elements are thought very likely to exist in the core of the earth as relics from when the atmosphere did not contain oxygen. Like the "pure" siderophiles, these elements (except iron) are considerably depleted in the crust relative to their solar abundances.
Owing to their strong affinity for oxygen, lithophile metals, although they form the great bulk of the metallic elements in Earth's crust, were never available as free metals before the development of electrolysis. With this development, many lithophile metals are of considerable value as structural metals (magnesium, aluminium, titanium, vanadium) or as reducing agents (sodium, magnesium, calcium). The process of smelting these metals is extremely energy-intensive. With emissions of greenhouse gases suspected of contributing to climate change, the use of these elements as industrial metals is called into question, despite the depletion of rarer and less reactive chalcophile metals leaving few substitutes.
The non-metals phosphorus and the halogens were also not known to early chemists, though production of these elements is less difficult than of metallic lithophiles since electrolysis is required only with fluorine. Elemental chlorine is particularly important as an oxidizing agent – usually being made by electrolysis of sodium chloride.
Siderophile (from sideron, "iron", and philia, "love") elements are the transition metals which tend to sink into the core because they dissolve readily in iron either as solid solutions or in the molten state, although some sources include elements which are not transition metals in their list of siderophiles, such as germanium. Other sources may also differ in their list based on the temperature being discussed - niobium, vanadium, chromium, and manganese may be considered siderophiles or not, depending on the assumed temperature and pressure. Also confusing the issue is that some elements, such as the aforementioned manganese, as well as molybdenum, form strong bonds with oxygen, but in the free state (as they existed on the primitive Earth when free oxygen did not exist) can mix so easily with iron that they do not concentrate in the siliceous crust, as do true lithophile elements. Iron, meanwhile, is simply everywhere.
The siderophile elements include the highly siderophilic ruthenium, rhodium, palladium, rhenium, osmium, iridium, platinum, and gold, the moderately siderophilic cobalt and nickel, in addition to the "disputed" elements mentioned earlier - some sources even include tungsten and silver.
Most siderophile elements have practically no affinity whatsoever for oxygen: indeed oxides of gold are thermodynamically unstable with respect to the elements. They form stronger bonds with carbon or sulfur, but even these are not strong enough to separate out with the chalcophile elements. Thus, siderophile elements are bound through metallic bonds with iron in the dense layer of the Earth's core, where pressures may be high enough to keep the iron solid. Manganese, iron, and molybdenum do form strong bonds with oxygen, but in the free state (as they existed on the primitive Earth when free oxygen did not exist) can mix so easily with iron that they do not concentrate in the siliceous crust, as do true lithophile elements. However, ores of manganese are found in much the same sites as are those of aluminium and titanium, owing to manganese's great reactivity towards oxygen.
Because they are so concentrated in the dense core, siderophile elements are known for their rarity in the Earth's crust. Most of them have always been known as precious metals because of this. Iridium is the rarest transition metal occurring within the Earth's crust, with an abundance by mass of less than one part per billion. Mineable deposits of precious metals usually form as a result of the erosion of ultramafic rocks, but are not highly concentrated even compared to their crustal abundances, which are typically several orders of magnitude below their solar abundances. However, because they are concentrated in the mantle and core, siderophile elements are believed to be present in the Earth as a whole (including the core) in something approaching their solar abundances.
Chalcophile elements are those that remain on or close to the surface because they combine readily with sulfur and/or some other chalcogen other than oxygen, forming compounds which do not sink into the core.
Chalcophile elements are those metals and heavier nonmetals that have a low affinity for oxygen and prefer to bond with sulfur as highly insoluble sulfides. Chalcophile derives from Greek khalkós (χαλκός), meaning "ore" (it also meant "bronze" or "copper", but in this case "ore" is the relevant meaning), and is taken to mean "chalcogen-loving" by various sources.
Because these sulfides are much denser than the silicate minerals formed by lithophile elements, chalcophile elements separated below the lithophiles at the time of the first crystallization of the Earth's crust. This has led to their depletion in the Earth's crust relative to their solar abundances, though because the minerals they form are nonmetallic, this depletion has not reached the levels found with siderophile elements.
However, because they formed volatile hydrides on the primitive Earth when the controlling redox reaction was the oxidation or reduction of hydrogen, the less metallic chalcophile elements are strongly depleted on Earth as a whole relative to cosmic abundances. This is most especially true of the chalcogens selenium and tellurium (which formed volatile hydrogen selenide and hydrogen telluride, respectively), which for this reason are among the rarest elements found in the Earth's crust (to illustrate, tellurium is only about as abundant as platinum).
The most metallic chalcophile elements (of the copper, zinc and boron groups) may mix to some degree with iron in the Earth's core. They are not likely to be depleted on Earth as a whole relative to their solar abundances since they do not form volatile hydrides. Zinc and gallium are somewhat "lithophile" in nature because they often occur in silicate or related minerals and form quite strong bonds with oxygen. Gallium, notably, is sourced mainly from bauxite, an aluminum hydroxide ore in which gallium ion substitutes for chemically similar aluminum.
Although no chalcophile element is of high abundance in the Earth's crust, chalcophile elements constitute the bulk of commercially important metals. This is because, whereas lithophile elements require energy-intensive electrolysis for extraction, chalcophiles can be easily extracted by reduction with coke, and chalcophiles' geochemical concentration – which in extreme cases can exceed 100,000 times average crustal abundance. These greatest enrichments occur in high plateaux like the Tibetan Plateau and the Bolivian altiplano where large quantities of chalcophile elements have been uplifted through plate collisions. A side-effect of this in modern times is that the rarest chalcophiles (like mercury) are so completely exploited that their value as minerals has almost completely disappeared.
Atmophile elements (also called "volatile elements") are defined as those that remain mostly on or above the surface because they are, or occur in, liquids and/or gases at temperatures and pressures found on the surface. The noble gases do not form stable compounds and occur as monatomic gases, while nitrogen, although it does not have a stable configuration for its individual atoms, forms a diatomic molecule so strong that all oxides of nitrogen are thermodynamically unstable with respect to nitrogen and oxygen. Consequently, with the development of free oxygen through photosynthesis, ammonia was oxidised to molecular nitrogen which has come to form four-fifths of the Earth's atmosphere. Carbon is also classed as an atmophile because it forms very strong multiple bonds with oxygen in carbon monoxide (slowly oxidised in the atmosphere) and carbon dioxide. The latter is the fourth-largest constituent of the Earth's atmosphere, while carbon monoxide occurs naturally in volcanoes and has a residence time in the atmosphere of a few months.
Hydrogen, which occurs in the compound water, is also classed as an atmophile. Water is classified as a volatile, because most of it is liquid or gas, even though it does exist as a solid compound on the surface.
Because all atmophile elements are either gases or form volatile hydrides, atmophile elements are strongly depleted on earth as a whole relative to their solar abundances owing to losses from the atmosphere during the formation of the Earth. The heavier noble gases (krypton, xenon) are the rarest stable elements on Earth.
The abundance of elements in Earth's crust is shown in tabulated form with the estimated crustal abundance for each chemical element shown as parts per million (ppm) by mass (10,000 ppm = 1%). Note that the noble gases are not included, as they form no part of the solid crust. Also not included are certain elements with extremely low crustal concentrations: technetium (atomic number 43), promethium (61), and all elements with atomic numbers greater than 83 except thorium (90) and uranium (92).Abundance of the chemical elements
The abundance of the chemical elements is a measure of the occurrence of the chemical elements relative to all other elements in a given environment. Abundance is measured in one of three ways: by the mass-fraction (the same as weight fraction); by the mole-fraction (fraction of atoms by numerical count, or sometimes fraction of molecules in gases); or by the volume-fraction. Volume-fraction is a common abundance measure in mixed gases such as planetary atmospheres, and is similar in value to molecular mole-fraction for gas mixtures at relatively low densities and pressures, and ideal gas mixtures. Most abundance values in this article are given as mass-fractions.
For example, the abundance of oxygen in pure water can be measured in two ways: the mass fraction is about 89%, because that is the fraction of water's mass which is oxygen. However, the mole-fraction is 33.3333...% because only 1 atom of 3 in water, H2O, is oxygen. As another example, looking at the mass-fraction abundance of hydrogen and helium in both the Universe as a whole and in the atmospheres of gas-giant planets such as Jupiter, it is 74% for hydrogen and 23–25% for helium; while the (atomic) mole-fraction for hydrogen is 92%, and for helium is 8%, in these environments. Changing the given environment to Jupiter's outer atmosphere, where hydrogen is diatomic while helium is not, changes the molecular mole-fraction (fraction of total gas molecules), as well as the fraction of atmosphere by volume, of hydrogen to about 86%, and of helium to 13%.The abundance of chemical elements in the universe is dominated by the large amounts of hydrogen and helium which were produced in the Big Bang. Remaining elements, making up only about 2% of the universe, were largely produced by supernovae and certain red giant stars. Lithium, beryllium and boron are rare because although they are produced by nuclear fusion, they are then destroyed by other reactions in the stars. The elements from carbon to iron are relatively more abundant in the universe because of the ease of making them in supernova nucleosynthesis. Elements of higher atomic number than iron (element 26) become progressively rarer in the universe, because they increasingly absorb stellar energy in their production. Also, elements with even atomic numbers are generally more common than their neighbors in the periodic table, due to favorable energetics of formation.
The abundance of elements in the Sun and outer planets is similar to that in the universe. Due to solar heating, the elements of Earth and the inner rocky planets of the Solar System have undergone an additional depletion of volatile hydrogen, helium, neon, nitrogen, and carbon (which volatilizes as methane). The crust, mantle, and core of the Earth show evidence of chemical segregation plus some sequestration by density. Lighter silicates of aluminum are found in the crust, with more magnesium silicate in the mantle, while metallic iron and nickel compose the core. The abundance of elements in specialized environments, such as atmospheres, or oceans, or the human body, are primarily a product of chemical interactions with the medium in which they reside.Alvarez hypothesis
The Alvarez hypothesis posits that the mass extinction of the dinosaurs and many other living things during the Cretaceous–Paleogene extinction event was caused by the impact of a large asteroid on the Earth. Prior to 2013, it was commonly cited as having happened about 65 million years ago, but Renne and colleagues (2013) gave an updated value of 66 million years. Evidence indicates that the asteroid fell in the Yucatán Peninsula, at Chicxulub, Mexico. The hypothesis is named after the father-and-son team of scientists Luis and Walter Alvarez, who first suggested it in 1980.
In March 2010, an international panel of scientists endorsed the asteroid hypothesis, specifically the Chicxulub impact, as being the cause of the extinction. A team of 41 scientists reviewed 20 years of scientific literature and in so doing also ruled out other theories such as massive volcanism. They had determined that a 10–15 km (6–9 mi) space rock hurtled into earth at Chicxulub. For comparison, the Martian moon Phobos is 11 km (7 mi) and Mount Everest is just under 9 km (5.6 mi). The collision would have released the same energy as 100,000,000 megatonnes of TNT (4.2×1023 J), over a billion times the energy of the atomic bombs dropped on Hiroshima and Nagasaki.A 2016 drilling project into the peak ring of the crater strongly supported the hypothesis, and confirmed various matters that had been unclear until that point. These included the fact that the peak ring comprised granite (a rock found deep within the earth) rather than typical sea floor rock, which had been shocked, melted, and ejected to the surface in minutes, and evidence of colossal seawater movement directly afterwards from sand deposits. Crucially the cores also showed a near complete absence of gypsum, a sulfate-containing rock, which would have been vaporized and dispersed as an aerosol into the atmosphere, confirming the presence of a probable link between the impact and global longer-term effects on the climate and food chain.Chemical element
A chemical element is a species of atom having the same number of protons in their atomic nuclei (that is, the same atomic number, or Z). For example, the atomic number of oxygen is 8, so the element oxygen consists of all atoms which have exactly 8 protons.
118 elements have been identified, of which the first 94 occur naturally on Earth with the remaining 24 being synthetic elements. There are 80 elements that have at least one stable isotope and 38 that have exclusively radionuclides, which decay over time into other elements. Iron is the most abundant element (by mass) making up Earth, while oxygen is the most common element in the Earth's crust.Chemical elements constitute all of the ordinary matter of the universe. However astronomical observations suggest that ordinary observable matter makes up only about 15% of the matter in the universe: the remainder is dark matter; the composition of this is unknown, but it is not composed of chemical elements.
The two lightest elements, hydrogen and helium, were mostly formed in the Big Bang and are the most common elements in the universe. The next three elements (lithium, beryllium and boron) were formed mostly by cosmic ray spallation, and are thus rarer than heavier elements. Formation of elements with from 6 to 26 protons occurred and continues to occur in main sequence stars via stellar nucleosynthesis. The high abundance of oxygen, silicon, and iron on Earth reflects their common production in such stars. Elements with greater than 26 protons are formed by supernova nucleosynthesis in supernovae, which, when they explode, blast these elements as supernova remnants far into space, where they may become incorporated into planets when they are formed.The term "element" is used for atoms with a given number of protons (regardless of whether or not they are ionized or chemically bonded, e.g. hydrogen in water) as well as for a pure chemical substance consisting of a single element (e.g. hydrogen gas). For the second meaning, the terms "elementary substance" and "simple substance" have been suggested, but they have not gained much acceptance in English chemical literature, whereas in some other languages their equivalent is widely used (e.g. French corps simple, Russian простое вещество). A single element can form multiple substances differing in their structure; they are called allotropes of the element.
When different elements are chemically combined, with the atoms held together by chemical bonds, they form chemical compounds. Only a minority of elements are found uncombined as relatively pure minerals. Among the more common of such native elements are copper, silver, gold, carbon (as coal, graphite, or diamonds), and sulfur. All but a few of the most inert elements, such as noble gases and noble metals, are usually found on Earth in chemically combined form, as chemical compounds. While about 32 of the chemical elements occur on Earth in native uncombined forms, most of these occur as mixtures. For example, atmospheric air is primarily a mixture of nitrogen, oxygen, and argon, and native solid elements occur in alloys, such as that of iron and nickel.
The history of the discovery and use of the elements began with primitive human societies that found native elements like carbon, sulfur, copper and gold. Later civilizations extracted elemental copper, tin, lead and iron from their ores by smelting, using charcoal. Alchemists and chemists subsequently identified many more; all of the naturally occurring elements were known by 1950.
The properties of the chemical elements are summarized in the periodic table, which organizes the elements by increasing atomic number into rows ("periods") in which the columns ("groups") share recurring ("periodic") physical and chemical properties. Save for unstable radioactive elements with short half-lives, all of the elements are available industrially, most of them in low degrees of impurities.Crust (geology)
In geology, the crust is the outermost solid shell of a rocky planet, dwarf planet, or natural satellite. It is usually distinguished from the underlying mantle by its chemical makeup; however, in the case of icy satellites, it may be distinguished based on its phase (solid crust vs. liquid mantle).
The crusts of Earth, Moon, Mercury, Venus, Mars, Io, and other planetary bodies formed via igneous processes, and were later modified by erosion, impact cratering, volcanism, and sedimentation.
Most terrestrial planets have fairly uniform crusts. Earth, however, has two distinct types: continental crust and oceanic crust. These two types have different chemical compositions and physical properties, and were formed by different geological processes.Dividing line between metals and nonmetals
The dividing line between metals and nonmetals can be found, in varying configurations, on some representations of the periodic table of the elements (see mini-example, right). Elements to the lower left of the line generally display increasing metallic behaviour; elements to the upper right display increasing nonmetallic behaviour. When presented as a regular stair-step, elements with the highest critical temperature for their groups (Li, Be, Al, Ge, Sb, Po) lie just below the line.Goldschmidt tolerance factor
Goldschmidt's tolerance factor is an indicator for the stability and distortion of crystal structures. It was originally only used to describe perovskite structure, but now tolerance factors are also used for ilmenite.Alternatively the tolerance factor can be used to calculate the compatibility of an ion with a crystal structure.The first description of the tolerance factor for perovskite was made by Victor Moritz Goldschmidt in 1926.Light metal
A light metal is any metal of relatively low density. More specific definitions have been proposed; none have obtained widespread acceptance. Magnesium, aluminium and titanium are light metals of significant commercial importance. Their densities of 1.7, 2.7 and 4.5 g/cm3 range from 19 to 56% of the densities of the older structural metals, iron (7.9) and copper (8.9).List of people whose names are used in chemical element names
Below is the list of people whose names are used in chemical element names. Of the 118 chemical elements, 19 are connected with the names of 20 people. 15 elements were named to honor 16 scientists. Four other elements have indirect connection to the names of non-scientists. Only gadolinium and samarium occur in nature; the rest are synthetic.List of places used in the names of chemical elements
40 of the 118 chemical elements have names associated with, or specifically named for, places around the world or among astronomical objects. 32 of these have names tied to the Earth and the other 8 have names connected to bodies in the Solar System. The first tables below list the terrestrial locations (excluding the entire Earth itself, taken as a whole) and the last table lists astronomical objects which the chemical elements are named after.Mendeleev's predicted elements
Dmitri Mendeleev published a periodic table of the chemical elements in 1869 based on properties that appeared with some regularity as he laid out the elements from lightest to heaviest. When Mendeleev proposed his periodic table, he noted gaps in the table and predicted that as-then-unknown elements existed with properties appropriate to fill those gaps. He named them eka-boron, eka-aluminium and eka-silicon, with respective atomic masses of 44, 68, and 72.Period 1 element
A period 1 element is one of the chemical elements in the first row (or period) of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate periodic (recurring) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The first period contains fewer elements than any other row in the table, with only two: hydrogen and helium. This situation can be explained by modern theories of atomic structure. In a quantum mechanical description of atomic structure, this period corresponds to the filling of the 1s orbital. Period 1 elements obey the duet rule in that they need two electrons to complete their valence shell. The maximum number of electrons that these elements can accommodate is two, both in the 1s orbital. Therefore, period 1 can have only two elements.Period 3 element
A period 3 element is one of the chemical elements in the third row (or period) of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when the periodic table skips a row and a chemical behaviour begins to repeat, meaning that elements with similar behavior fall into the same vertical columns. The third period contains eight elements: sodium, magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon. The first two, sodium and magnesium, are members of the s-block of the periodic table, while the others are members of the p-block. Note that there is a 3d subshell, but it is not filled until period 4, such giving the period table its characteristic shape of "two rows at a time". All of the period 3 elements occur in nature and have at least one stable isotope.Period 4 element
A period 4 element is one of the chemical elements in the fourth row (or period) of the periodic table of the elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The fourth period contains 18 elements, beginning with potassium and ending with krypton. As a rule, period 4 elements fill their 4s shells first, then their 3d and 4p shells, in that order; however, there are exceptions, such as chromium.Period 7 element
A period 7 element is one of the chemical elements in the seventh row (or period) of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The seventh period contains 32 elements, tied for the most with period 6, beginning with francium and ending with oganesson, the heaviest element currently discovered. As a rule, period 7 elements fill their 7s shells first, then their 5f, 6d, and 7p shells, in that order; however, there are exceptions, such as plutonium.Siderophile
Siderophile means "iron-loving". This can refer to:
Siderophilic bacteria, bacteria that require or are facilitated by free iron
Siderophile elements, chemical elements such as iridium or gold that tend to bond with metallic iron, as described by the Goldschmidt classification
Siderophilia, another name for haemochromatosis, a disease in which the body accumulates too much ironSystematic element name
A systematic element name is the temporary name assigned to a newly synthesized or not yet synthesized chemical element. A systematic symbol is also derived from this name. In chemistry, a transuranic element receives a permanent name and symbol only after its synthesis has been confirmed. In some cases, such as the Transfermium Wars, controversies over the formal name and symbol have been protracted and highly political. In order to discuss such elements without ambiguity, the International Union of Pure and Applied Chemistry (IUPAC) uses a set of rules to assign a temporary systematic name and symbol to each such element. This approach to naming originated in the successful development of regular rules for the naming of organic compounds.Transition metal
In chemistry, the term transition metal (or transition element) has three possible meanings:
The IUPAC definition defines a transition metal as "an element whose atom has a partially filled d sub-shell, or which can give rise to cations with an incomplete d sub-shell".
Many scientists describe a "transition metal" as any element in the d-block of the periodic table, which includes groups 3 to 12 on the periodic table. In actual practice, the f-block lanthanide and actinide series are also considered transition metals and are called "inner transition metals".
Cotton and Wilkinson expand the brief IUPAC definition (see above) by specifying which elements are included. As well as the elements of groups 4 to 11, they add scandium and yttrium in group 3, which have a partially filled d subshell in the metallic state. Lanthanum and actinium in group 3 are, however, classified as lanthanides and actinides respectively.English chemist Charles Bury (1890–1968) first used the word transition in this context in 1921, when he referred to a transition series of elements during the change of an inner layer of electrons (for example n = 3 in the 4th row of the periodic table) from a stable group of 8 to one of 18, or from 18 to 32. These elements are now known as the d-block.Victor Goldschmidt
Victor Moritz Goldschmidt (January 27, 1888 in Zürich – March 20, 1947 in Oslo) was a Norwegian mineralogist considered (together with Vladimir Vernadsky) to be the founder of modern geochemistry and crystal chemistry, developer of the Goldschmidt Classification of elements.