An extended periodic table theorizes about chemical elements beyond those currently known in the periodic table and proven up through oganesson, which completes the seventh period (row) in the periodic table at atomic number (Z) 118.
If further elements with higher atomic numbers than this are discovered, they will be placed in additional periods, laid out (as with the existing periods) to illustrate periodically recurring trends in the properties of the elements concerned. Any additional periods are expected to contain a larger number of elements than the seventh period, as they are calculated to have an additional so-called g-block, containing at least 18 elements with partially filled g-orbitals in each period. An eight-period table containing this block was suggested by Glenn T. Seaborg in 1969. The first element of the g-block may have atomic number 121, and thus would have the systematic name unbiunium. Despite many searches, no elements in this region have been synthesized or discovered in nature.
According to the orbital approximation in quantum mechanical descriptions of atomic structure, the g-block would correspond to elements with partially filled g-orbitals, but spin-orbit coupling effects reduce the validity of the orbital approximation substantially for elements of high atomic number. While Seaborg's version of the extended period had the heavier elements following the pattern set by lighter elements, as it did not take into account relativistic effects, models that take relativistic effects into account do not. Pekka Pyykkö and Burkhard Fricke used computer modeling to calculate the positions of elements up to Z = 172, and found that several were displaced from the Madelung rule. As a result of uncertainty and variability in predictions of chemical and physical properties of elements beyond 120, there is currently no consensus on their placement in the extended periodic table.
Elements in this region are likely to be highly unstable with respect to radioactive decay and undergo alpha decay or spontaneous fission with extremely short half-lives, though element 126 is hypothesized to be within an island of stability that is resistant to fission but not to alpha decay. Other islands of stability beyond the known elements may also be possible, including one theorized around element 164, though the extent of stabilizing effects from closed nuclear shells is uncertain. It is not clear how many elements beyond the expected island of stability are physically possible, whether period 8 is complete, or if there is a period 9. The International Union of Pure and Applied Chemistry (IUPAC) defines an element to exist if its lifetime is longer than 10−14 seconds (0.01 picoseconds, or 10 femtoseconds), which is the time it takes for the nucleus to form an electron cloud.
As early as 1940, it was noted that a simplistic interpretation of the relativistic Dirac equation runs into problems with electron orbitals at Z > 1/α ≈ 137, suggesting that neutral atoms cannot exist beyond element 137, and that a periodic table of elements based on electron orbitals therefore breaks down at this point. On the other hand, a more rigorous analysis calculates the analogous limit to be Z ≈ 173 where the 1s subshell dives into the Dirac sea, and that it is instead not neutral atoms that cannot exist beyond element 173, but bare nuclei, thus posing no obstacle to the further extension of the periodic system. Atoms beyond this critical atomic number are called supercritical atoms.
Heavier elements beyond the actinides were first proposed to exist as early as 1955, and were called superheavy elements. The first predictions on properties of undiscovered superheavy elements were made in 1957, when the concept of nuclear shells was first explored and an island of stability was theorized to exist around element 126. In 1967, more rigorous calculations were performed, and the island of stability was theorized to be centered at the then-undiscovered flerovium (element 114); this and other subsequent studies motivated many researchers to search for superheavy elements in nature or attempt to synthesize them at accelerators. Many searches for superheavy elements were conducted in the 1970s, all with negative results. As of December 2018, synthesis has been attempted for every element up to and including unbiseptium (Z = 127), except unbitrium (Z = 123), with the heaviest successfully synthesized element being oganesson in 2002 and the most recent discovery being that of tennessine in 2010.
As some superheavy elements were predicted to lie beyond the seven-period periodic table, an additional eighth period containing these elements was first proposed by Glenn T. Seaborg in 1969. This model continued the pattern in established elements and introduced a new g-block and superactinide series beginning at element 121, raising the number of elements in period 8 compared to known periods. These early calculations failed to consider relativistic effects that break down periodic trends and render simple extrapolation impossible, however. In 1971, Fricke calculated the periodic table up to Z = 172, and discovered that some elements indeed had different properties that break the established pattern, and a 2010 calculation by Pekka Pyykkö also noted that several elements might behave differently than expected. It is unknown how far the periodic table might extend beyond the known 118 elements, as heavier elements are predicted to be increasingly unstable. Glenn T. Seaborg suggested that the highest possible element may be under Z = 130, while Walter Greiner predicted that there may not be a highest possible element.
There is currently no consensus on the placement of elements beyond atomic number 120 in the periodic table. The table below shows one possibility for the appearance of the eighth period, with placement of elements primarily based on their predicted chemistry.
All of these hypothetical undiscovered elements are named by the International Union of Pure and Applied Chemistry (IUPAC) systematic element name standard which creates a generic name for use until the element has been discovered, confirmed, and an official name approved. These names are typically not used in the literature, and are referred to by their atomic numbers; hence, element 164 would usually not be called "unhexquadium" (the IUPAC systematic name), but rather "element 164" with symbol "164", "(164)", or "E164".
At element 118, the orbitals 1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p, 4d, 4f, 5s, 5p, 5d, 5f, 6s, 6p, 6d, 7s and 7p are assumed to be filled, with the remaining orbitals unfilled. A simple extrapolation from the Aufbau principle would predict the eighth row to fill orbitals in the order 8s, 5g, 6f, 7d, 8p; but after element 120, the proximity of the electron shells makes placement in a simple table problematic. Although a simple extrapolation of the periodic table, following Seaborg's original concept, would put the elements after 120 as follows: 121-138 form the g-block superactinides; 139-152 form the f-block superactinides, 153-161 would be transition metals; 162-166 post-transition metals; 167=halogen; 168=noble gas; 169=alkali metal; 170=alkaline earth metal, Dirac-Fock calculations predict that it will most likely go: 121-142 form the g-block superactinides; 143-156 form the f-block superactinides; 157-165 form the transition metals; 166-170 post-transition metals; 171=halogen; 172=noble gas.
Not all models show the higher elements following the pattern established by lighter elements. Pekka Pyykkö, for example, used computer modeling to calculate the positions of elements up to Z = 172 and their possible chemical properties. He found that several elements were displaced from the Madelung energy-ordering rule as a result of overlapping orbitals; this is caused by the increasing role of relativistic effects in heavy elements. He predicts that the orbitals will fill up in this order: 8s, 5g, the first two spaces of 8p, 6f, 7d, 9s, the first two spaces of 9p, the rest of 8p. This corresponds to elements 119 and 120 being alkali and alkaline earth metals, 121-138 g-block superactinides, 139 and 140 post-transition metals placed below thallium and lead, respectively, 141-155 f-block superactinides, 156-164 transition metals, 165 and 166 alkali and alkaline earth metals below 119 and 120 and opening period 9, 167-168 below 139 and 140, and 169-172 completing period 8. He also suggests that period 8 be split into three parts: 8a, containing 8s, 8b, containing the first two elements of 8p, and 8c, containing 7d and the rest of 8p.
Fricke's predictions — up to element 184 — also found some elements to be displaced from the Aufbau principle as a consequence of relativistic effects. He predicted that after element 120, a long transition series (the superactinides) characterized by the filling of 5g and 6f orbitals would begin, and continue until element 154. A fifth transition metal series in which 7d orbitals are filled then would contain elements 155-164, and the eighth period would possibly end there. It is also possible that element 157 is in fact the first 7d transition metal, another shift resulting from relativistic effects. Elements 165 and 166 were predicted to be alkali and alkaline earth metals, though they may also mix characteristics of groups 11 and 12 and instead be placed below roentgenium and copernicium, respectively. Finally, elements 167 to 172 would be the heaviest members of groups 13-18. Fricke initially proposed that elements 165-172 would constitute a ninth period, as these elements may follow a similar pattern to periods 2 and 3 and have no transition metals. Due to overlapping orbitals and possible mixing of group characteristics in superheavy elements, element 172 may instead close period 8, however.
The period 8 elements up to unbiseptium, except unbitrium, have had synthesis attempts. So far, none of these synthesis attempts have been successful.
No atoms were identified, leading to a limiting cross section of 300 nb. Later calculations suggest that the cross section of the 3n reaction (which would result in 299Uue and three neutrons as products) would actually be six hundred thousand times lower than this upper bound, at 0.5 pb.
As ununennium is the lightest undiscovered element, it has been the target of synthesis experiments by both German and Russian teams in recent years. The Russian experiments were conducted in 2011, and no results were released, strongly implying that no ununennium atoms were identified. From April to September 2012, an attempt to synthesize the isotopes 295Uue and 296Uue was made by bombarding a target of berkelium-249 with titanium-50 at the GSI Helmholtz Centre for Heavy Ion Research in Darmstadt, Germany. Based on the theoretically predicted cross-section, it was expected that an ununennium atom would be synthesized within five months of the beginning of the experiment.
The experiment was originally planned to continue to November 2012, but was stopped early to make use of the 249Bk target to confirm the synthesis of tennessine (thus changing the projectiles to 48Ca). This reaction between 249Bk and 50Ti was predicted to be the most favorable practical reaction for formation of ununennium, as it is rather asymmetrical, though also somewhat cold. (The reaction between 254Es and 48Ca would be superior, but preparing milligram quantities of 254Es for a target is difficult.) Nevertheless, the necessary change from the "silver bullet" 48Ca to 50Ti divides the expected yield of ununennium by about twenty, as the yield is strongly dependent on the asymmetry of the fusion reaction.
Due to the predicted short half-lives, the GSI team used new "fast" electronics capable of registering decay events within microseconds. No ununennium atoms were identified, implying a limiting cross-section of 70 fb. The predicted actual cross-section is around 40 fb, which is at the limits of current technology.
The team at the Joint Institute for Nuclear Research in Dubna, Russia, is planning to begin new experiments on the synthesis of ununennium and unbinilium using the 249Bk+50Ti and 249Cf+50Ti reactions in 2019 using a new experimental complex. The team at RIKEN in Japan also plans to make attempts on these elements around the same time with 248Cm targets using the 248Cm+51V and 248Cm+54Cr reactions.
Following their success in obtaining oganesson by the reaction between 249Cf and 48Ca in 2006, the team at the Joint Institute for Nuclear Research (JINR) in Dubna started similar experiments in March–April 2007, in hope of creating unbinilium (element 120) from nuclei of 58Fe and 244Pu. Isotopes of unbinilium are predicted to have alpha decay half-lives of the order of microseconds. Initial analysis revealed that no atoms of unbinilium were produced, providing a limit of 400 fb for the cross section at the energy studied.
The Russian team planned to upgrade their facilities before attempting the reaction again.
No atoms were detected providing a limit of 1.6 pb for the cross section at the energy provided. The GSI repeated the experiment with higher sensitivity in three separate runs in April–May 2007, January–March 2008, and September–October 2008, all with negative results, reaching a cross section limit of 90 fb.
In June–July 2010, and again in 2011, after upgrading their equipment to allow the use of more radioactive targets, scientists at the GSI attempted the more asymmetrical fusion reaction:
It was expected that the change in reaction would quintuple the probability of synthesizing unbinilium, as the yield of such reactions is strongly dependent on their asymmetry. Three correlated signals were observed that matched the predicted alpha decay energies of 299Ubn and its daughter 295Og, as well as the experimentally known decay energy of its granddaughter 291Lv. However, the lifetimes of these possible decays were much longer than expected, and the results could not be confirmed.
Because of its asymmetry, the reaction between 249Cf and 50Ti was predicted to be the most favorable practical reaction for synthesizing unbinilium, although it is also somewhat cold. No unbinilium atoms were identified, implying a limiting cross-section of 200 fb. Jens Volker Kratz predicted the actual maximum cross-section for producing unbinilium by any of these reactions to be around 0.1 fb; in comparison, the world record for the smallest cross section of a successful reaction was 30 fb for the reaction 209Bi(70Zn,n)278Nh, and Kratz predicted a maximum cross-section of 20 fb for producing the neighbouring ununennium. If these predictions are accurate, then synthesizing ununennium would be at the limits of current technology, and synthesizing unbinilium would require new methods.
The team at the Joint Institute for Nuclear Research in Dubna, Russia, is planning to begin new experiments on the synthesis of ununennium and unbinilium using the 249Bk+50Ti and 249Cf+50Ti reactions in 2019 using a new experimental complex. The team at RIKEN in Japan also plans to make attempts on these elements around the same time with 248Cm targets using the 248Cm+51V and 248Cm+54Cr reactions.
No atoms were identified.
These experiments were motivated by early predictions on the existence of an island of stability at N = 184 and Z > 120. No atoms were detected and a yield limit of 5 nb (5,000 pb) was measured. Current results (see flerovium) have shown that the sensitivity of these experiments were too low by at least 3 orders of magnitude.
These results indicate that the synthesis of such heavier elements remains a significant challenge and further improvements of beam intensity and experimental efficiency is required. The sensitivity should be increased to 1 fb in the future for more quality results.
In particular, the reaction between 170Er and 136Xe was expected to yield alpha-emitters with half-lives of microseconds that would decay down to isotopes of flerovium with half-lives perhaps increasing up to several hours, as flerovium is predicted to lie near the center of the island of stability. After twelve hours of irradiation, nothing was found in this reaction. Following a similar unsuccessful attempt to synthesize unbiunium from 238U and 65Cu, it was concluded that half-lives of superheavy nuclei must be less than one microsecond or the cross sections are very small. More recent research into synthesis of superheavy elements suggests that both conclusions are true. The two attempts in the 1970s to synthesize unbibium were both propelled by the research investigating whether superheavy elements could potentially be naturally occurring.
Several experiments studying the fission characteristics of various superheavy compound nuclei such as 306Ubb were performed between 2000–2004 at the Flerov Laboratory of Nuclear Reactions. Two nuclear reactions were used, namely 248Cm + 58Fe and 242Pu + 64Ni. The results reveal how superheavy nuclei fission predominantly by expelling closed shell nuclei such as 132Sn (Z=50, N=82). It was also found that the yield for the fusion-fission pathway was similar between 48Ca and 58Fe projectiles, suggesting a possible future use of 58Fe projectiles in superheavy element formation.
Scientists at GANIL (Grand Accélérateur National d'Ions Lourds) attempted to measure the direct and delayed fission of compound nuclei of elements with Z = 114, 120, and 124 in order to probe shell effects in this region and to pinpoint the next spherical proton shell. This is because having complete nuclear shells (or, equivalently, having a magic number of protons or neutrons) would confer more stability on the nuclei of such superheavy elements, thus moving closer to the island of stability. In 2006, with full results published in 2008, the team provided results from a reaction involving the bombardment of a natural germanium target with uranium ions:
The team reported that they had been able to identify compound nuclei fissioning with half-lives > 10−18 s. This result suggests a strong stabilizing effect at Z = 124 and points to the next proton shell at Z > 120, not at Z = 114 as previously thought. A compound nucleus is a loose combination of nucleons that have not arranged themselves into nuclear shells yet. It has no internal structure and is held together only by the collision forces between the target and projectile nuclei. It is estimated that it requires around 10−14 s for the nucleons to arrange themselves into nuclear shells, at which point the compound nucleus becomes a nuclide, and this number is used by IUPAC as the minimum half-life a claimed isotope must have to potentially be recognised as being discovered. Thus, the GANIL experiments do not count as a discovery of element 124.
Similarly to previous experiments conducted at the JINR (Joint Institute for Nuclear Research), fission fragments clustered around doubly magic nuclei such as 132Sn (Z = 50, N = 82), revealing a tendency for superheavy nuclei to expel such doubly magic nuclei in fission. The average number of neutrons per fission from the 312124 compound nucleus (relative to lighter systems) was also found to increase, confirming that the trend of heavier nuclei emitting more neutrons during fission continues into the superheavy mass region.
No atoms were detected, and a cross section limit of 5 nb was determined. This experiment was motivated by the possibility of greater stability for nuclei around Z ~ 126 and N ~ 184, though more recent research suggests the island of stability may instead lie at a lower atomic number (such as copernicium, Z = 112), and the synthesis of heavier elements such as unbipentium will require more sensitive experiments.
The first and only attempt to synthesize unbihexium, which was unsuccessful, was performed in 1971 at CERN (European Organization for Nuclear Research) by René Bimbot and John M. Alexander using the hot fusion reaction:
High energy (13-15 MeV) alpha particles were observed and taken as possible evidence for the synthesis of unbihexium. Subsequent unsuccessful experiments with higher sensitivity suggest that the 10 mb sensitivity of this experiment was too low; hence, the formation of unbihexium nuclei in this reaction is highly unlikely.
The first and only attempt to synthesize unbiseptium, which was unsuccessful, was performed in 1978 at the UNILAC accelerator at the GSI Helmholtz Center, where a natural tantalum target was bombarded with xenon-136 ions:
A study in 1976 by a group of American researchers from several universities proposed that primordial superheavy elements, mainly livermorium, unbiquadium, unbihexium, and unbiseptium, could be a cause of unexplained radiation damage (particularly radiohalos) in minerals. This prompted many researchers to search for them in nature from 1976 to 1983. A group led by Tom Cahill, a professor at the University of California at Davis, claimed in 1976 that they had detected alpha particles and X-rays with the right energies to cause the damage observed, supporting the presence of these elements. In particular, the presence of long-lived (on the order of 109 years) unbiquadium and unbihexium nuclei, along with their decay products, at an abundance of 10−11 relative to their possible congeners uranium and plutonium, was conjectured. Others claimed that none had been detected, and questioned the proposed characteristics of primordial superheavy nuclei. In particular, they cited that any such superheavy nuclei must have a closed neutron shell at N = 184 or N = 228, and this necessary condition for enhanced stability only exists in neutron deficient isotopes of livermorium or neutron rich isotopes of the other elements that would not be beta-stable unlike most naturally occurring isotopes. This activity was also proposed to be caused by nuclear transmutations in natural cerium, raising further ambiguity upon this claimed observation of superheavy elements.
On April 24, 2008, a group led by Amnon Marinov at the Hebrew University of Jerusalem claimed to have found single atoms of unbibium-292 in naturally occurring thorium deposits at an abundance of between 10−11 and 10−12 relative to thorium. The claim of Marinov et al. was criticized by a part of the scientific community, and Marinov says he has submitted the article to the journals Nature and Nature Physics but both turned it down without sending it for peer review. The unbibium-292 atoms were claimed to be superdeformed or hyperdeformed isomers, with a half-life of at least 100 million years.
A criticism of the technique, previously used in purportedly identifying lighter thorium isotopes by mass spectrometry, was published in Physical Review C in 2008. A rebuttal by the Marinov group was published in Physical Review C after the published comment.
A repeat of the thorium-experiment using the superior method of Accelerator Mass Spectrometry (AMS) failed to confirm the results, despite a 100-fold better sensitivity. This result throws considerable doubt on the results of the Marinov collaboration with regard to their claims of long-lived isotopes of thorium, roentgenium and unbibium. It is still possible that traces of unbibium might only exist in some thorium samples, although this is unlikely.
The possible extent of primordial superheavy elements on Earth today is uncertain. Even if they are confirmed to have caused the radiation damage long ago, they might now have decayed to mere traces, or even be completely gone. It is also uncertain if such superheavy nuclei may be produced naturally at all, as spontaneous fission is expected to terminate the r-process responsible for heavy element formation between mass number 270 and 290, well before elements heavier than unbinilium may be formed.
Element 118, oganesson, is the last element that has been synthesized. The next two elements, elements 119 and 120, should form an 8s series and be an alkali and alkaline earth metal respectively. Beyond element 120, the superactinide series is expected to begin, when the 8s electrons and the filling 8p1/2, 7d3/2, 6f5/2, and 5g7/2 subshells determine the chemistry of these elements. Complete and accurate CCSD calculations are not available for elements beyond 122 because of the extreme complexity of the situation: the 5g, 6f, and 7d orbitals should have about the same energy level, and in the region of element 160, the 9s, 8p3/2, and 9p1/2 orbitals should also be about equal in energy. This will cause the electron shells to mix so that the block concept no longer applies very well, and will also result in novel chemical properties that will make positioning these elements in a periodic table very difficult. For example, element 164 is expected to mix characteristics of the elements of group 10, 12, 14, and 18.
|Standard atomic weight|||||
|Valence electron configuration||8s1||8s2|
|Stable oxidation states||1, 3||2, 4|
|First ionization energy||463 kJ/mol||580 kJ/mol|
|Metallic radius||260 pm||200 pm|
|Density||3 g/cm3||7 g/cm3|
|Melting point||0–30 °C (32–86 °F)||680 °C (1,300 °F)|
|Boiling point||630 °C (1,200 °F)||1,700 °C (3,100 °F)|
The first two elements of period 8 will be ununennium and unbinilium, elements 119 and 120. Their electron configurations should have the 8s orbital being filled. This orbital is relativistically stabilized and contracted; thus, elements 119 and 120 should be more like rubidium and strontium than their immediate neighbours above, francium and radium. Another effect of the relativistic contraction of the 8s orbital is that the atomic radii of these two elements should be about the same as those of francium and radium. They should behave like normal alkali and alkaline earth metals, normally forming +1 and +2 oxidation states respectively, but the relativistic destabilization of the 7p3/2 subshell and the relatively low ionization energies of the 7p3/2 electrons should make higher oxidation states like +3 and +4 (respectively) possible as well.
The superactinide series is expected to contain elements 121 to 157. In the superactinide series, the 7d3/2, 8p1/2, 6f5/2 and 5g7/2 shells should all fill simultaneously. This creates very complicated situations, so much so that complete and accurate CCSD calculations have been done only for elements 121 and 122. The first superactinide, unbiunium (element 121), should be a congener of lanthanum and actinium and should have similar properties to them: its main oxidation state should be +3, although the closeness of the valence subshells' energy levels may permit higher oxidation states, just as in elements 119 and 120. Relativistic stabilization of the 8p subshell should result in a ground-state 8s28p1 valence electron configuration for element 121, in contrast to the ds2 configurations of lanthanum and actinium. Its first ionization energy is predicted to be 429.4 kJ/mol, which would be lower than those of all known elements except for the alkali metals potassium, rubidium, caesium, and francium: this value is even lower than that of the period 8 alkali metal ununennium (463 kJ/mol). Similarly, the next superactinide, unbibium (element 122), may be a congener of cerium and thorium, with a main oxidation state of +4, but would have a ground-state 7d18s28p1 valence electron configuration, unlike thorium's 6d27s2 configuration. Hence, its first ionization energy would be smaller than thorium's (Th: 6.3 eV; Ubb: 5.6 eV) because of the greater ease of ionizing unbibium's 8p1/2 electron than thorium's 6d electron. The collapse of the 5g orbital itself is delayed until element 125; the electron configurations of the 119-electron isoelectronic series are expected to be [Og]8s1 for elements 119 through 122, [Og]6f1 for elements 123 and 124, and [Og]5g1 for element 125 onwards.
In the first few superactinides, the binding energies of the added electrons are predicted to be small enough that they can lose all their valence electrons; for example, unbihexium (element 126) could easily form a +8 oxidation state, and even higher oxidation states for the next few elements may be possible. Unbihexium is also predicted to display a variety of other oxidation states: recent calculations have suggested a stable monofluoride UbhF may be possible, resulting from a bonding interaction between the 5g orbital on unbihexium and the 2p orbital on fluorine. Other predicted oxidation states include +2, +4, and +6; +4 is expected to be the most usual oxidation state of unbihexium. The superactinides from unbipentium (element 125) to unbiennium (element 129) are predicted to exhibit a +6 oxidation state and form hexafluorides, though UbpF6 and UbhF6 are predicted to be relatively weakly bound. Stable monofluorides of these elements may also be possible. The bond dissociation energies are expected to greatly increase at element 127 and even more so at element 129. This suggests a shift from strong ionic character in fluorides of element 125 to more covalent character, involving the 8p orbital, in fluorides of element 129. The bonding in these superactinide hexafluorides is mostly between the highest 8p subshell of the superactinide and the 2p subshell of fluorine, unlike how uranium uses its 5f and 6d orbitals for bonding in uranium hexafluoride.
Despite the ability of early superactinides to reach high oxidation states, it has been calculated that the 5g electrons will be most difficult to ionize; the Ubp6+ and Ubh7+ ions are expected to bear a 5g1 configuration, similar to the 5f1 configuration of the Np6+ ion. Similar behavior is observed in the chemical inactivity of the 4f electrons in lanthanides; this is a consequence of the 5g orbitals being small and deeply buried in the electron cloud. The presence of electrons in g-orbitals, which do not exist in the ground state electron configuration of any currently known element, should allow presently unknown hybrid orbitals to form and influence the chemistry of the superactinides in new ways, although the absence of g electrons in known elements makes predicting superactinide chemistry more difficult.
|Oxidation states||3||4||5||6||1, 6, 7||1, 2, 4, 6, 8||6||6||1, 6||6||4, 6||6, 8||3, 4, 5, 6, 8||6||8||12||3||0, 2||3, 5||2||3|
In the later superactinides, the oxidation states should become lower. By element 132, the predominant most stable oxidation state will be only +6; this is further reduced to +3 and +4 by element 144, and at the end of the superactinide series it will be only +2 (and possibly even 0) because the 6f shell, which is being filled at that point, is deep inside the electron cloud and the 8s and 8p1/2 electrons are bound too strongly to be chemically active. The 5g shell should be filled at element 144 and the 6f shell at around element 154, and at this region of the superactinides the 8p1/2 electrons are bound so strongly that they are no longer active chemically, so that only a few electrons can participate in chemical reactions. Calculations by Fricke et al. predict that at element 154, the 6f shell is full and there are no d- or other electron wave functions outside the chemically inactive 8s and 8p1/2 shells. This would cause element 154 to be very unreactive, so that it may exhibit properties similar to those of the noble gases.
Similarly to the lanthanide and actinide contractions, there should be a superactinide contraction in the superactinide series where the ionic radii of the superactinides are smaller than expected. In the lanthanides, the contraction is about 4.4 pm per element; in the actinides, it is about 3 pm per element. The contraction is larger in the lanthanides than in the actinides due to the greater localization of the 4f wave function as compared to the 5f wave function. Comparisons with the wave functions of the outer electrons of the lanthanides, actinides, and superactinides lead to a prediction of a contraction of about 2 pm per element in the superactinides; although this is smaller than the contractions in the lanthanides and actinides, its total effect is larger due to the fact that 32 electrons are filled in the deeply buried 5g and 6f shells, instead of just 14 electrons being filled in the 4f and 5f shells in the lanthanides and actinides respectively.
Pekka Pyykkö divides these superactinides into three series: a 5g series (elements 121 to 138), an 8p1/2 series (elements 139 to 140), and a 6f series (elements 141 to 155), also noting that there would be a great deal of overlapping between energy levels and that the 6f, 7d, or 8p1/2 orbitals could well also be occupied in the early superactinide atoms or ions. He also expects that they would behave more like "superlanthanides", in the sense that the 5g electrons would mostly be chemically inactive, similarly to how only one or two 4f electrons in each lanthanide are ever ionized in chemical compounds. He also predicted that the possible oxidation states of the superactinides might rise very high in the 6f series, to values such as +12 in element 148.
As an example from the late superactinides, element 156 is expected to exhibit mainly the +2 oxidation state. Its first ionization energy should be about 400 kJ/mol and its metallic radius should be about 170 picometers. It should be a very heavy metal with a density of around 26 g/cm3. Its relative atomic mass should be around 445 u.
The transition metals in period 8 are expected to be elements 157 to 165 (or perhaps with element 121 replacing 157, similarly to the dispute on whether lanthanum or lutetium is better placed as the first 5d transition metal). To these, element 166 may be added to complete the 7d subshell, although like its lighter group 12 homologues, it is questionable if it would show transition metal character. Although the 8s and 8p1/2 electrons are bound so strongly in these elements that they should not be able to take part in any chemical reactions, the 9s and 9p1/2 levels are expected to be readily available for hybridization.
The noble metals of this series of transition metals are not expected to be as noble as their lighter homologues, due to the absence of an outer s shell for shielding and also because the 7d shell is strongly split into two subshells due to relativistic effects. This causes the first ionization energies of the 7d transition metals to be smaller than those of their lighter congeners.
Calculations predict that the 7d electrons of element 164 (unhexquadium) should participate very readily in chemical reactions, so that unhexquadium should be able to show stable +6 and +4 oxidation states in addition to the normal +2 state in aqueous solutions with strong ligands. Unhexquadium should thus be able to form compounds like Uhq(CO)4, Uhq(PF3)4 (both tetrahedral), and Uhq(CN)2−
2 (linear), which is very different behavior from that of lead, which unhexquadium would be a heavier homologue of if not for relativistic effects. Nevertheless, the divalent state would be the main one in aqueous solution, and unhexquadium(II) should behave more similarly to lead than unhexquadium(IV) and unhexquadium(VI).
Unhexquadium should be a soft metal like mercury, and metallic unhexquadium should have a high melting point as it is predicted to bond covalently. It is also expected to be a soft Lewis acid and have Ahrlands softness parameter close to 4 eV. It should also have some similarities to oganesson as well as to the other group 12 elements. Unhexquadium should be at most moderately reactive, having a first ionization energy that should be around 685 kJ/mol, comparable to that of molybdenum. Due to the lanthanide, actinide, and superactinide contractions, unhexquadium should have a metallic radius of only 158 pm, very close to that of the much lighter magnesium, despite its expected atomic weight of around 474 u which is about 19.5 times the atomic weight of magnesium. This small radius and high weight cause it to be expected to have an extremely high density of around 46 g·cm−3, over twice that of osmium, currently the most dense element known, at 22.61 g·cm−3; unhexquadium should be the second most dense element in the first 172 elements in the periodic table, with only its neighbor unhextrium (element 163) being more dense (at 47 g·cm−3). Metallic unhexquadium should be quite stable, as the 8s and 8p1/2 electrons are very deeply buried in the electron core and only the 7d electrons are available for bonding. Metallic unhexquadium should have a very large cohesive energy (enthalpy of crystallization) due to its covalent bonds, most probably resulting in a high melting point.
Theoretical interest in the chemistry of unhexquadium is largely motivated by theoretical predictions that it, especially the isotopes 472Uhq and 482Uhq (with 164 protons and 308 or 318 neutrons), would be at the center of a hypothetical second island of stability (the first being centered on copernicium, particularly the isotopes 291Cn, 293Cn, and 296Cn which are expected to have half-lives of centuries or millennia).
Elements 165 (unhexpentium) and 166 (unhexhexium), the last two 7d metals, should behave similarly to alkali and alkaline earth metals when in the +1 and +2 oxidation states respectively. The 9s electrons should have ionization energies comparable to those of the 3s electrons of sodium and magnesium, due to relativistic effects causing the 9s electrons to be much more strongly bound than non-relativistic calculations would predict. Elements 165 and 166 should normally exhibit the +1 and +2 oxidation states respectively, although the ionization energies of the 7d electrons are low enough to allow higher oxidation states like +3 for element 165. The oxidation state +4 for element 166 is less likely, creating a situation similar to the lighter elements in groups 11 and 12 (particularly gold and mercury). As with mercury but not copernicium, ionization of element 166 to Uhh2+ is expected to result in a 7d10 configuration corresponding to the loss of the s-electrons but not the d-electrons, making it more analogous to the lighter "less relativistic" group 12 elements zinc, cadmium, and mercury, which have essentially no transition-metal character.
|Standard atomic weight|||||||||||||||||||||||
(12, 14, 18)
|Valence electron configuration||7d2||7d3||7d4||7d4 9s1||7d5 9s1||7d6 9s1||7d7 9s1||7d8 9s1||7d10||7d10 9s1||7d10 9s2|
|Stable oxidation states||2||3||4||1, 5||2, 6||3, 7||4, 8||5||0, 2, 4, 6||1, 3||2|
|First ionization energy||400 kJ/mol||450 kJ/mol||520 kJ/mol||340 kJ/mol||420 kJ/mol||470 kJ/mol||560 kJ/mol||620 kJ/mol||690 kJ/mol||520 kJ/mol||630 kJ/mol|
|Metallic radius||170 pm||163 pm||157 pm||152 pm||148 pm||148 pm||149 pm||152 pm||158 pm||250 pm||200 pm|
|Density||26 g/cm3||28 g/cm3||30 g/cm3||33 g/cm3||36 g/cm3||40 g/cm3||45 g/cm3||47 g/cm3||46 g/cm3||7 g/cm3||11 g/cm3|
The next six elements on the periodic table should be the last main-group elements in their period. In elements 167 to 172, the 9p1/2 and 8p3/2 shells will be filled. Their energy eigenvalues are so close together that they behave as one combined p shell, similar to the non-relativistic 2p and 3p shells. Thus, the inert pair effect does not occur and the most common oxidation states of elements 167 to 170 should be +3, +4, +5, and +6 respectively. Element 171 (unseptunium) is expected to show some similarities to the halogens, showing various oxidation states ranging from −1 to +7, although its physical properties should be closer to that of a metal. Its electron affinity should be 3.0 eV, allowing it to form HUsu, analogous to a hydrogen halide. The Usu− ion is expected to be a soft base, comparable to iodide (I−). Element 172 (unseptbium) should be a noble gas with chemical behaviour similar to that of xenon, as their ionization energies should be very similar (Xe, 1170.4 kJ/mol; Usb, 1090.3 kJ/mol). The only main difference between them is that element 172, unlike xenon, is expected to be a liquid or a solid at standard temperature and pressure due to its much higher atomic weight. Unseptbium should be a strong Lewis acid, forming fluorides and oxides, similarly to its lighter congener xenon. Because of this analogy of elements 165–172 to periods 2 and 3, Fricke et al. considered them to form a ninth period of the periodic table, while the eighth period was taken by them to end at the noble metal element 164. This ninth period would be similar to the second and third period in that it should have no transition metals.
|Standard atomic weight|||||||||||||
|Valence electron configuration||9s2 9p1||9s2 9p2||9s2 9p2 8p1||9s2 9p2 8p2||9s2 9p2 8p3||9s2 9p2 8p4|
|Stable oxidation states||3||4||5||6||−1, 3, 7||0, 4, 6, 8|
|First ionization energy||617.5 kJ/mol||723.6 kJ/mol||800.8 kJ/mol||887.7 kJ/mol||984.2 kJ/mol||1090.3 kJ/mol|
|Metallic or covalent radius||190 pm||180 pm||175 pm||170 pm||165 pm||220 pm|
|Density||17 g/cm3||19 g/cm3||18 g/cm3||17 g/cm3||16 g/cm3||9 g/cm3|
Immediately after element 172 (unseptbium, the last period 8 element), the first noble gas after oganesson (the last period 7 element), it was originally expected that another long transition series like the superactinides should begin, filling at least the 6g, 7f, and 8d shells (with 10s, 10p1/2, and 6h11/2 too high in energy to contribute early in the series). These electrons would be very loosely bound, potentially rendering extremely high oxidation states reachable, though the electrons would become more tightly bound as the ionic charge rises.
In element 173 (unsepttrium), the last electron would enter the 6g7/2 subshell. Because spin-orbit interactions would create a very large energy gap between the 8p3/2 and 6g7/2 subshells, this outermost electron is expected to be very loosely bound and very easily lost to form a Ust+ cation. As a result, element 173 is expected to behave chemically like an alkali metal, and one by far more reactive than even caesium (francium and element 119 being less reactive than caesium due to relativistic effects).
Element 184 (unoctquadium) was significantly targeted in early predictions, as it was originally speculated that 184 would be a proton magic number: it is predicted to have an electron configuration of [Usb] 6g5 7f4 8d3, with at least the 7f and 8d electrons chemically active. Its chemical behaviour is expected to be similar to uranium and neptunium, as further ionisation past the +6 state (corresponding to removal of the 6g electrons) is likely to be unprofitable; the +4 state should be most common in aqueous solution, with +5 and +6 reachable in solid compounds.
The number of physically possible elements is unknown. A low estimate is that the periodic table may end soon after the island of stability, which is expected to center on Z = 126, as the extension of the periodic and nuclides tables is restricted by the proton and the neutron drip lines and stability toward alpha decay and spontaneous fission. One calculation by Y. Gambhir et al., analyzing nuclear binding energy and stability in various decay channels, suggests a limit to the existence of bound nuclei at Z = 146. Some, such as Walter Greiner, predicted that there may not be an end to the periodic table. Other predictions of an end to the periodic table include Z = 128 (John Emsley) and Z = 155 (Albert Khazan).
It is a "folk legend" among physicists that Richard Feynman suggested that neutral atoms could not exist for atomic numbers greater than Z = 137, on the grounds that the relativistic Dirac equation predicts that the ground-state energy of the innermost electron in such an atom would be an imaginary number. Here, the number 137 arises as the inverse of the fine-structure constant. By this argument, neutral atoms cannot exist beyond untriseptium (alternatively called "feynmanium"), and therefore a periodic table of elements based on electron orbitals breaks down at this point. However, this argument presumes that the atomic nucleus is pointlike. A more accurate calculation must take into account the small, but nonzero, size of the nucleus, which is predicted to push the limit further to Z ≈ 173.
where Z is the atomic number, and α is the fine structure constant, a measure of the strength of electromagnetic interactions. Under this approximation, any element with an atomic number of greater than 137 would require 1s electrons to be traveling faster than c, the speed of light. Hence, the non-relativistic Bohr model is inaccurate when applied to such an element.
where m is the rest mass of the electron. For Z > 137, the wave function of the Dirac ground state is oscillatory, rather than bound, and there is no gap between the positive and negative energy spectra, as in the Klein paradox. More accurate calculations taking into account the effects of the finite size of the nucleus indicate that the binding energy first exceeds 2mc2 for Z > Zcr ≈ 173. For Z > Zcr, if the innermost orbital (1s) is not filled, the electric field of the nucleus will pull an electron out of the vacuum, resulting in the spontaneous emission of a positron. This diving of the 1s subshell into the negative continuum has often been taken to constitute an "end" to the periodic table, although more detailed treatments suggest a less bleak outcome.
Atoms with atomic numbers above Zcr ≈ 173 have been termed supercritical atoms. Supercritical atoms cannot be totally ionised because their 1s subshell would be filled by spontaneous pair creation in which an electron-positron pair is created from the negative continuum, with the electron being bound and the positron escaping. However, the strong field around the atomic nucleus is restricted to a very small region of space, so that the Pauli exclusion principle forbids further spontaneous pair creation once the subshells that have dived into the negative continuum are filled. Elements 173–184 have been termed weakly supercritical atoms as for them only the 1s shell has dived into the negative continuum; the 2p1/2 shell is expected to join around element 185 and the 2s shell around element 245. Experiments have so far not succeeded in detecting spontaneous pair creation from assembling supercritical charges through the collision of heavy nuclei (e.g. colliding lead with uranium to momentarily give an effective Z of 174; uranium with uranium gives effective Z = 184 and uranium with californium gives effective Z = 190). Supercritical atoms are hence expected to pose no difficulties with their electronic structure, so that the end of the periodic table may be determined instead by nuclear instability rather than electron shell instabilities.
Predicted half-lives (top) and decay modes (bottom) of superheavy nuclei. The line of synthesized proton-rich nuclei is expected to be broken soon after Z = 120, because of half-lives shorter than 1 microsecond from Z = 121, the increasing contribution of spontaneous fission instead of alpha decay from Z = 122 onward until it dominates from Z = 125, and the proton drip line around Z = 130. The white rings denote the expected location of the island of stability; the two squares outlined in white denote 291Cn and 293Cn, predicted to be the longest-lived nuclides on the island with half-lives of centuries or millennia.
The stability of nuclei decreases greatly with the increase in atomic number after plutonium, the heaviest primordial element, so that all isotopes with an atomic number above 101 decay radioactively with a half-life under a day, with an exception of dubnium-268. No elements with atomic numbers above 82 (after lead) have stable isotopes. Nevertheless, because of reasons not very well understood yet, there is a slight increased nuclear stability around atomic numbers 110–114, which leads to the appearance of what is known in nuclear physics as the "island of stability". This concept, proposed by University of California professor Glenn Seaborg, explains why superheavy elements last longer than predicted.
Calculations according to the Hartree–Fock–Bogoliubov method using the non-relativistic Skyrme interaction have proposed Z = 126 as a closed proton shell. In this region of the periodic table, N = 184, N = 196, and N = 228 have been suggested as closed neutron shells. Therefore, the isotopes of most interest are 310126, 322126, and 354126, for these might be considerably longer-lived than other isotopes. Element 126, having a magic number of protons, is predicted to be more stable than other elements in this region, and may have nuclear isomers with very long half-lives. It is also possible that the island of stability is instead centered at 306122, which may be spherical and doubly magic.
Taking nuclear deformation and relativistic effects into account, an analysis of single-particle levels predicts new magic numbers for superheavy nuclei at Z = 126, 138, 154, and 164 and N = 228, 308, and 318. Therefore, in addition to the island of stability centered at 291Cn, 293Cn, and 298Fl, further islands of stability may exist around the doubly magic 354126 as well as 472164 or 482164. These nuclei are predicted to be beta-stable and decay by alpha emission or spontaneous fission with relatively long half-lives, and confer additional stability on neighboring N = 228 isotones and elements 152-168, respectively. On the other hand, the same analysis suggests that proton shell closures may be relatively weak or even nonexistent in some cases such as 354126, meaning that such nuclei might not be doubly magic and stability will instead be primarily determined by strong neutron shell closures. Additionally, due to the enormously greater forces of electromagnetic repulsion that must be overcome by the strong force at the second island (Z = 164), it is possible that nuclei around this region only exist as resonances and cannot stay together for a meaningful amount of time. It is also possible that some of the superactinides between these series may not actually exist because they are too far from both islands, in which case the periodic table might end around Z = 130.
Beyond element 164, the fissility line defining the limit of stability with respect to spontaneous fission may converge with the neutron drip line, posing a limit to the existence of heavier elements. Nevertheless, further magic numbers have been predicted at Z = 210, 274, and 354 and N = 308, 406, 524, 644, and 772, with two beta-stable doubly magic nuclei found at 616210 and 798274; the same calculation method reproduced the predictions for 298Fl and 472164. Although additional stability toward alpha decay and fission are predicted for these nuclei, with half-lives up to hundreds of microseconds for 616210, there will not exist islands of stability as significant as those predicted at Z = 114 and 164. As the existence of superheavy elements is very strongly dependent on stabilizing effects from closed shells, nuclear instability and fission will likely determine the end of the periodic table beyond these islands of stability.
As the main island of stability is thought to lie at 291Cn and 293Cn, undiscovered elements beyond oganesson may be very unstable and undergo alpha decay or spontaneous fission in microseconds or less. The exact region in which half-lives exceed one microsecond is unknown, though various models suggest that isotopes of elements heavier than unbinilium that may be produced in fusion reactions with available targets and projectiles will have half-lives under one microsecond and therefore may not be detected. It is consistently predicted that there will exist regions of stability at N = 184 and N = 228, and possibly also at Z ~ 124 and N ~ 198. These nuclei may have half-lives of a few seconds and undergo predominantly alpha decay and spontaneous fission, though minor beta-plus decay (or electron capture) branches may also exist. Outside these regions of enhanced stability, fission barriers are expected to drop significantly due to loss of stabilization effects, resulting in fission half-lives below 10−18 seconds, especially in even-even nuclei for which hindrance is even lower due to nucleon pairing. In general, alpha decay half-lives are expected to increase with neutron number, from nanoseconds in the most neutron-deficient isotopes to seconds closer to the beta-stability line. For nuclei with only a few neutrons more than a magic number, binding energy substantially drops, resulting in a break in the trend and shorter half-lives. The most neutron deficient isotopes of these elements may also be unbound and undergo proton emission. Cluster decay (heavy particle emission) has also been proposed as an alternative decay mode for some isotopes, posing yet another hurdle to identification of these elements.
The following are the expected electron configurations of elements 118–173. Beyond element 123, no complete calculations are available and hence the data in this table must be taken as tentative. In the case of element 123, and perhaps also heavier elements, several possible electron configurations are predicted to have very similar energy levels, such that it is very difficult to predict the ground state.
|Chemical element||Chemical series||Predicted electron configuration|
|118||Og||Oganesson||Noble gas||[Rn] 5f14 6d10 7s2 7p6|
|119||Uue||Ununennium||Alkali metal||[Og] 8s1|
|120||Ubn||Unbinilium||Alkaline earth metal||[Og] 8s2|
|121||Ubu||Unbiunium||Superactinide||[Og] 8s2 8p1|
|122||Ubb||Unbibium||Superactinide||[Og] 7d1 8s2 8p1|
|123||Ubt||Unbitrium||Superactinide||[Og] 6f1 7d1 8s2 8p1|
|124||Ubq||Unbiquadium||Superactinide||[Og] 6f3 8s2 8p1|
|125||Ubp||Unbipentium||Superactinide||[Og] 5g1 6f2 8s2 8p2|
|126||Ubh||Unbihexium||Superactinide||[Og] 5g2 6f3 8s2 8p1|
|127||Ubs||Unbiseptium||Superactinide||[Og] 5g3 6f2 8s2 8p2|
|128||Ubo||Unbioctium||Superactinide||[Og] 5g4 6f2 8s2 8p2|
|129||Ube||Unbiennium||Superactinide||[Og] 5g4 6f3 7d1 8s2 8p1|
|130||Utn||Untrinilium||Superactinide||[Og] 5g5 6f3 7d1 8s2 8p1|
|131||Utu||Untriunium||Superactinide||[Og] 5g6 6f3 8s2 8p2|
|132||Utb||Untribium||Superactinide||[Og] 5g7 6f3 8s2 8p2|
|133||Utt||Untritrium||Superactinide||[Og] 5g8 6f3 8s2 8p2|
|134||Utq||Untriquadium||Superactinide||[Og] 5g8 6f4 8s2 8p2|
|135||Utp||Untripentium||Superactinide||[Og] 5g9 6f4 8s2 8p2|
|136||Uth||Untrihexium||Superactinide||[Og] 5g10 6f4 8s2 8p2|
|137||Uts||Untriseptium||Superactinide||[Og] 5g11 6f4 8s2 8p2|
|138||Uto||Untrioctium||Superactinide||[Og] 5g12 6f3 7d1 8s2 8p2|
|139||Ute||Untriennium||Superactinide||[Og] 5g13 6f2 7d2 8s2 8p2|
|140||Uqn||Unquadnilium||Superactinide||[Og] 5g14 6f3 7d1 8s2 8p2|
|141||Uqu||Unquadunium||Superactinide||[Og] 5g15 6f2 7d2 8s2 8p2|
|142||Uqb||Unquadbium||Superactinide||[Og] 5g16 6f2 7d2 8s2 8p2|
|143||Uqt||Unquadtrium||Superactinide||[Og] 5g17 6f2 7d2 8s2 8p2|
|144||Uqq||Unquadquadium||Superactinide||[Og] 5g17 6f2 7d3 8s2 8p2|
|145||Uqp||Unquadpentium||Superactinide||[Og] 5g18 6f3 7d2 8s2 8p2|
|146||Uqh||Unquadhexium||Superactinide||[Og] 5g18 6f4 7d2 8s2 8p2|
|147||Uqs||Unquadseptium||Superactinide||[Og] 5g18 6f5 7d2 8s2 8p2|
|148||Uqo||Unquadoctium||Superactinide||[Og] 5g18 6f6 7d2 8s2 8p2|
|149||Uqe||Unquadennium||Superactinide||[Og] 5g18 6f6 7d3 8s2 8p2|
|150||Upn||Unpentnilium||Superactinide||[Og] 5g18 6f7 7d3 8s2 8p2|
|151||Upu||Unpentunium||Superactinide||[Og] 5g18 6f8 7d3 8s2 8p2|
|152||Upb||Unpentbium||Superactinide||[Og] 5g18 6f9 7d3 8s2 8p2|
|153||Upt||Unpenttrium||Superactinide||[Og] 5g18 6f10 7d3 8s2 8p2|
|154||Upq||Unpentquadium||Superactinide||[Og] 5g18 6f11 7d3 8s2 8p2|
|155||Upp||Unpentpentium||Superactinide||[Og] 5g18 6f12 7d3 8s2 8p2|
|156||Uph||Unpenthexium||Superactinide||[Og] 5g18 6f13 7d3 8s2 8p2|
|157||Ups||Unpentseptium||Superactinide||[Og] 5g18 6f14 7d3 8s2 8p2|
|158||Upo||Unpentoctium||Transition metal||[Og] 5g18 6f14 7d4 8s2 8p2|
|159||Upe||Unpentennium||Transition metal||[Og] 5g18 6f14 7d4 8s2 8p2|
|160||Uhn||Unhexnilium||Transition metal||[Og] 5g18 6f14 7d5 8s2 8p2|
|161||Uhu||Unhexunium||Transition metal||[Og] 5g18 6f14 7d6 8s2 8p2|
|162||Uhb||Unhexbium||Transition metal||[Og] 5g18 6f14 7d7 8s2 8p2|
|163||Uht||Unhextrium||Transition metal||[Og] 5g18 6f14 7d8 8s2 8p2|
|164||Uhq||Unhexquadium||Transition metal||[Og] 5g18 6f14 7d10 8s2 8p2|
|165||Uhp||Unhexpentium||Transition metal||[Og] 5g18 6f14 7d10 8s2 8p2|
|166||Uhh||Unhexhexium||Post-transition metal||[Og] 5g18 6f14 7d10 8s2 8p2|
|167||Uhs||Unhexseptium||Post-transition metal||[Og] 5g18 6f14 7d10 8s2 8p2|
1/2 9s2 9p1
|168||Uho||Unhexoctium||Post-transition metal||[Og] 5g18 6f14 7d10 8s2 8p2|
1/2 9s2 9p2
|169||Uhe||Unhexennium||Post-transition metal||[Og] 5g18 6f14 7d10 8s2 8p2|
3/2 9s2 9p2
|170||Usn||Unseptnilium||Post-transition metal||[Og] 5g18 6f14 7d10 8s2 8p2|
3/2 9s2 9p2
|171||Usu||Unseptunium||Post-transition metal||[Og] 5g18 6f14 7d10 8s2 8p2|
3/2 9s2 9p2
|172||Usb||Unseptbium||Noble gas||[Og] 5g18 6f14 7d10 8s2 8p2|
3/2 9s2 9p2
|173||Ust||Unsepttrium||Alkali metal||[Usb] 6g1|
The Dubna team are now upgrading their smasher ahead of attempts to synthesize Elements 119 and 120 in a series of experiments before 2012.
"The discovery of elements 115, 117 and 118 is an accomplished fact; they were placed in the periodic table, though still unnamed and will be confirmed only at the end of the year. The D.I.Mendeleev Periodic Table is not infinite. In 2019, scientists will begin the synthesis of elements 119 and 120 which are the first in the 8th period," said S.N. Dmitriev.
Расчеты при этом указывают на то, что единственный валентный электрон этого элемента будет находиться на 6g-подслое и иметь столь высокую энергию, что цезий по сравнению со 173-м можно будет считать металлом невысокой активности.
Alternative periodic tables are tabulations of chemical elements differing significantly in their organization from the traditional depiction of the periodic system. Several have been devised, often purely for didactic reasons, as not all correlations between the chemical elements are effectively captured by the standard periodic table.
Alternative periodic tables are developed often to highlight or emphasize different chemical or physical properties of the elements which are not as apparent in traditional periodic tables. Some tables aim to emphasize both the nucleon and electronic structure of atoms. This can be done by changing the spatial relationship or representation each element has with respect to another element in the table. Other tables aim to emphasize the chemical element isolations by humans over time.E123
E123 may refer to:
Amaranth (dye) or E123, a food additive
Element 123, a predicted chemical element; see Extended periodic table § Superactinides
European route E123, a road in central Asia
E.123, an ITU-T recommendation
E-123 Omega, a recurring character in Sonic the Hedgehog gamesElectron configuration
In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. For example, the electron configuration of the neon atom is 1s2 2s2 2p6, using the notation explained below.
Electronic configurations describe each electron as moving independently in an orbital, in an average field created by all other orbitals. Mathematically, configurations are described by Slater determinants or configuration state functions.
According to the laws of quantum mechanics, for systems with only one electron, a level of energy is associated with each electron configuration and in certain conditions, electrons are able to move from one configuration to another by the emission or absorption of a quantum of energy, in the form of a photon.
Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements. This is also useful for describing the chemical bonds that hold atoms together. In bulk materials, this same idea helps explain the peculiar properties of lasers and semiconductors.Extended periodic table (detailed cells)
This is a large version of the extended periodic table of the chemical elements. For the natural isotopic composition of each element it shows name, atomic number, symbol, standard atomic weight (or atomic weight) and a link to the element's isotopes. It also has, by keyed markings, a notification of occurrence, state of matter and metallic character. It is named extended because it shows elements that are theoretical only (in period 8), and large means that the table might exceed page width. The presentation is wide which means that there are no table parts separated (as is more common in print).
The current standard table contains 7 periods, culminating in oganesson, which has atomic number 118. The layout of the table has been refined and extended over time, as new elements have been discovered, and new theoretical models have been developed to explain chemical behavior. If further elements with higher atomic numbers than this are discovered, they will be placed in additional periods, laid out (as with the existing periods) to illustrate periodically recurring trends in the properties of the elements concerned. Any additional periods are expected to contain a larger number of elements than the seventh period, as they are calculated to have an additional so-called g-block, containing 18 elements with partially filled g-orbitals in each period. An eight-period table containing this block was suggested by Glenn T. Seaborg in 1969.It is not known how many elements are physically possible, if period 8 is complete, or if there is a period 9.Index of chemistry articles
Chemistry (from Egyptian kēme (chem), meaning "earth") is the physical science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions.Below is a list of chemistry-related articles. Chemical compounds are listed separately at list of organic compounds, list of inorganic compounds or list of biomolecules.Index of physics articles (E)
The index of physics articles is split into multiple pages due to its size.
To navigate by individual letter use the table of contents below.Nuclear drip line
The nuclear drip line is the boundary delimiting the zone beyond which atomic nuclei decay by the emission of a proton or neutron.
An arbitrary combination of protons and neutrons does not necessarily yield a stable nucleus. One can think of moving up and/or to the right across the table of nuclides by adding one type of nucleon to a given nucleus. However, adding nucleons one at a time to a given nucleus will eventually lead to a newly formed nucleus that immediately decays by emitting a proton (or neutron). Colloquially speaking, the nucleon has 'leaked' or 'dripped' out of the nucleus, hence giving rise to the term "drip line".
Drip lines are defined for protons and neutrons at the extreme of the proton-to-neutron ratio; at p:n ratios at or beyond the drip lines, no bound nuclei can exist. While the location of the proton drip line is well known for many elements, the location of the neutron drip line is only known for elements up to neon.Period (periodic table)
A period in the periodic table is a row of chemical elements. All elements in a row have the same number of electron shells. Each next element in a period has one more proton and is less metallic than its predecessor. Arranged this way, groups of elements in the same column have similar chemical and physical properties, reflecting the periodic law. For example, the alkali metals lie in the first column (group 1) and share similar properties, such as high reactivity and the tendency to lose one electron to arrive at a noble-gas electronic configuration. As of 2016, a total of 118 elements have been discovered and confirmed.
Modern quantum mechanics explains these periodic trends in properties in terms of electron shells. As atomic number increases, shells fill with electrons in approximately the order shown at right. The filling of each shell corresponds to a row in the table.
In the s-block and p-block of the periodic table, elements within the same period generally do not exhibit trends and similarities in properties (vertical trends down groups are more significant). However, in the d-block, trends across periods become significant, and in the f-block elements show a high degree of similarity across periods.Periodic table
The periodic table, also known as the periodic table of elements, is a tabular display of the chemical elements, which are arranged by atomic number, electron configuration, and recurring chemical properties. The structure of the table shows periodic trends. The seven rows of the table, called periods, generally have metals on the left and non-metals on the right. The columns, called groups, contain elements with similar chemical behaviours. Six groups have accepted names as well as assigned numbers: for example, group 17 elements are the halogens; and group 18 are the noble gases. Also displayed are four simple rectangular areas or blocks associated with the filling of different atomic orbitals.
The organization of the periodic table can be used to derive relationships between the various element properties, and also to predict chemical properties and behaviours of undiscovered or newly synthesized elements. Russian chemist Dmitri Mendeleev published the first recognizable periodic table in 1869, developed mainly to illustrate periodic trends of the then-known elements. He also predicted some properties of unidentified elements that were expected to fill gaps within the table. Most of his forecasts proved to be correct. Mendeleev's idea has been slowly expanded and refined with the discovery or synthesis of further new elements and the development of new theoretical models to explain chemical behaviour. The modern periodic table now provides a useful framework for analyzing chemical reactions, and continues to be widely used in chemistry, nuclear physics and other sciences.
The elements from atomic numbers 1 (hydrogen) through 118 (oganesson) have been discovered or synthesized, completing seven full rows of the periodic table. The first 94 elements all occur naturally, though some are found only in trace amounts and a few were discovered in nature only after having first been synthesized. Elements 95 to 118 have only been synthesized in laboratories or nuclear reactors. The synthesis of elements having higher atomic numbers is currently being pursued: these elements would begin an eighth row, and theoretical work has been done to suggest possible candidates for this extension. Numerous synthetic radionuclides of naturally occurring elements have also been produced in laboratories.Timeline of chemical element discoveries
The discovery of the 118 chemical elements known to exist as of 2019 is presented in chronological order. The elements are listed generally in the order in which each was first defined as the pure element, as the exact date of discovery of most elements cannot be accurately determined. There are plans to synthesise more elements, and it is not known how many elements are possible.
Each element's name, atomic number, year of first report, name of the discoverer, and notes related to the discovery are listed.UHB
UHB may refer to:
Hokkaido Cultural Broadcasting, a television company in Hokkaidō, Japan
University of Rennes 2 - Upper Brittany, short for Université Rennes 2 - Haute Bretagne
Urskog-Hølandsbanen, a railway in Norway
University Hospitals Birmingham NHS Foundation Trust, a UK hospital
Ultra-High Bypass turbofan, an engine known as a Propfan
Uhb, the 162nd element of extended periodic tableUPT
UPT and Upt can stand for:
United Paramount Theaters
Universal Personal Telecommunications
University of Pittsburgh at Titusville
Unlimited Paenga Tawhiti, secondary school in Christchurch City, New Zealand
Unpenttrium, a hypothetical chemical element in the extended periodic table with the temporary symbol Upt
Upper Palatinate Tower, an observation tower
Uptown New Orleans
UK railway stations – U in the UK
Universitatea Politehnica, din Timişoara (Polytechnic University of Timișoara), Romania
Universidade Portucalense Infante D. Henrique (UPT), PortugalUnbibium
Unbibium, also known as element 122 or eka-thorium, is the hypothetical chemical element in the periodic table with the placeholder symbol of Ubb and atomic number 122. Unbibium and Ubb are the temporary systematic IUPAC name and symbol respectively, until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table of the elements, it is expected to follow unbiunium as the second element of the superactinides and the fourth element of the 8th period. It has attracted recent attention, for similarly to unbiunium, it is expected to fall within the range of the island of stability, potentially conferring additional stability on some isotopes, especially 306Ubb which is expected to have a magic number of neutrons (184).
Despite several attempts, unbibium has not yet been synthesized, nor have any naturally occurring isotopes been found to exist. There are currently no plans to attempt to synthesize unbibium. In 2008, it was claimed to have been discovered in natural thorium samples, but that claim has now been dismissed by recent repetitions of the experiment using more accurate techniques.
Chemically, unbibium is expected to show some resemblance to its lighter congeners cerium and thorium. However, relativistic effects may cause some of its properties to differ; for example, it is expected to have a ground state electron configuration of [Og] 7d18s28p1, despite its predicted position in the g-block superactinide series.Unbihexium
Unbihexium, also known as element 126 or eka-plutonium, is the hypothetical chemical element with atomic number 126 and placeholder symbol Ubh. Unbihexium and Ubh are the temporary IUPAC name and symbol, respectively, until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table, unbihexium is expected to be a g-block superactinide and the eighth element in the 8th period. Unbihexium has attracted attention, especially in early predictions targeting properties of superheavy elements, for 126 may be a magic number of protons near the center of an island of stability, leading to longer half-lives, especially for 310Ubh or 354Ubh which may also have magic numbers of neutrons.
Early interest in possible increased stability led to the first attempted synthesis of unbihexium in 1971 and searches for it in nature in subsequent years. Despite several reported observations, more recent studies suggest that these experiments were insufficiently sensitive; hence, no unbihexium has been found naturally or artificially. The stability of unbihexium is also widely debated, as the island of stability may in fact lie at a lower atomic number, closer to copernicium and flerovium.
Unbihexium is predicted to be a chemically active superactinide, exhibiting a variety of oxidation states from +1 to +8, and possibly being a heavier congener of plutonium. It is predicted to be the second element with an electron in a g orbital, a consequence of relativistic effects seen only in heavy and superheavy elements. An overlap in energy levels of the 5g, 6f, 7d, and 8p orbitals is also expected, which complicates predictions of chemical properties for this element.Unbinilium
Unbinilium, also known as eka-radium or simply element 120, is the hypothetical chemical element in the periodic table with symbol Ubn and atomic number 120. Unbinilium and Ubn are the temporary systematic IUPAC name and symbol, until a permanent name is decided upon. In the periodic table of the elements, it is expected to be an s-block element, an alkaline earth metal, and the second element in the eighth period. It has attracted attention because of some predictions that it may be in the island of stability, although newer calculations expect the island to actually occur at a slightly lower atomic number, closer to copernicium and flerovium.
Unbinilium has not yet been synthesized, despite multiple attempts from German and Russian teams. One 2011 attempt from the German team at the GSI Helmholtz Centre for Heavy Ion Research had a suggestive but not conclusive result suggesting the possible production of 299Ubn, but the data was incomplete and did not match theoretical expectations. Planned attempts from Russian, Japanese, and French teams are scheduled for 2017–2020. Experimental evidence from these attempts shows that the period 8 elements would likely be far more difficult to synthesise than the previous known elements, and that unbinilium may even be the last element that can be synthesized with current technology.
Unbinilium's position as the seventh alkaline earth metal suggests that it would have similar properties to its lighter congeners, beryllium, magnesium, calcium, strontium, barium, and radium; however, relativistic effects may cause some of its properties to differ from those expected from a straight application of periodic trends. For example, unbinilium is expected to be less reactive than barium and radium and be closer in behavior to strontium, and while it should show the characteristic +2 oxidation state of the alkaline earth metals, it is also predicted to show the +4 oxidation state, which is unknown in any other alkaline earth metals.Unbiquadium
Unbiquadium, also known as element 124 or eka-uranium, is the hypothetical chemical element with atomic number 124 and placeholder symbol Ubq. Unbiquadium and Ubq are the temporary IUPAC name and symbol, respectively, until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table, unbiquadium is expected to be a g-block superactinide and the sixth element in the 8th period. Unbiquadium has attracted attention, as it may lie within the island of stability, leading to longer half-lives, especially for 308Ubq which is predicted to have a magic number of neutrons (184).
Despite several searches, unbiquadium has not been synthesized, nor have any naturally occurring isotopes been found to exist. It is believed that the synthesis of unbiquadium will be far more challenging than that of lighter undiscovered elements, and nuclear instability may pose further difficulties in identifying unbiquadium, unless the island of stability has a stronger stabilizing effect than predicted in this region.
As a member of the superactinide series, unbiquadium is expected to bear some resemblance to its possible lighter congener uranium. The valence electrons of unbiquadium are expected to participate in chemical reactions fairly easily, though relativistic effects may significantly influence some of its properties; for example, the electron configuration has been calculated to differ considerably from the one predicted by the Aufbau principle.Unbiunium
Unbiunium, also known as eka-actinium or simply element 121, is the hypothetical chemical element with symbol Ubu and atomic number 121. Unbiunium and Ubu are the temporary systematic IUPAC name and symbol respectively, until a permanent name is decided upon. In the periodic table of the elements, it is expected to be the first of the superactinides, and the third element in the eighth period: analogously to lanthanum and actinium, it could be considered the fifth member of group 3 and the first member of the fifth-row transition metals. It has attracted attention because of some predictions that it may be in the island of stability, although newer calculations expect the island to actually occur at a slightly lower atomic number, closer to copernicium and flerovium.
Unbiunium has not yet been synthesized. Nevertheless, because it is only three elements away from the heaviest known element, oganesson (element 118), its synthesis may come in the near future; it is expected to be one of the last few reachable elements with current technology, and the limit may be anywhere between element 120 and 124. It will also likely be far more difficult to synthesize than the elements known so far up to 118, and still more difficult than elements 119 and 120. The team at RIKEN in Japan has plans to attempt the synthesis of element 121 in the future after its attempts on elements 119 and 120.
The position of unbiunium in the periodic table suggests that it would have similar properties to its lighter congeners, scandium, yttrium, lanthanum, and actinium; however, relativistic effects may cause some of its properties to differ from those expected from a straight application of periodic trends. For example, unbiunium is expected to have a s2p valence electron configuration instead of the s2d of its lighter congeners in group 3, but this is not expected to significantly affect its chemistry, which is predicted to be that of a normal group 3 element; it would on the other hand significantly lower its first ionisation energy beyond what would be expected from periodic trends.Ununennium
Ununennium, also known as eka-francium or element 119, is the hypothetical chemical element with symbol Uue and atomic number 119. Ununennium and Uue are the temporary systematic IUPAC name and symbol respectively, until its discovery is confirmed and a permanent name is decided upon. In the periodic table of the elements, it is expected to be an s-block element, an alkali metal, and the first element in the eighth period. It is the lightest element that has not yet been synthesized.
Experiments aimed at the synthesis of ununennium began in June 2018 at RIKEN in Japan; another attempt by the team at the Joint Institute for Nuclear Research at Dubna, Russia is scheduled to begin in 2019. Prior to this, two unsuccessful attempts had been made to synthesize ununennium, one by an American team and one by a German team. Theoretical and experimental evidence has shown that the synthesis of ununennium would likely be far more difficult than that of the previous elements, and it may even be one of the last two elements (with unbinilium) that can be synthesized with current technology.
Ununennium's position as the seventh alkali metal suggests that it would have similar properties to its lighter congeners: lithium, sodium, potassium, rubidium, caesium, and francium; however, relativistic effects may cause some of its properties to differ from those expected from a straight application of periodic trends. For example, ununennium is expected to be less reactive than caesium and francium and to be closer in behavior to potassium or rubidium, and while it should show the characteristic +1 oxidation state of the alkali metals, it is also predicted to show the +3 oxidation state, which is unknown in any other alkali metal.
Extended periodic table (Large version)
Extended periodic table (Large version)
|Periodic table forms|
|Sets of elements|