Cerium(III) carbonate

Cerium(III) carbonate Ce2(CO3)3, is the salt formed by cerium(III) cations and carbonate anions. Its pure form was not yet confirmed to exist in the nature, but Ce-bearing carbonates (mainly bastnäsite group) stand for an ore of cerium metal, along with monazite.

Cerium(III) CARBONATE
Names
IUPAC names
Cerium(III) carbonate
Cerium tricarbonate
Other names
Cerous carbonate
Identifiers
3D model (JSmol)
ECHA InfoCard 100.007.870
EC Number
  • 208-655-6
UNII
Properties
Ce2(CO3)3
Molar mass 460.26 g/mol
Appearance white solid
Melting point 500 °C (932 °F; 773 K)
negligible
Hazards
not listed
Flash point Non-flammable
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Molecular weight

The molecular weight of the compound of cerium(III) carbonate is 460.2587g/mole.[1]

Different names

IUPAC name:Cerium tricarbonate.[2] Other chemical names: Dicerium tricarbonate;Cerium(III) carbonate;Cerium carbonate;Cerous Carbonate;Dicerium(3+)Ion Tricarbonate.

Uses

Cerium(III) carbonate is used in the production of cerium(III) chloride, and in incandescent lamps.[3]

References

  1. ^ http://www.endmemo.com/chem/compound/ce2co3_3.php
  2. ^ https://pubchem.ncbi.nlm.nih.gov/compound/160516#section=Names-and-Identifiers
  3. ^ www.alfa.com
Cerium(III) methanesulfonate

Cerium(III) methanesulfonate is a white salt, usually found as the dihydrate with the formula Ce(CH3SO3)3·2H2O that precipitates from the neutralisation of cerium(III) carbonate with methanesulfonic acid, as first reported by L.B. Zinner in 1979. The crystals have a monoclinic polymeric structure were each methanesulfonate ion forms bonds with two cerium atoms, which present a coordination number of 8. The anhydrous salt is formed by water loss at 120 °C. Similar methanesulfonates can be prepared with other lanthanides. Cerium(III) methanesulfonate in solution is used as a precursor of electrogenerated cerium(IV), which is a strong oxidant and whose salts can be used in organic synthesis. The same principle of Ce(IV) electrogeneration is the fundamental reaction in the positive half-cell of the zinc–cerium battery.

List of inorganic compounds

Although most compounds are referred to by their IUPAC systematic names (following IUPAC nomenclature), "traditional" names have also been kept where they are in wide use or of significant historical interests.

Cerium compounds
Cerium(III)
Cerium(III,IV)
Cerium(IV)

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