The boron group are the chemical elements in group 13 of the periodic table, comprising boron (B), aluminium (Al), gallium (Ga), indium (In), thallium (Tl), and perhaps also the chemically uncharacterized nihonium (Nh). The elements in the boron group are characterized by having three electrons in their outer energy levels (valence layers). These elements have also been referred to as the triels.[note 1]
Boron is classified as a typical non-metal while the rest, with the possible exception of nihonium, are considered post-transition metals. Boron occurs sparsely, probably because bombardment by the subatomic particles produced from natural radioactivity disrupts its nuclei. Aluminium occurs widely on earth, and indeed is the third most abundant element in the Earth's crust (8.3%). Gallium is found in the earth with an abundance of 13 ppm. Indium is the 61st most abundant element in the earth's crust, and thallium is found in moderate amounts throughout the planet. Nihonium is never found in nature and therefore is termed a synthetic element.
Several group 13 elements have biological roles in the ecosystem. Boron is a trace element in humans and is essential for some plants. Lack of boron can lead to stunted plant growth, while an excess can also cause harm by inhibiting growth. Aluminium has neither a biological role nor significant toxicity and is considered safe. Indium and gallium can stimulate metabolism; gallium is credited with the ability to bind itself to iron proteins. Thallium is highly toxic, interfering with the function of numerous vital enzymes, and has seen use as a pesticide.
|Boron group (group 13)|
13 Post-transition metal
31 Post-transition metal
49 Post-transition metal
81 Post-transition metal
113 unknown chemical properties
Like other groups, the members of this family show patterns in electron configuration, especially in the outermost shells, resulting in trends in chemical behavior:
|Z||Element||No. of electrons per shell|
|13||aluminium||2, 8, 3|
|31||gallium||2, 8, 18, 3|
|49||indium||2, 8, 18, 18, 3|
|81||thallium||2, 8, 18, 32, 18, 3|
|113||nihonium||2, 8, 18, 32, 32, 18, 3 (predicted)|
The boron group is notable for trends in the electron configuration, as shown above, and in some of its elements' characteristics. Boron differs from the other group members in its hardness, refractivity and reluctance to participate in metallic bonding. An example of a trend in reactivity is boron's tendency to form reactive compounds with hydrogen.
Most of the elements in the boron group show increasing reactivity as the elements get heavier in atomic mass and higher in atomic number. Boron, the first element in the group, is generally unreactive with many elements except at high temperatures, although it is capable of forming many compounds with hydrogen, sometimes called boranes. The simplest borane is diborane, or B2H6. Another example is B10H14.
The next group-13 elements, aluminium and gallium, form fewer stable hydrides, although both AlH3 and GaH3 exist. Indium, the next element in the group, is not known to form many hydrides, except in complex compounds such as the phosphine complex H3InP(Cy)3. No stable compound of thallium and hydrogen has been synthesized in any laboratory.
All of the boron-group elements are known to form a trivalent oxide, with two atoms of the element bonded covalently with three atoms of oxygen. These elements show a trend of increasing pH (from acidic to basic). Boron oxide (B2O3) is slightly acidic, aluminium and gallium oxide (Al2O3 and Ga2O3 respectively) are amphoteric, indium(III) oxide (In2O3) is nearly amphoteric, and thallium(III) oxide (Tl2O3) is a Lewis base because it dissolves in acids to form salts. Each of these compounds are stable, but thallium oxide decomposes at temperatures higher than 875 °C.
The elements in group 13 are also capable of forming stable compounds with the halogens, usually with the formula MX3 (where M is a boron-group element and X is a halogen.) Fluorine, the first halogen, is able to form stable compounds with every element that has been tested (except neon and helium), and the boron group is no exception. It is even hypothesized that nihonium could form a compound with fluorine, NhF3, before spontaneously decaying due to nihonium's radioactivity. Chlorine also forms stable compounds with all of the elements in the boron group, including thallium, and is hypothesized to react with nihonium. All of the elements will react with bromine under the right conditions, as with the other halogens but less vigorously than either chlorine or fluorine. Iodine will react with all natural elements in the periodic table except for the noble gases, and is notable for its explosive reaction with aluminium to form 2AlI3. Astatine, the heaviest halogen, has only formed a few compounds, due to its radioactivity and short half-life, and no reports of a compound with an At–B, –Al, –Ga, –In, –Tl, or –Nh bond have been seen, although scientists think that it should form salts with metals.
It has been noticed that the elements in the boron group have similar physical properties, although most of boron's are exceptional. For example, all of the elements in the boron group, except for boron itself, are soft. Moreover, all of the other elements in group 13 are relatively reactive at moderate temperatures, while boron's reactivity only becomes comparable at very high temperatures. One characteristic that all do have in common is having three electrons in their valence shells. Boron, being a metalloid, is a thermal and electrical insulator at room temperature, but a good conductor of heat and electricity at high temperatures. Unlike boron, the metals in the group are good conductors under normal conditions. This is in accordance with the long-standing generalization that all metals conduct heat and electricity better than most non-metals.
The inert s-pair effect is significant in the group-13 elements, especially the heavier ones like thallium. This results in a variety of oxidation states. In the lighter elements, the +3 state is the most stable, but the +1 state becomes more prevalent with increasing atomic number, and is the most stable for thallium. Boron is capable of forming compounds with lower oxidization states, of +1 or +2, and aluminium can do the same. Gallium can form compounds with the oxidation states +1, +2 and +3. Indium is like gallium, but its +1 compounds are more stable than those of the lighter elements. The strength of the inert-pair effect is maximal in thallium, which is generally only stable in the oxidation state of +1, although the +3 state is seen in some compounds. Stable and monomeric gallium, indium and thallium radicals with a formal oxidation state of +2 have since been reported.
There are several trends that one could notice as they look at the properties of Boron group members. The Boiling Points of these elements drop from period to period, while densities tend to rise.
|Element||Boiling Point (C)||Density (g/cm3)|
With the exception of the synthetic nihonium, all of the elements of the boron group have stable isotopes. Because all their atomic numbers are odd, boron, gallium and thallium have only two stable isotopes, while aluminium and indium are monoisotopic, having only one, although most indium found in nature is the weakly radioactive 115In. 10B and 11B are both stable, as are 27Al, 69Ga and 71Ga, 113In, and 203Tl and 205Tl. All of these isotopes are readily found in macroscopic quantities in nature. In theory, though, all isotopes with an atomic number greater than 66 are supposed to be unstable to alpha decay. Conversely, all elements with atomic numbers are less than or equal to 66 (except Tc, Pm, Sm and Eu) have at least one isotope that is theoretically energetically stable to all forms of decay (with the exception of proton decay, which has never been observed, and spontaneous fission, which is theoretically possible for elements with atomic numbers greater than 40).
Like all other elements, the elements of the boron group have radioactive isotopes, either found in trace quantities in nature or produced synthetically. The longest-lived of these unstable isotopes is the indium isotope 115In, with its extremely long half-life of 4.41 × 1014 y. This isotope makes up the vast majority of all naturally occurring indium despite its slight radioactivity. The shortest-lived is 7B, with a half-life of a mere 350±50 × 10−24 s, being the boron isotope with the fewest neutrons and a half-life long enough to measure. Some radioisotopes have important roles in scientific research; a few are used in the production of goods for commercial use or, more rarely, as a component of finished products.
The boron group has had many names over the years. According to former conventions it was Group IIIB in the European naming system and Group IIIA in the American. The group has also gained two collective names, "earth metals" and "triels". The latter name is derived from the Latin prefix tri- ("three") and refers to the three valence electrons that all of these elements, without exception, have in their valence shells.
Boron was known to the ancient Egyptians, but only in the mineral borax. The metalloid element was not known in its pure form until 1808, when Humphry Davy was able to extract it by the method of electrolysis. Davy devised an experiment in which he dissolved a boron-containing compound in water and sent an electric current through it, causing the elements of the compound to separate into their pure states. To produce larger quantities he shifted from electrolysis to reduction with sodium. Davy named the element boracium. At the same time two French chemists, Joseph Louis Gay-Lussac and Louis Jacques Thénard, used iron to reduce boric acid. The boron they produced was oxidized to boron oxide.
Aluminium, like boron, was first known in minerals before it was finally extracted from alum, a common mineral in some areas of the world. Antoine Lavoisier and Humphry Davy had each separately tried to extract it. Although neither succeeded, Davy had given the metal its current name. It was only in 1825 that the Danish scientist Hans Christian Ørsted successfully prepared a rather impure form of the element. Many improvements followed, a significant advance being made just two years later by Friedrich Wöhler, whose slightly modified procedure still yielded an impure product. The first pure sample of aluminium is credited to Henri Etienne Sainte-Claire Deville, who substituted sodium for potassium in the procedure. At that time aluminium was considered precious, and it was displayed next to such metals as gold and silver. The method used today, electrolysis of aluminium oxide dissolved in cryolite, was developed by Charles Martin Hall and Paul Héroult in the late 1880s.
Thallium, the heaviest stable element in the boron group, was discovered by William Crookes and Claude-Auguste Lamy in 1861. Unlike gallium and indium, thallium had not been predicted by Dmitri Mendeleev, having been discovered before Mendeleev invented the periodic table. As a result, no one was really looking for it until the 1850s when Crookes and Lamy were examining residues from sulfuric acid production. In the spectra they saw a completely new line, a streak of deep green, which Crookes named after the Greek word θαλλός (thallos), referring to a green shoot or twig. Lamy was able to produce larger amounts of the new metal and determined most of its chemical and physical properties.
Indium is the fourth element of the boron group but was discovered before the third, gallium, and after the fifth, thallium. In 1863 Ferdinand Reich and his assistant, Hieronymous Theodor Richter, were looking in a sample of the mineral zinc blende, also known as sphalerite (ZnS), for the spectroscopic lines of the newly discovered element thallium. Reich heated the ore in a coil of platinum metal and observed the lines that appeared in a spectroscope. Instead of the green thallium lines that he expected, he saw a new line of deep indigo-blue. Concluding that it must come from a new element, they named it after the characteristic indigo color it had produced.
Gallium minerals were not known before August 1875, when the element itself was discovered. It was one of the elements that the inventor of the periodic table, Dmitri Mendeleev, had predicted to exist six years earlier. While examining the spectroscopic lines in zinc blende the French chemist Paul Emile Lecoq de Boisbaudran found indications of a new element in the ore. In just three months he was able to produce a sample, which he purified by dissolving it in a potassium hydroxide (KOH) solution and sending an electric current through it. The next month he presented his findings to the French Academy of Sciences, naming the new element after the Greek name for Gaul, modern France.
The last confirmed element in the boron group, nihonium, was not discovered but rather created or synthesized. The element's synthesis was first reported by the Dubna Joint Institute for Nuclear Research team in Russia and the Lawrence Livermore National Laboratory in the United States, though it was the Dubna team who successfully conducted the experiment in August 2003. Nihonium was discovered in the decay chain of moscovium, which produced a few precious atoms of nihonium. The results were published in January of the following year. Since then around 13 atoms have been synthesized and various isotopes characterized. However, their results did not meet the stringent criteria for being counted as a discovery, and it was the later RIKEN experiments of 2004 aimed at directly synthesizing nihonium that were acknowledged by IUPAC as the discovery.
The name "boron" comes from the Arabic word for the mineral borax,(بورق, boraq) which was known before boron was ever extracted. The "-on" suffix is thought to have been taken from "carbon"; so the name can regarded as a portmanteau of "borax" and "carbon". Aluminium was named by Humphry Davy in the early 1800s. It is derived from the Greek word alumen, meaning bitter salt, or the Latin alum, the mineral. Gallium is derived from the Latin Gallia, referring to France, the place of its discovery. Indium comes from the Latin word indicum, meaning indigo dye, and refers to the element's prominent indigo spectroscopic line. Thallium, like indium, is named after the Greek word for the color of its spectroscopic line: thallos, meaning a green twig or shoot. "Nihonium" is named after Japan (Nihon in Japanese), where it was discovered.
Boron, with its atomic number of 5, is a very light element. Almost never found free in nature, it is very low in abundance, composing only 0.001% (10 ppm) of the Earth's crust. It is known to occur in over a hundred different minerals and ores, however: the main source is borax, but it is also found in colemanite, boracite, kernite, tusionite, berborite and fluoborite. Major world miners and extractors of boron include the United States, Turkey, Argentina, China, Bolivia and Peru. Turkey is by far the most prominent of these, accounting for around 70% of all boron extraction in the world. The United States is second, most of its yield coming from the state of California.
Aluminium, in contrast to boron, is the most abundant metal in the Earth's crust, and the third most abundant element. It composes about 8.2% (82,000 ppm) of the Earth, surpassed only by oxygen and silicon. It is like boron, however, in that it is uncommon in nature as a free element. This is due to aluminium’s tendency to attract oxygen atoms, forming several aluminium oxides. Aluminium is now known to occur in nearly as many minerals as boron, including garnets, turquoises and beryls, but the main source is the ore bauxite. The world's leading countries in the extraction of aluminium are Ghana, Surinam, Russia and Indonesia, followed by Australia, Guinea and Brazil.
Gallium is a relatively rare element in the Earth's crust and is not found in as many minerals as its lighter homologues. Its abundance on the Earth is a mere 0.0018% (18 ppm). Its production is very low compared to other elements, but has increased greatly over the years as extraction methods have improved. Gallium can be found as a trace in a variety of ores, including bauxite and sphalerite, and in such minerals as diaspore and germanite. Trace amounts have been found in coal as well. The gallium content is greater in a few minerals, including gallite (CuGaS2), but these are too rare to be counted as major sources and make negligible contributions to the world's supply.
Indium is another rare element in the boron group. Even less abundant than gallium at only 0.000005% (0.05 ppm), it is the 61st most common element in the earth's crust. Very few indium-containing minerals are known, all of them scarce: an example is indite. Indium is found in several zinc ores, but only in minute quantities; likewise some copper and lead ores contain traces. As is the case for most other elements found in ores and minerals, the indium extraction process has become more efficient in recent years, ultimately leading to larger yields. Canada is the world's leader in indium reserves, but both the United States and China have comparable amounts.
Thallium is neither rare nor common in the Earth's crust, but falls somewhere in the middle. Its abundance is estimated to be 0.00006% (0.6 ppm). Thallium is the 56th most common element in the earth's crust, more abundant than indium by a sizeable amount. It is found on the ground in some rocks, in the soil and in clay. Many sulfide ores of iron, zinc and cobalt contain thallium. In minerals it is found in moderate quantities: some examples are crookesite (in which it was first discovered), lorandite, routhierite, bukovite, hutchinsonite and sabatierite. There are other minerals that contain small amounts of thallium, but they are very rare and do not serve as primary sources.
Nihonium is an element that is never found in nature but has been created in a laboratory. It is therefore classified as a synthetic element with no stable isotopes.
With the exception of synthetic nihonium, all the elements in the boron group have numerous uses and applications in the production and content of many items.
Boron has found many industrial applications in recent decades, and new ones are still being found. A common application is in fiberglass. There has been rapid expansion in the market for borosilicate glass; most notable among its special qualities is a much greater resistance to thermal expansion than regular glass. Another commercially expanding use of boron and its derivatives is in ceramics. Several boron compounds, especially the oxides, have unique and valuable properties that have led to their substitution for other materials that are less useful. Boron may be found in pots, vases, plates, and ceramic pan-handles for its insulating properties.
The compound borax is used in bleaches, for both clothes and teeth. The hardness of boron and some of its compounds give it a wide array of additional uses. A small part (5%) of the boron produced finds use in agriculture.
Aluminium is a metal with numerous familiar uses in everyday life. It is most often encountered in construction materials, in electrical devices, especially as the conductor in cables, and in tools and vessels for cooking and preserving food. Aluminium's lack of reactivity with food products makes it particularly useful for canning. Its high affinity for oxygen makes it a powerful reducing agent. Finely powdered pure aluminium oxidizes rapidly in air, generating a huge amount of heat in the process (burning at about 5500 °F or 3037 °C), leading to applications in welding and elsewhere that a large amount of heat is needed. Aluminium is a component of alloys used for making lightweight bodies for aircraft. Cars also sometimes incorporate aluminium in their framework and body, and there are similar applications in military equipment. Less common uses include components of decorations and some guitars. The element is also sees use in a diverse range of electronics.
Gallium and its derivatives have only found applications in recent decades. Gallium arsenide has been used in semiconductors, in amplifiers, in solar cells (for example in satellites) and in tunnel diodes for FM transmitter circuits. Gallium alloys are used mostly for dental purposes. Gallium ammonium chloride is used for the leads in transistors. A major application of gallium is in LED lighting. The pure element has been used as a dopant in semiconductors, and has additional uses in electronic devices with other elements. Gallium has the property of being able to 'wet' glass and porcelain, and thus can be used to make mirrors and other highly reflective objects. Gallium can be added to alloys of other metals to lower their melting points.
Indium's uses can be divided into four categories: the largest part (70%) of the production is used for coatings, usually combined as indium tin oxide (ITO); a smaller portion (12%) goes into alloys and solders; a similar amount is used in electrical components and in semiconductors; and the final 6% goes to minor applications. Among the items in which indium may be found are platings, bearings, display devices, heat reflectors, phosphors, and nuclear control rods. Indium tin oxide has found a wide range of applications, including glass coatings, solar panels, streetlights, electrophosetic displays (EPDs), electroluminescent displays (ELDs), plasma display panels (PDPs), electrochemic displays (ECs), field emission displays (FEDs), sodium lamps, windshield glass and cathode ray tubes, making it the single most important indium compound.
Thallium is used in its elemental form more often than the other boron-group elements. Uncompounded thallium is used in low-melting glasses, photoelectric cells, switches, mercury alloys for low-range glass thermometers, and thallium salts. It can be found in lamps and electronics, and is also used in myocardial imaging. The possibility of using thallium in semiconductors has been researched, and it is a known catalyst in organic synthesis. Thallium hydroxide (TlOH) is used mainly in the production of other thallium compounds. Thallium sulfate (Tl2SO4) is an outstanding vermin-killer, and it is a principal component in some rat and mouse poisons. However, the United States and some European countries have banned the substance because of its high toxicity to humans. In other countries, though, the market for the substance is growing. Tl2SO4 is also used in optical systems.
None of the group-13 elements has a major biological role in complex animals, but some are at least associated with a living being. As in other groups, the lighter elements usually have more biological roles than the heavier. The heaviest ones are toxic, as are the other elements in the same periods. Boron is essential in most plants, whose cells use it for such purposes as strengthening cell walls. It is found in humans, certainly as a trace element, but there is ongoing debate over its significance in human nutrition. Boron's chemistry does allow it to form complexes with such important molecules as carbohydrates, so it is plausible that it could be of greater use in the human body than previously thought. Boron has also been shown to be able to replace iron in some of its functions, particularly in the healing of wounds. Aluminium has no known biological role in plants or animals. Gallium is not essential for the human body, but its relation to iron(III) allows it to become bound to proteins that transport and store iron. Gallium can also stimulate metabolism. Indium and its heavier homologues have no biological role, although indium salts in small doses, like gallium, can stimulate metabolism.
All of the elements in the boron group can be toxic, given a high enough dose. Some of them are only toxic to plants, some only to animals, and some to both.
As an example of boron toxicity, it has been observed to harm barley in concentrations exceeding 20 mM. The symptoms of boron toxicity are numerous in plants, complicating research: they include reduced cell division, decreased shoot and root growth, decreased production of leaf chlorophyll, inhibition of photosynthesis, lowering of stomata conductance, reduced proton extrusion from roots, and deposition of lignin and suborgin.
Aluminium does not present a prominent toxicity hazard in small quantities, but very large doses are slightly toxic. Gallium is not considered toxic, although it may have some minor effects. Indium is not toxic and can be handled with nearly the same precautions as gallium, but some of its compounds are slightly to moderately toxic.
Thallium, unlike gallium and indium, is extremely toxic, and has caused many poisoning deaths. Its most noticeable effect, apparent even from tiny doses, is hair loss all over the body, but it causes a wide range of other symptoms, disrupting and eventually halting the functions of many organs. The nearly colorless, odorless and tasteless nature of thallium compounds has led to their use by murderers. The incidence of thallium poisoning, intentional and accidental, increased when thallium (with its similarly toxic compound, thallium sulfate) was introduced to control rats and other pests. The use of thallium pesticides has therefore been prohibited since 1975 in many countries, including the USA.
Nihonium is a highly unstable element and decays by emitting alpha particles. Due to its strong radioactivity, it would definitely be extremely toxic, although significant quantities of nihonium (larger than a few atoms) have not yet been assembled.
The alkali metals are a group (column) in the periodic table consisting of the chemical elements lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). This group lies in the s-block of the periodic table of elements as all alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of group trends in properties in the periodic table, with elements exhibiting well-characterised homologous behaviour.
The alkali metals are all shiny, soft, highly reactive metals at standard temperature and pressure and readily lose their outermost electron to form cations with charge +1. They can all be cut easily with a knife due to their softness, exposing a shiny surface that tarnishes rapidly in air due to oxidation by atmospheric moisture and oxygen (and in the case of lithium, nitrogen). Because of their high reactivity, they must be stored under oil to prevent reaction with air, and are found naturally only in salts and never as the free elements. Caesium, the fifth alkali metal, is the most reactive of all the metals. In the modern IUPAC nomenclature, the alkali metals comprise the group 1 elements, excluding hydrogen (H), which is nominally a group 1 element but not normally considered to be an alkali metal as it rarely exhibits behaviour comparable to that of the alkali metals. All the alkali metals react with water, with the heavier alkali metals reacting more vigorously than the lighter ones.
All of the discovered alkali metals occur in nature as their compounds: in order of abundance, sodium is the most abundant, followed by potassium, lithium, rubidium, caesium, and finally francium, which is very rare due to its extremely high radioactivity; francium occurs only in the minutest traces in nature as an intermediate step in some obscure side branches of the natural decay chains. Experiments have been conducted to attempt the synthesis of ununennium (Uue), which is likely to be the next member of the group, but they have all met with failure. However, ununennium may not be an alkali metal due to relativistic effects, which are predicted to have a large influence on the chemical properties of superheavy elements; even if it does turn out to be an alkali metal, it is predicted to have some differences in physical and chemical properties from its lighter homologues.
Most alkali metals have many different applications. One of the best-known applications of the pure elements is the use of rubidium and caesium in atomic clocks, of which caesium atomic clocks are the most accurate and precise representation of time. A common application of the compounds of sodium is the sodium-vapour lamp, which emits light very efficiently. Table salt, or sodium chloride, has been used since antiquity. Lithium finds use as a psychiatric medication and as an anode in lithium batteries. Sodium and potassium are also essential elements, having major biological roles as electrolytes, and although the other alkali metals are not essential, they also have various effects on the body, both beneficial and harmful.Aluminium
Aluminium or aluminum is a chemical element with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic and ductile metal in the boron group. By mass, aluminium makes up about 8% of the Earth's crust; it is the third most abundant element after oxygen and silicon and the most abundant metal in the crust, though it is less common in the mantle below. The chief ore of aluminium is bauxite. Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is found combined in over 270 different minerals.Aluminium is remarkable for its low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the aerospace industry and important in transportation and building industries, such as building facades and window frames. The oxides and sulfates are the most useful compounds of aluminium.Despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts' abundance, the potential for a biological role for them is of continuing interest, and studies continue.Antimonide
Antimonides (sometimes called stibnides) are compounds of antimony with more electropositive elements. The antimonide ion is Sb3−.
Some antimonides are semiconductors, e.g. those of the boron group. Many antimonides are flammable or decomposed by oxygen when heated since the antimonide ion is a reducing agent.Boron
Boron is a chemical element with symbol B and atomic number 5. Produced entirely by cosmic ray spallation and supernovae and not by stellar nucleosynthesis, it is a low-abundance element in the Solar system and in the Earth's crust. Boron is concentrated on Earth by the water-solubility of its more common naturally occurring compounds, the borate minerals. These are mined industrially as evaporites, such as borax and kernite. The largest known boron deposits are in Turkey, the largest producer of boron minerals.
Elemental boron is a metalloid that is found in small amounts in meteoroids but chemically uncombined boron is not otherwise found naturally on Earth. Industrially, very pure boron is produced with difficulty because of refractory contamination by carbon or other elements. Several allotropes of boron exist: amorphous boron is a brown powder; crystalline boron is silvery to black, extremely hard (about 9.5 on the Mohs scale), and a poor electrical conductor at room temperature. The primary use of elemental boron is as boron filaments with applications similar to carbon fibers in some high-strength materials.
Boron is primarily used in chemical compounds. About half of all boron consumed globally is an additive in fiberglass for insulation and structural materials. The next leading use is in polymers and ceramics in high-strength, lightweight structural and refractory materials. Borosilicate glass is desired for its greater strength and thermal shock resistance than ordinary soda lime glass. Boron as sodium perborate is used as a bleach. A small amount of boron is used as a dopant in semiconductors, and reagent intermediates in the synthesis of organic fine chemicals. A few boron-containing organic pharmaceuticals are used or are in study. Natural boron is composed of two stable isotopes, one of which (boron-10) has a number of uses as a neutron-capturing agent.
In biology, borates have low toxicity in mammals (similar to table salt), but are more toxic to arthropods and are used as insecticides. Boric acid is mildly antimicrobial, and several natural boron-containing organic antibiotics are known. Boron is an essential plant nutrient and boron compounds such as borax and boric acid are used as fertilizers in agriculture, although it's only required in small amounts, with excess being toxic. Boron compounds play a strengthening role in the cell walls of all plants. There is no consensus on whether boron is an essential nutrient for mammals, including humans, although there is some evidence it supports bone health.Carbon group
The carbon group is a periodic table group consisting of carbon (C), silicon (Si), germanium (Ge), tin (Sn), lead (Pb), and flerovium (Fl).
In modern IUPAC notation, it is called Group 14. In the field of semiconductor physics, it is still universally called Group IV. The group was once also known as the tetrels (from the Greek word tetra, which means four), stemming from the Roman numeral IV in the group names, or (not coincidentally) from the fact that these elements have four valence electrons (see below).Gallium
Gallium is a chemical element with symbol Ga and atomic number 31. Gallium in its solid state is slightly blue; however in its liquid state it becomes silvery white. Gallium is soft enough to be cut with shears however; if too much force is applied Gallium may fracture conchoidally. It is in group 13 of the periodic table, and thus has similarities to the other metals of the group, aluminium, indium, and thallium. Gallium does not occur as a free element in nature, but as gallium(III) compounds in trace amounts in zinc ores and in bauxite. Elemental gallium is a liquid at temperatures greater than 29.76 °C (85.57 °F) (above room temperature, but below the normal human body temperature of 37 °C (99 °F), hence, the metal will melt in a person's hands).
The melting point of gallium is used as a temperature reference point. Gallium alloys are used in thermometers as a non-toxic and environmentally friendly alternative to mercury, and can withstand higher temperatures than mercury. The alloy galinstan (70% gallium, 21.5% indium, and 10% tin) has an even lower melting point of −19 °C (−2 °F), well below the freezing point of water.
Since its discovery in 1875, gallium has been used to make alloys with low melting points. It is also used in semiconductors as a dopant in semiconductor substrates.
Gallium is predominantly used in electronics. Gallium arsenide, the primary chemical compound of gallium in electronics, is used in microwave circuits, high-speed switching circuits, and infrared circuits. Semiconducting gallium nitride and indium gallium nitride produce blue and violet light-emitting diodes (LEDs) and diode lasers. Gallium is also used in the production of artificial gadolinium gallium garnet for jewelry. Gallium is considered a technology-critical element.
Gallium has no known natural role in biology. Gallium(III) behaves in a similar manner to ferric salts in biological systems and has been used in some medical applications, including pharmaceuticals and radiopharmaceuticals.Group (periodic table)
In chemistry, a group (also known as a family) is a column of elements in the periodic table of the chemical elements. There are 18 numbered groups in the periodic table, and the f-block columns (between groups 3 and 4) are not numbered. The elements in a group have similar physical or chemical characteristics of the outermost electron shells of their atoms (i.e., the same core charge), as most chemical properties are dominated by the orbital location of the outermost electron.
There are three systems of group numbering for the groups, that often assign the same number to different groups. The modern numbering "group 1" to "group 18" has been recommended by the International Union of Pure and Applied Chemistry (IUPAC) since about 1990. It replaces two older incompatible naming schemes, used by the Chemical Abstract Service (CAS, more popular in the U. S.), and by IUPAC before 1990 (more popular in Europe).
Groups may also be identified by their topmost element or have a specific name. For example, group 16 is variously described as the "oxygen group" and as the "chalcogens". However, iron group usually does not mean "group 8". In chemistry it may mean either iron, cobalt, and nickel, or some other set of elements with similar chemical properties. In astrophysics and nuclear physics, it usually means those three plus chromium and manganese.Hydroboration–oxidation reaction
In organic chemistry, the hydroboration–oxidation reaction is a two-step hydration reaction that converts an alkene into an alcohol. The process results in the syn addition of a hydrogen and a hydroxyl group where the double bond had been. Hydroboration–oxidation is an anti-Markovnikov reaction, with the hydroxyl group attaching to the less-substituted carbon. The reaction thus provides a more stereospecific and complementary regiochemical alternative to other hydration reactions such as acid-catalyzed addition and the oxymercuration–reduction process. The reaction was first reported by Herbert C. Brown in the late 1950s and it was recognized in his receiving the Nobel Prize in Chemistry in 1979.
The general form of the reaction is as follows:
Tetrahydrofuran (THF) is the archetypal solvent used for hydroborations.Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. A hydroxide attached to a strongly electropositive center may itself ionize, liberating a hydrogen cation (H+), making the parent compound an acid.
The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently-bound group –OH of atoms is the hydroxy group.
Hydroxide ion and hydroxy group are nucleophiles and can act as a catalysts in organic chemistry.
Many inorganic substances which bear the word "hydroxide" in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups.Nihonium
Nihonium is a synthetic chemical element with the symbol Nh and atomic number 113. It is extremely radioactive; its most stable known isotope, nihonium-286, has a half-life of about 10 seconds. In the periodic table, nihonium is a transactinide element in the p-block. It is a member of period 7 and group 13 (boron group).
Nihonium was first reported to have been created in 2003 by a Russian–American collaboration at the Joint Institute for Nuclear Research (JINR) in Dubna, Russia, and in 2004 by a team of Japanese scientists at Riken in Wakō, Japan. The confirmation of their claims in the ensuing years involved independent teams of scientists working in the United States, Germany, Sweden, and China, as well as the original claimants in Russia and Japan. In 2015, the IUPAC/IUPAP Joint Working Party recognised the element and assigned the priority of the discovery and naming rights for the element to Riken, as it judged that they had demonstrated that they had observed element 113 before the JINR team did so. The Riken team suggested the name nihonium in 2016, which was approved in the same year. The name comes from the common Japanese name for Japan (日本, nihon).
Very little is known about nihonium, as it has only been made in very small amounts that decay away within seconds. The anomalously long lives of some superheavy nuclides, including some nihonium isotopes, are explained by the "island of stability" theory. Experiments support the theory, with the half-lives of the confirmed nihonium isotopes increasing from milliseconds to seconds as neutrons are added and the island is approached. Nihonium has been calculated to have similar properties to its homologues boron, aluminium, gallium, indium, and thallium. All but boron are post-transition metals, and nihonium is expected to be a post-transition metal as well. It should also show several major differences from them; for example, nihonium should be more stable in the +1 oxidation state than the +3 state, like thallium, but in the +1 state nihonium should behave more like silver and astatine than thallium. Preliminary experiments in 2017 showed that elemental nihonium is not very volatile; its chemistry remains largely unexplored.Nowotny phase
In inorganic chemistry, a Nowotny chimney ladder phase (NCL phase) is a particular intermetallic crystal structure found with certain binary compounds. NLC phases are generally tetragonal and are composed of two separate sublattices. The first is a tetragonal array of transition metal atoms, generally from group 4 through group 9 of the periodic table. Contained within this array of transition metal atoms is a second network of main group atoms, typically from group 13 (boron group) or group 14 (carbon group). The transition metal atoms form a chimney with helical zigzag chain. The main-group elements form a ladder spiraling inside the transition metal helix.
The phase is named after one of the early investigators H. Nowotny. Examples are RuGa2, Mn4Si7, Ru2Ge3, Ir3Ga5, Ir4Ge5 V17Ge31, Cr11Ge19, Mn11Si19, Mn15Si26, Mo9Ge16, Mo13Ge23, Rh10Ga17, and Rh17Ge22.In RuGa2 the ruthenium atoms in the chimney are separated by 329 pm. The gallium atoms spiral around the Ru chimney with a Ga–Ga intrahelix distance of 257 pm. The view perpendicular to the chimney axis is that of a hexagonal lattice with gallium atoms occupying the vertices and ruthenium atoms occupying the center. Each gallium atom bonds to 5 other gallium atoms forming a distorted trigonal bipyramid. The gallium atoms carry a positive charge and the ruthenium atoms have a formal charge of −2 (filled 4d shell).In Ru2Sn3 the ruthenium atoms spiral around the tin inner helix. In two dimension the Ru atoms form a tetragonal lattice with the tin atoms appearing as triangular units in the Ru channels.The occurrence of a LCP phase can be predicted by the so-called 14 electron rule. In it the total number of valence electrons per transition metal atom is 14.Onium ion
In chemistry, an onium ion is a cation formally obtained by the protonation of mononuclear parent hydride of a pnictogen (group 15 of the periodic table), chalcogen (group 16), or halogen (group 17). The oldest-known onium ion, and the namesake for the class, is ammonium, NH+4, the protonated derivative of ammonia, NH3.The name onium is also used for cations that would result from the substitution of hydrogen atoms in those ions by other groups, such as organic radicals, or halogens; such as tetraphenylphosphonium, (C6H5)4P+. The substituent groups may be divalent or trivalent, yielding ions such as iminium and nitrilium.A simple onium ion has a charge of +1. A larger ion that has two onium ion subgroups is called a double onium ion, and has a charge of +2. A triple onium ion has a charge of +3, and so on.
Compounds of an onium cation and some other negative ion are known as onium compounds or onium salts.
Onium ions and onium compounds are inversely analogous to -ate ions and ate complexes:
Lewis bases form onium ions when the central atom gains one more bond and becomes a positive cation.
Lewis acids form -ate ions when the central atom gains one more bond and becomes a negative anion.Organoboron chemistry
Organoborane or organoboron compounds are chemical compounds of boron and carbon that are organic derivatives of BH3, for example trialkyl boranes. Organoboron chemistry or organoborane chemistry is the chemistry of these compounds. Organoboron compounds are important reagents in organic chemistry enabling many chemical transformations, the most important one called hydroboration.Period 3 element
A period 3 element is one of the chemical elements in the third row (or period) of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when the periodic table skips a row and a chemical behaviour begins to repeat, meaning that elements with similar behavior fall into the same vertical columns. The third period contains eight elements: sodium, magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon. The first two, sodium and magnesium, are members of the s-block of the periodic table, while the others are members of the p-block. Note that there is a 3d subshell, but it is not filled until period 4, such giving the period table its characteristic shape of "two rows at a time". All of the period 3 elements occur in nature and have at least one stable isotope.Periodic table (detailed cells)
The periodic table is a tabular method of displaying the chemical elements. It can show much information, after name, symbol and atomic number. Also, for each element mean atomic mass value for the natural isotopic composition of each element can be noted.
The two layout forms originate from two graphic forms of presentation of the same periodic table. Historically, when the f-block was identified it was drawn below the existing table, with markings for its in-table location (this page uses dots or asterisks). Also, a common presentation is to put all 15 lanthanide and actinide columns below, while the f-block only has 14 columns. One lanthanide and actinide each are d-block elements, belonging to group 3 with scandium and yttrium, though whether these are the first of each series (lanthanum and actinium) or the last (lutetium and lawrencium) has been disputed. The tables below show lanthanum and actinium as group 3 elements, as this is the more common form in the literature.
Although precursors to this table exist, its invention is generally credited to Russian chemist Dmitri Mendeleev in 1869. Mendeleev invented the table to illustrate recurring ("periodic") trends in the properties of the elements. The layout of the table has been refined and extended over time, as new elements have been discovered, and new theoretical models have been developed to explain chemical behavior.Pnictogen
A pnictogen is one of the chemical elements in group 15 of the periodic table. This group is also known as the nitrogen family. It consists of the elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), and perhaps the chemically uncharacterized synthetic element moscovium (Mc).
In modern IUPAC notation, it is called Group 15. In CAS and the old IUPAC systems it was called Group VA and Group VB respectively (pronounced "group five A" and "group five B", "V" for the Roman numeral 5). In the field of semiconductor physics, it is still usually called Group V. The "five" ("V") in the historical names comes from the "pentavalency" of nitrogen, reflected by the stoichiometry of compounds such as N2O5. They have also been called the pentels.
The term pnictogen (or pnigogen) is derived from the Ancient Greek word πνίγειν (pnígein) meaning "to choke", referring to the choking or stifling property of nitrogen gas.Thallium
Thallium is a chemical element with symbol Tl and atomic number 81. It is a gray post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Chemists William Crookes and Claude-Auguste Lamy discovered thallium independently in 1861, in residues of sulfuric acid production. Both used the newly developed method of flame spectroscopy, in which thallium produces a notable green spectral line. Thallium, from Greek θαλλός, thallós, meaning "a green shoot or twig", was named by Crookes. It was isolated by both Lamy and Crookes in 1862; Lamy by electrolysis, and Crookes by precipitation and melting of the resultant powder. Crookes exhibited it as a powder precipitated by zinc at the International exhibition, which opened on 1 May that year.Thallium tends to oxidize to the +3 and +1 oxidation states as ionic salts. The +3 state resembles that of the other elements in group 13 (boron, aluminium, gallium, indium). However, the +1 state, which is far more prominent in thallium than the elements above it, recalls the chemistry of alkali metals, and thallium(I) ions are found geologically mostly in potassium-based ores, and (when ingested) are handled in many ways like potassium ions (K+) by ion pumps in living cells.
Commercially, thallium is produced not from potassium ores, but as a byproduct from refining of heavy-metal sulfide ores. Approximately 60–70% of thallium production is used in the electronics industry, and the remainder is used in the pharmaceutical industry and in glass manufacturing. It is also used in infrared detectors. The radioisotope thallium-201 (as the soluble chloride TlCl) is used in small, nontoxic amounts as an agent in a nuclear medicine scan, during one type of nuclear cardiac stress test.
Soluble thallium salts (many of which are nearly tasteless) are toxic, and they were historically used in rat poisons and insecticides. Use of these compounds has been restricted or banned in many countries, because of their nonselective toxicity. Thallium poisoning usually results in hair loss, although this characteristic symptom does not always surface. Because of its historic popularity as a murder weapon, thallium has gained notoriety as "the poisoner's poison" and "inheritance powder" (alongside arsenic).Valence electron
In chemistry, a valence electron is an outer shell electron that is associated with an atom, and that can participate in the formation of a chemical bond if the outer shell is not closed; in a single covalent bond, both atoms in the bond contribute one valence electron in order to form a shared pair. The presence of valence electrons can determine the element's chemical properties, such as its valence—whether it may bond with other elements and, if so, how readily and with how many. For a main group element, a valence electron can exist only in the outermost electron shell; in a transition metal, a valence electron can also be in an inner shell.
An atom with a closed shell of valence electrons (corresponding to an electron configuration s2p6) tends to be chemically inert. Atoms with one or two more valence electrons than are needed for a "closed" shell are highly reactive due to the following reasons:
1) It requires relatively low energy (compared to the lattice enthalpy) to remove the extra valence electrons to form a positive ion.
2) Because of their tendency either to gain the missing valence electrons (thereby forming a negative ion), or to share valence electrons (thereby forming a covalent bond).
Similar to an electron in an inner shell, a valence electron has the ability to absorb or release energy in the form of a photon. An energy gain can trigger an electron to move (jump) to an outer shell; this is known as atomic excitation. Or the electron can even break free from its associated atom's valence shell; this is ionization to form a positive ion. When an electron loses energy (thereby causing a photon to be emitted), then it can move to an inner shell which is not fully occupied.
Valence energy levels correspond to the principal quantum numbers (n = 1, 2, 3, 4, 5 ...) or are labeled alphabetically with letters used in the X-ray notation (K, L, M, …).
|Some common chemical compounds of the boron group|
|Aluminium||(γ/δ/η/θ/χ)Al2O3||(α/α`/β/δ/ε/θ/γ) AlH3||AlF3||AlCl3||(α/β/γ) Al2S3|
|Periodic table forms|
|Sets of elements|
Boron group elements