Actinium

Actinium is a chemical element with symbol Ac and atomic number 89. It was first isolated by French chemist André-Louis Debierne in 1899. Friedrich Oskar Giesel later independently isolated it in 1902 and, unaware that it was already known, gave it the name emanium.[3] Actinium gave the name to the actinide series, a group of 15 similar elements between actinium and lawrencium in the periodic table. It is also sometimes considered the first of the 7th-period transition metals, although lawrencium is less commonly given that position. Together with polonium, radium, and radon, actinium was one of the first non-primordial radioactive elements to be isolated.

A soft, silvery-white radioactive metal, actinium reacts rapidly with oxygen and moisture in air forming a white coating of actinium oxide that prevents further oxidation. As with most lanthanides and many actinides, actinium assumes oxidation state +3 in nearly all its chemical compounds. Actinium is found only in traces in uranium and thorium ores as the isotope 227Ac, which decays with a half-life of 21.772 years, predominantly emitting beta and sometimes alpha particles, and 228Ac, which is beta active with a half-life of 6.15 hours. One tonne of natural uranium in ore contains about 0.2 milligrams of actinium-227, and one tonne of thorium contains about 5 nanograms of actinium-228. The close similarity of physical and chemical properties of actinium and lanthanum makes separation of actinium from the ore impractical. Instead, the element is prepared, in milligram amounts, by the neutron irradiation of 226Ra in a nuclear reactor. Owing to its scarcity, high price and radioactivity, actinium has no significant industrial use. Its current applications include a neutron source and an agent for radiation therapy targeting cancer cells in the body and killing them.

Actinium,  89Ac
Actinium
Actinium
Pronunciation/ækˈtɪniəm/ (ak-TIN-ee-əm)
Appearancesilvery-white, glowing with an eerie blue light;[1] sometimes with a golden cast[2]
Mass number227 (most stable isotope)
Actinium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
La

Ac

(Ubu)
radiumactiniumthorium
Atomic number (Z)89
Groupgroup 3
Periodperiod 7
Blockd-block
Element category  actinide, sometimes considered a transition metal
Electron configuration[Rn] 6d1 7s2
Electrons per shell
2, 8, 18, 32, 18, 9, 2
Physical properties
Phase at STPsolid
Melting point1500 K ​(1227 °C, ​2240 °F) (estimated)[2]
Boiling point3500±300 K ​(3200±300 °C, ​5800±500 °F) (extrapolated)[2]
Density (near r.t.)10 g/cm3
Heat of fusion14 kJ/mol
Heat of vaporization400 kJ/mol
Molar heat capacity27.2 J/(mol·K)
Atomic properties
Oxidation states+2, +3 (a strongly basic oxide)
ElectronegativityPauling scale: 1.1
Ionization energies
  • 1st: 499 kJ/mol
  • 2nd: 1170 kJ/mol
  • 3rd: 1900 kJ/mol
  • (more)
Covalent radius215 pm
Color lines in a spectral range
Spectral lines of actinium
Other properties
Natural occurrencefrom decay
Crystal structureface-centered cubic (fcc)
Face-centered cubic crystal structure for actinium
Thermal conductivity12 W/(m·K)
CAS Number7440-34-8
History
Discovery and first isolationFriedrich Oskar Giesel (1902)
Named byAndré-Louis Debierne (1899)
Main isotopes of actinium
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
225Ac trace 10 d α 221Fr
226Ac syn 29.37 h β 226Th
ε 226Ra
α 222Fr
227Ac trace 21.772 y β 227Th
α 223Fr

History

André-Louis Debierne, a French chemist, announced the discovery of a new element in 1899. He separated it from pitchblende residues left by Marie and Pierre Curie after they had extracted radium. In 1899, Debierne described the substance as similar to titanium[4] and (in 1900) as similar to thorium.[5] Friedrich Oskar Giesel independently discovered actinium in 1902[6] as a substance being similar to lanthanum and called it "emanium" in 1904.[7] After a comparison of the substances half-lives determined by Debierne,[8] Harriet Brooks in 1904, and Otto Hahn and Otto Sackur in 1905, Debierne's chosen name for the new element was retained because it had seniority, despite the contradicting chemical properties he claimed for the element at different times.[9][10]

Articles published in the 1970s[11] and later[12] suggest that Debierne's results published in 1904 conflict with those reported in 1899 and 1900. Furthermore, the now-known chemistry of actinium precludes its presence as anything other than a minor constituent of Debierne's 1899 and 1900 results; in fact, the chemical properties he reported make it likely that he had, instead, accidentally identified protactinium, which would not be discovered for another fourteen years, only to have it disappear due to its hydrolysis and adsorption onto his laboratory equipment. This has led some authors to advocate that Giesel alone should be credited with the discovery.[2] A less confrontational vision of scientific discovery is proposed by Adloff.[12] He suggests that hindsight criticism of the early publications should be mitigated by the then nascent state of radiochemistry: highlighting the prudence of Debierne's claims in the original papers, he notes that nobody can contend that Debierne's substance did not contain actinium.[12] Debierne, who is now considered by the vast majority of historians as the discoverer, lost interest in the element and left the topic. Giesel, on the other hand, can rightfully be credited with the first preparation of radiochemically pure actinium and with the identification of its atomic number 89.[11]

The name actinium originates from the Ancient Greek aktis, aktinos (ακτίς, ακτίνος), meaning beam or ray.[13] Its symbol Ac is also used in abbreviations of other compounds that have nothing to do with actinium, such as acetyl, acetate[14] and sometimes acetaldehyde.[15]

Properties

Actinium is a soft, silvery-white,[16][17] radioactive, metallic element. Its estimated shear modulus is similar to that of lead.[18] Owing to its strong radioactivity, actinium glows in the dark with a pale blue light, which originates from the surrounding air ionized by the emitted energetic particles.[19] Actinium has similar chemical properties to lanthanum and other lanthanides, and therefore these elements are difficult to separate when extracting from uranium ores. Solvent extraction and ion chromatography are commonly used for the separation.[20]

The first element of the actinides, actinium gave the group its name, much as lanthanum had done for the lanthanides. The group of elements is more diverse than the lanthanides and therefore it was not until 1928 that Charles Janet proposed the most significant change to Dmitri Mendeleev's periodic table since the recognition of the lanthanides, by introducing the actinides, a move suggested again in 1945 by Glenn T. Seaborg.[21]

Actinium reacts rapidly with oxygen and moisture in air forming a white coating of actinium oxide that impedes further oxidation.[16] As with most lanthanides and actinides, actinium exists in the oxidation state +3, and the Ac3+ ions are colorless in solutions.[22] The oxidation state +3 originates from the [Rn]6d17s2 electronic configuration of actinium, with three valence electrons that are easily donated to give the stable closed-shell structure of the noble gas radon.[17] The rare oxidation state +2 is only known for actinium dihydride (AcH2); even this may in reality be an electride compound like its lighter congener LaH2 and thus have actinium(III).[23] Ac3+ is the largest of all known tripositive ions and its first coordination sphere contains approximately 10.9 ± 0.5 water molecules.[24]

Chemical compounds

Only a limited number of actinium compounds are known including AcF3, AcCl3, AcBr3, AcOF, AcOCl, AcOBr, Ac2S3, Ac2O3 and AcPO4, due to actinium's intense radioactivity. Except for AcPO4, they are all similar to the corresponding lanthanum compounds. They all contain actinium in the oxidation state +3.[22][25] In particular, the lattice constants of the analogous lanthanum and actinium compounds differ by only a few percent.[25]

Formula color symmetry space group No Pearson symbol a (pm) b (pm) c (pm) Z density,
g/cm3
Ac silvery fcc[23] Fm3m 225 cF4 531.1 531.1 531.1 4 10.07
AcH2 unknown cubic[23] Fm3m 225 cF12 567 567 567 4 8.35
Ac2O3 white[16] trigonal[26] P3m1 164 hP5 408 408 630 1 9.18
Ac2S3 black cubic[27] I43d 220 cI28 778.56 778.56 778.56 4 6.71
AcF3 white[28] hexagonal[25][26] P3c1 165 hP24 741 741 755 6 7.88
AcCl3 white hexagonal[25][29] P63/m 165 hP8 764 764 456 2 4.8
AcBr3 white[25] hexagonal[29] P63/m 165 hP8 764 764 456 2 5.85
AcOF white[30] cubic[25] Fm3m 593.1 8.28
AcOCl white tetragonal[25] 424 424 707 7.23
AcOBr white tetragonal[25] 427 427 740 7.89
AcPO4·0.5H2O unknown hexagonal[25] 721 721 664 5.48

Here a, b and c are lattice constants, No is space group number and Z is the number of formula units per unit cell. Density was not measured directly but calculated from the lattice parameters.

Oxides

Actinium oxide (Ac2O3) can be obtained by heating the hydroxide at 500 °C or the oxalate at 1100 °C, in vacuum. Its crystal lattice is isotypic with the oxides of most trivalent rare-earth metals.[25]

Halides

Actinium trifluoride can be produced either in solution or in solid reaction. The former reaction is carried out at room temperature, by adding hydrofluoric acid to a solution containing actinium ions. In the latter method, actinium metal is treated with hydrogen fluoride vapors at 700 °C in an all-platinum setup. Treating actinium trifluoride with ammonium hydroxide at 900–1000 °C yields oxyfluoride AcOF. Whereas lanthanum oxyfluoride can be easily obtained by burning lanthanum trifluoride in air at 800 °C for an hour, similar treatment of actinium trifluoride yields no AcOF and only results in melting of the initial product.[25][30]

AcF3 + 2 NH3 + H2O → AcOF + 2 NH4F

Actinium trichloride is obtained by reacting actinium hydroxide or oxalate with carbon tetrachloride vapors at temperatures above 960 °C. Similar to oxyfluoride, actinium oxychloride can be prepared by hydrolyzing actinium trichloride with ammonium hydroxide at 1000 °C. However, in contrast to the oxyfluoride, the oxychloride could well be synthesized by igniting a solution of actinium trichloride in hydrochloric acid with ammonia.[25]

Reaction of aluminium bromide and actinium oxide yields actinium tribromide:

Ac2O3 + 2 AlBr3 → 2 AcBr3 + Al2O3

and treating it with ammonium hydroxide at 500 °C results in the oxybromide AcOBr.[25]

Other compounds

Actinium hydride was obtained by reduction of actinium trichloride with potassium at 300 °C, and its structure was deduced by analogy with the corresponding LaH2 hydride. The source of hydrogen in the reaction was uncertain.[31]

Mixing monosodium phosphate (NaH2PO4) with a solution of actinium in hydrochloric acid yields white-colored actinium phosphate hemihydrate (AcPO4·0.5H2O), and heating actinium oxalate with hydrogen sulfide vapors at 1400 °C for a few minutes results in a black actinium sulfide Ac2S3. It may possibly be produced by acting with a mixture of hydrogen sulfide and carbon disulfide on actinium oxide at 1000 °C.[25]

Isotopes

Naturally occurring actinium is composed of two radioactive isotopes; 227
Ac
(from the radioactive family of 235
U
) and 228
Ac
(a granddaughter of 232
Th
). 227
Ac
decays mainly as a beta emitter with a very small energy, but in 1.38% of cases it emits an alpha particle, so it can readily be identified through alpha spectrometry.[2] Thirty-six radioisotopes have been identified, the most stable being 227
Ac
with a half-life of 21.772 years, 225
Ac
with a half-life of 10.0 days and 226
Ac
with a half-life of 29.37 hours. All remaining radioactive isotopes have half-lives that are less than 10 hours and the majority of them have half-lives shorter than one minute. The shortest-lived known isotope of actinium is 217
Ac
(half-life of 69 nanoseconds) which decays through alpha decay and electron capture. Actinium also has two known meta states.[32] The most significant isotopes for chemistry are 225Ac, 227Ac, and 228Ac.[2]

Purified 227
Ac
comes into equilibrium with its decay products after about a half of year. It decays according to its 21.772-year half-life emitting mostly beta (98.62%) and some alpha particles (1.38%);[32] the successive decay products are part of the actinium series. Owing to the low available amounts, low energy of its beta particles (maximum 44.8 keV) and low intensity of alpha radiation, 227
Ac
is difficult to detect directly by its emission and it is therefore traced via its decay products.[22] The isotopes of actinium range in atomic weight from 206 u (206
Ac
) to 236 u (236
Ac
).[32]

Isotope Production Decay Half-life
221Ac 232Th(d,9n)→225Pa(α)→221Ac α 52 ms
222Ac 232Th(d,8n)→226Pa(α)→222Ac α 5.0 s
223Ac 232Th(d,7n)→227Pa(α)→223Ac α 2.1 min
224Ac 232Th(d,6n)→228Pa(α)→224Ac α 2.78 hours
225Ac 232Th(n,γ)→233Th(β)→233Pa(β)→233U(α)→229Th(α)→225Ra(β)→225Ac α 10 days
226Ac 226Ra(d,2n)→226Ac α, β
electron capture
29.37 hours
227Ac 235U(α)→231Th(β)→231Pa(α)→227Ac α, β 21.77 years
228Ac 232Th(α)→228Ra(β)→228Ac β 6.15 hours
229Ac 228Ra(n,γ)→229Ra(β)→229Ac β 62.7 min
230Ac 232Th(d,α)→230Ac β 122 s
231Ac 232Th(γ,p)→231Ac β 7.5 min
232Ac 232Th(n,p)→232Ac β 119 s

Occurrence and synthesis

Uraninite-39029
Uraninite ores have elevated concentrations of actinium.

Actinium is found only in traces in uranium ores – one tonne of uranium in ore contains about 0.2 milligrams of 227Ac[33][34] – and in thorium ores, which contain about 5 nanograms of 228Ac per one tonne of thorium. The actinium isotope 227Ac is a transient member of the uranium-actinium series decay chain, which begins with the parent isotope 235U (or 239Pu) and ends with the stable lead isotope 207Pb. The isotope 228Ac is a transient member of the thorium series decay chain, which begins with the parent isotope 232Th and ends with the stable lead isotope 208Pb. Another actinium isotope (225Ac) is transiently present in the neptunium series decay chain, beginning with 237Np (or 233U) and ending with thallium (205Tl) and near-stable bismuth (209Bi); even though all primordial 237Np has decayed away, it is continuously produced by neutron knock-out reactions on natural 238U.

The low natural concentration, and the close similarity of physical and chemical properties to those of lanthanum and other lanthanides, which are always abundant in actinium-bearing ores, render separation of actinium from the ore impractical, and complete separation was never achieved.[25] Instead, actinium is prepared, in milligram amounts, by the neutron irradiation of 226Ra in a nuclear reactor.[34][35]

The reaction yield is about 2% of the radium weight. 227Ac can further capture neutrons resulting in small amounts of 228Ac. After the synthesis, actinium is separated from radium and from the products of decay and nuclear fusion, such as thorium, polonium, lead and bismuth. The extraction can be performed with thenoyltrifluoroacetone-benzene solution from an aqueous solution of the radiation products, and the selectivity to a certain element is achieved by adjusting the pH (to about 6.0 for actinium).[33] An alternative procedure is anion exchange with an appropriate resin in nitric acid, which can result in a separation factor of 1,000,000 for radium and actinium vs. thorium in a two-stage process. Actinium can then be separated from radium, with a ratio of about 100, using a low cross-linking cation exchange resin and nitric acid as eluant.[36]

225Ac was first produced artificially at the Institute for Transuranium Elements (ITU) in Germany using a cyclotron and at St George Hospital in Sydney using a linac in 2000.[37] This rare isotope has potential applications in radiation therapy and is most efficiently produced by bombarding a radium-226 target with 20–30 MeV deuterium ions. This reaction also yields 226Ac which however decays with a half-life of 29 hours and thus does not contaminate 225Ac.[38]

Actinium metal has been prepared by the reduction of actinium fluoride with lithium vapor in vacuum at a temperature between 1100 and 1300 °C. Higher temperatures resulted in evaporation of the product and lower ones lead to an incomplete transformation. Lithium was chosen among other alkali metals because its fluoride is most volatile.[13][16]

Applications

Owing to its scarcity, high price and radioactivity, 227Ac currently has no significant industrial use, but 225Ac is currently being studied for use in cancer treatments such as targeted alpha therapies.[13][39] 227Ac is highly radioactive and was therefore studied for use as an active element of radioisotope thermoelectric generators, for example in spacecraft. The oxide of 227Ac pressed with beryllium is also an efficient neutron source with the activity exceeding that of the standard americium-beryllium and radium-beryllium pairs.[40] In all those applications, 227Ac (a beta source) is merely a progenitor which generates alpha-emitting isotopes upon its decay. Beryllium captures alpha particles and emits neutrons owing to its large cross-section for the (α,n) nuclear reaction:

The 227AcBe neutron sources can be applied in a neutron probe – a standard device for measuring the quantity of water present in soil, as well as moisture/density for quality control in highway construction.[41][42] Such probes are also used in well logging applications, in neutron radiography, tomography and other radiochemical investigations.[43]

DOTA polyaminocarboxylic acid
Chemical structure of the DOTA carrier for 225Ac in radiation therapy.

225Ac is applied in medicine to produce 213Bi in a reusable generator[36] or can be used alone as an agent for radiation therapy, in particular targeted alpha therapy (TAT). This isotope has a half-life of 10 days, making it much more suitable for radiation therapy than 213Bi (half-life 46 minutes).[39] Additionally, 225Ac decays to nontoxic 209Bi rather than stable but toxic lead, which is the final product in the decay chains of several other candidate isotopes, namely 227Th, 228Th, and 230U.[39] Not only 225Ac itself, but also its daughters, emit alpha particles which kill cancer cells in the body. The major difficulty with application of 225Ac was that intravenous injection of simple actinium complexes resulted in their accumulation in the bones and liver for a period of tens of years. As a result, after the cancer cells were quickly killed by alpha particles from 225Ac, the radiation from the actinium and its daughters might induce new mutations. To solve this problem, 225Ac was bound to a chelating agent, such as citrate, ethylenediaminetetraacetic acid (EDTA) or diethylene triamine pentaacetic acid (DTPA). This reduced actinium accumulation in the bones, but the excretion from the body remained slow. Much better results were obtained with such chelating agents as HEHA (1,4,7,10,13,16-hexaazacyclohexadecane-N,N′,N″,N‴,N‴′,N‴″-hexaacetic acid)[44] or DOTA (1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid) coupled to trastuzumab, a monoclonal antibody that interferes with the HER2/neu receptor. The latter delivery combination was tested on mice and proved to be effective against leukemia, lymphoma, breast, ovarian, neuroblastoma and prostate cancers.[45][46][47]

The medium half-life of 227Ac (21.77 years) makes it very convenient radioactive isotope in modeling the slow vertical mixing of oceanic waters. The associated processes cannot be studied with the required accuracy by direct measurements of current velocities (of the order 50 meters per year). However, evaluation of the concentration depth-profiles for different isotopes allows estimating the mixing rates. The physics behind this method is as follows: oceanic waters contain homogeneously dispersed 235U. Its decay product, 231Pa, gradually precipitates to the bottom, so that its concentration first increases with depth and then stays nearly constant. 231Pa decays to 227Ac; however, the concentration of the latter isotope does not follow the 231Pa depth profile, but instead increases toward the sea bottom. This occurs because of the mixing processes which raise some additional 227Ac from the sea bottom. Thus analysis of both 231Pa and 227Ac depth profiles allows researchers to model the mixing behavior.[48][49]

There are theoretical predictions that AcHx hydrides (in this case with very high pressure) are a candidate for a near room-temperature superconductor as they have Tc significantly higher than H3S, possibly near 250 K.[50]

Precautions

227Ac is highly radioactive and experiments with it are carried out in a specially designed laboratory equipped with a tight glove box. When actinium trichloride is administered intravenously to rats, about 33% of actinium is deposited into the bones and 50% into the liver. Its toxicity is comparable to, but slightly lower than that of americium and plutonium.[51] For trace quantities, fume hoods with good aeration suffice; for gram amounts, hot cells with shielding from the intense gamma radiation emitted by 227Ac are necessary.[52]

See also

References

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Bibliography

External links

89

89 may refer to:

89 (number)

Atomic number 89: actinium

Actinide

The actinide or actinoid (IUPAC nomenclature) series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium.Strictly speaking, both actinium and lawrencium have been labeled as group 3 elements, but both elements are often included in any general discussion of the chemistry of the actinide elements. Actinium is the more often omitted of the two, because its placement as a group 3 element is somewhat more common in texts and for semantic reasons: since "actinide" means "like actinium", it has been argued that actinium cannot logically be an actinide, even though IUPAC acknowledges its inclusion based on common usage.The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide. All but one of the actinides are f-block elements, with the exception being either actinium or lawrencium. The series mostly corresponds to the filling of the 5f electron shell, although actinium and thorium lack any f-electrons, and curium and lawrencium have the same number as the preceding element. In comparison with the lanthanides, also mostly f-block elements, the actinides show much more variable valence. They all have very large atomic and ionic radii and exhibit an unusually large range of physical properties. While actinium and the late actinides (from americium onwards) behave similarly to the lanthanides, the elements thorium, protactinium, and uranium are much more similar to transition metals in their chemistry, with neptunium and plutonium occupying an intermediate position.

All actinides are radioactive and release energy upon radioactive decay; naturally occurring uranium and thorium, and synthetically produced plutonium are the most abundant actinides on Earth. These are used in nuclear reactors and nuclear weapons. Uranium and thorium also have diverse current or historical uses, and americium is used in the ionization chambers of most modern smoke detectors.

Of the actinides, primordial thorium and uranium occur naturally in substantial quantities. The radioactive decay of uranium produces transient amounts of actinium and protactinium, and atoms of neptunium and plutonium are occasionally produced from transmutation reactions in uranium ores. The other actinides are purely synthetic elements. Nuclear weapons tests have released at least six actinides heavier than plutonium into the environment; analysis of debris from a 1952 hydrogen bomb explosion showed the presence of americium, curium, berkelium, californium, einsteinium and fermium.In presentations of the periodic table, the lanthanides and the actinides are customarily shown as two additional rows below the main body of the table, with placeholders or else a selected single element of each series (either lanthanum or lutetium, and either actinium or lawrencium, respectively) shown in a single cell of the main table, between barium and hafnium, and radium and rutherfordium, respectively. This convention is entirely a matter of aesthetics and formatting practicality; a rarely used wide-formatted periodic table inserts the lanthanide and actinide series in their proper places, as parts of the table's sixth and seventh rows (periods).

Actinide chemistry

Actinide chemistry (or actinoid chemistry) is one of the main branches of nuclear chemistry that investigates the processes and molecular systems of the actinides. The actinides derive their name from the group 3 element actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide. All but one of the actinides are f-block elements, corresponding to the filling of the 5f electron shell; lawrencium, a d-block element, is also generally considered an actinide. In comparison with the lanthanides, also mostly f-block elements, the actinides show much more variable valence. The actinide series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium.

Actinium(III) chloride

Actinium(III) chloride is a chemical compound containing the rare radioactive element actinium. It has the formula AcCl3. Molecular weight of the compound is 333.378 g/m ol.

Actinium fluoride

Actinium fluoride (AcF3) is an inorganic compound of actinium and fluorine.

André-Louis Debierne

André-Louis Debierne (French pronunciation: ​[ɑ̃dʁe lwi dəbjɛʁn]; 14 July 1874 – 31 August 1949) was a French chemist and is considered the discoverer of the element actinium.

Debierne studied at the elite École supérieure de physique et de chimie industrielles de la ville de Paris (ESPCI ParisTech). He was a student of Charles Friedel, was a close friend of Pierre and Marie Curie and was associated with their work. In 1899, he discovered the radioactive element actinium, as a result of continuing the work with pitchblende that the Curies had initiated.

After the death of Pierre Curie in 1906, Debierne helped Marie Curie carry on and worked with her in teaching and research.

In 1910, he and Marie Curie prepared radium in metallic form in visible amounts. They did not keep it metallic, however. Having demonstrated the metal's existence as a matter of scientific curiosity, they reconverted it into compounds with which they might continue their researches.

Decay chain

In nuclear science, the decay chain refers to a series of radioactive decays of different radioactive decay products as a sequential series of transformations. It is also known as a "radioactive cascade". Most radioisotopes do not decay directly to a stable state, but rather undergo a series of decays until eventually a stable isotope is reached.

Decay stages are referred to by their relationship to previous or subsequent stages. A parent isotope is one that undergoes decay to form a daughter isotope. One example of this is uranium (atomic number 92) decaying into thorium (atomic number 90). The daughter isotope may be stable or it may decay to form a daughter isotope of its own. The daughter of a daughter isotope is sometimes called a granddaughter isotope.

The time it takes for a single parent atom to decay to an atom of its daughter isotope can vary widely, not only between different parent-daughter pairs, but also randomly between identical pairings of parent and daughter isotopes. The decay of each single atom occurs spontaneously, and the decay of an initial population of identical atoms over time t, follows a decaying exponential distribution, e−λt, where λ is called a decay constant. One of the properties of an isotope is its half-life, the time by which half of an initial number of identical parent radioisotopes have decayed to their daughters, which is inversely related to λ. Half-lives have been determined in laboratories for many radioisotopes (or radionuclides). These can range from nearly instantaneous to as much as 1019 years or more.

The intermediate stages each emit the same amount of radioactivity as the original radioisotope (i.e. there is a one-to-one relationship between the numbers of decays in successive stages) but each stage releases a different quantity of energy. If and when equilibrium is achieved, each successive daughter isotope is present in direct proportion to its half-life; but since its activity is inversely proportional to its half-life, each nuclide in the decay chain finally contributes as many individual transformations as the head of the chain, though not the same energy. For example, uranium-238 is weakly radioactive, but pitchblende, a uranium ore, is 13 times more radioactive than the pure uranium metal because of the radium and other daughter isotopes it contains. Not only are unstable radium isotopes significant radioactivity emitters, but as the next stage in the decay chain they also generate radon, a heavy, inert, naturally occurring radioactive gas. Rock containing thorium and/or uranium (such as some granites) emits radon gas that can accumulate in enclosed places such as basements or underground mines.

Francium

Francium is a chemical element with symbol Fr and atomic number 87. It used to be known as eka-caesium. It is extremely radioactive; its most stable isotope, francium-223 (originally called actinium K after the natural decay chain it appears in), has a half-life of only 22 minutes. It is the second-most electropositive element, behind only caesium, and is the second rarest naturally occurring element (after astatine). The isotopes of francium decay quickly into astatine, radium, and radon. The electronic structure of a francium atom is [Rn] 7s1, and so the element is classed as an alkali metal.

Bulk francium has never been viewed. Because of the general appearance of the other elements in its periodic table column, it is assumed that francium would appear as a highly reactive metal, if enough could be collected together to be viewed as a bulk solid or liquid. Obtaining such a sample is highly improbable, since the extreme heat of decay caused by its short half-life would immediately vaporize any viewable quantity of the element.

Francium was discovered by Marguerite Perey in France (from which the element takes its name) in 1939. It was the last element first discovered in nature, rather than by synthesis. Outside the laboratory, francium is extremely rare, with trace amounts found in uranium and thorium ores, where the isotope francium-223 continually forms and decays. As little as 20–30 g (one ounce) exists at any given time throughout the Earth's crust; the other isotopes (except for francium-221) are entirely synthetic. The largest amount produced in the laboratory was a cluster of more than 300,000 atoms.

Group 3 element

Group 3 is a group of elements in the periodic table. This group, like other d-block groups, should contain four elements, but it is not agreed what elements belong in the group. Scandium (Sc) and yttrium (Y) are always included, but the other two spaces are usually occupied by lanthanum (La) and actinium (Ac), or by lutetium (Lu) and lawrencium (Lr); less frequently, it is considered the group should be expanded to 32 elements (with all the lanthanides and actinides included) or contracted to contain only scandium and yttrium. When the group is understood to contain all of the lanthanides, its trivial name is the rare-earth metals.

Three group 3 elements occur naturally: scandium, yttrium, and either lanthanum or lutetium. Lanthanum continues the trend started by two lighter members in general chemical behavior, while lutetium behaves more similarly to yttrium. While the choice of lutetium would be in accordance with the trend for period 6 transition metals to behave more similarly to their upper periodic table neighbors, the choice of lanthanum is in accordance with the trends in the s-block, which the group 3 elements are chemically more similar to. They all are silvery-white metals under standard conditions. The fourth element, either actinium or lawrencium, has only radioactive isotopes. Actinium, which occurs only in trace amounts, continues the trend in chemical behavior for metals that form tripositive ions with a noble gas configuration; synthetic lawrencium is calculated and partially shown to be more similar to lutetium and yttrium. So far, no experiments have been conducted to synthesize any element that could be the next group 3 element. Unbiunium (Ubu), which could be considered a group 3 element if preceded by lanthanum and actinium, might be synthesized in the near future, it being only three spaces away from the current heaviest element known, oganesson.

Isotopes of actinium

Actinium (89Ac) has no stable isotopes and no characteristic terrestrial isotopic composition, thus a standard atomic weight cannot be given. There are 32 known isotopes, from 205Ac to 236Ac, and 7 isomers. Three isotopes are found in nature, 225Ac, 227Ac and 228Ac, as intermediate decay products of, respectively, 237Np, 235U, and 232Th. 228Ac and 225Ac are extremely rare, so almost all natural actinium is 227Ac.

The most stable isotopes are 227Ac with a half-life of 21.772 years, 225Ac with a half-life of 10.0 days, and 226Ac with a half-life of 29.37 hours. All other isotopes have half-lives under 10 hours, and most under a minute. The shortest-lived known isotope is 217Ac with a half-life of 69 ns.

Purified 227Ac comes into equilibrium with its decay products (227Th and 223Fr) after 185 days.

Isotopes of bismuth

Bismuth (83Bi) has no stable isotopes, but does have one very long-lived isotope; thus, the standard atomic weight can be given as 208.98040(1). Although bismuth-209 is now known to be unstable, it has classically been considered to be a "stable" isotope because it has a half-life of over 1.9×1019 years, which is more than a billion times the age of the universe. Besides 209Bi, the most stable bismuth radioisotopes are 210mBi with a half-life of 3.04 million years, 208Bi with a half-life of 368,000 years and 207Bi, with a half-life of 32.9 years, none of which occur in nature. All other isotopes have half-lives under 1 year, most under a day. Of naturally occurring radioisotopes, the most stable is radiogenic 210Bi with a half-life of 5.012 days.

Commercially the radioactive isotope bismuth-213 can be produced by bombarding radium with bremsstrahlung photons from a linear particle accelerator. In 1997 an antibody conjugate with Bi-213, which has a 45-minute half-life, and decays with the emission of an alpha-particle, was used to treat patients with leukemia. This isotope has also been tried in Targeted Alpha Therapy (TAT) program, to treat a variety of cancers. Bismuth-213 is also found on the decay chain of uranium-233 which is the fuel "bred" by Thorium reactors.

Isotopes of radon

There are 35 known isotopes of radon (86Rn) from 195Rn to 229Rn; all are radioactive. The most stable isotope is 222Rn with a half-life of 3.823 days, which decays into 218Po. Four isotopes, 218, 219, 220, 222Rn occur in trace quantities in nature as decay products of, respectively, 218At, 223Ra, 224Ra, and 226Ra. 218Rn and 222Rn are intermediate steps in the decay chain for 238U, 219Rn is an intermediate step in the decay chain for 235U, and 220Rn occurs in the decay chain for 232Th.

Isotopes of thallium

Thallium (81Tl) has 37 isotopes with atomic masses that range from 176 to 212. 203Tl and 205Tl are the only stable isotopes and 204Tl is the most stable radioisotope with a half-life of 3.78 years. 207Tl, with a half-life of 4.77 minutes, has the longest half-life of naturally occurring radioisotopes.

Thallium-202 (half-life 12.23 days) can be made in a cyclotron while thallium-204 (half-life 3.78 years) is made by the neutron activation of stable thallium in a nuclear reactor.In the fully ionized state, the isotope 205Tl becomes beta-radioactive, decaying to 205Pb, but 203Tl remains stable.

Marguerite Perey

Marguerite Catherine Perey (19 October 1909 – 13 May 1975) was a French physicist and a student of Marie Curie. In 1939, Perey discovered the element francium by purifying samples of lanthanum that contained actinium. In 1962, she was the first woman to be elected to the French Académie des Sciences, an honor denied to her mentor Curie. Perey died of cancer in 1975.

Period 7 element

A period 7 element is one of the chemical elements in the seventh row (or period) of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The seventh period contains 32 elements, tied for the most with period 6, beginning with francium and ending with oganesson, the heaviest element currently discovered. As a rule, period 7 elements fill their 7s shells first, then their 5f, 6d, and 7p shells, in that order; however, there are exceptions, such as plutonium.

Periodic table (detailed cells)

The periodic table is a tabular method of displaying the chemical elements. It can show much information, after name, symbol and atomic number. Also, for each element mean atomic mass value for the natural isotopic composition of each element can be noted.

The two layout forms originate from two graphic forms of presentation of the same periodic table. Historically, when the f-block was identified it was drawn below the existing table, with markings for its in-table location (this page uses dots or asterisks). Also, a common presentation is to put all 15 lanthanide and actinide columns below, while the f-block only has 14 columns. One lanthanide and actinide each are d-block elements, belonging to group 3 with scandium and yttrium, though whether these are the first of each series (lanthanum and actinium) or the last (lutetium and lawrencium) has been disputed. The tables below show lanthanum and actinium as group 3 elements, as this is the more common form in the literature.

Although precursors to this table exist, its invention is generally credited to Russian chemist Dmitri Mendeleev in 1869. Mendeleev invented the table to illustrate recurring ("periodic") trends in the properties of the elements. The layout of the table has been refined and extended over time, as new elements have been discovered, and new theoretical models have been developed to explain chemical behavior.

Protactinium

Protactinium (formerly protoactinium) is a chemical element with symbol Pa and atomic number 91. It is a dense, silvery-gray actinide metal which readily reacts with oxygen, water vapor and inorganic acids. It forms various chemical compounds in which protactinium is usually present in the oxidation state +5, but it can also assume +4 and even +3 or +2 states. Concentrations of protactinium in the Earth's crust are typically a few parts per trillion, but may reach up to a few parts per million in some uraninite ore deposits. Because of its scarcity, high radioactivity and high toxicity, there are currently no uses for protactinium outside scientific research, and for this purpose, protactinium is mostly extracted from spent nuclear fuel.

Protactinium was first identified in 1913 by Kasimir Fajans and Oswald Helmuth Göhring and named brevium because of the short half-life of the specific isotope studied, i.e. protactinium-234. A more stable isotope of protactinium, 231Pa, was discovered in 1917/18 by Otto Hahn and Lise Meitner, and they chose the name proto-actinium, but the IUPAC finally named it "protactinium" in 1949 and confirmed Hahn and Meitner as discoverers. The new name meant "(nuclear) precursor of actinium" and reflected that actinium is a product of radioactive decay of protactinium. John Arnold Cranston (working with Frederick Soddy and Ada Hitchins) is also credited with discovering the most stable isotope in 1915, but delayed his announcement due to being called up for service in the First World War.The longest-lived and most abundant (nearly 100%) naturally occurring isotope of protactinium, protactinium-231, has a half-life of 32,760 years and is a decay product of uranium-235. Much smaller trace amounts of the short-lived protactinium-234 and its nuclear isomer protactinium-234m occur in the decay chain of uranium-238. Protactinium-233 results from the decay of thorium-233 as part of the chain of events used to produce uranium-233 by neutron irradiation of thorium-232. It is an undesired intermediate product in thorium-based nuclear reactors and is therefore removed from the active zone of the reactor during the breeding process. Analysis of the relative concentrations of various uranium, thorium and protactinium isotopes in water and minerals is used in radiometric dating of sediments which are up to 175,000 years old and in modeling of various geological processes.

Symbol (chemistry)

In relation to the chemical elements, a symbol is a code for a chemical element. Many functional groups have their own chemical symbol, e.g. Ph for the phenyl group, and Me for the methyl group. Chemical symbols for elements normally consist of one or two letters from the Latin alphabet, but can contain three when the element has a systematic temporary name (as of March 2017, no discovered elements have such a name), and are written with the first letter capitalized.

Earlier chemical element symbols stem from classical Latin and Greek vocabulary. For some elements, this is because the material was known in ancient times, while for others, the name is a more recent invention. For example, "He" is the symbol for helium (New Latin name, not known in ancient Roman times), "Pb" for lead (plumbum in Latin), and "Hg" for mercury (hydrargyrum in Greek). Some symbols come from other sources, like "W" for tungsten (Wolfram in German, not known in Roman times).

Temporary symbols assigned to newly or not-yet synthesized elements use 3-letter symbols based on their atomic numbers. For example, "Uno" was the temporary symbol for hassium (element 108) which had the temporary name of unniloctium.

Chemical symbols may be modified by the use of prepended superscripts or subscripts to specify a particular isotope of an atom. Additionally, appended superscripts may be used to indicate the ionization or oxidation state of an element. They are widely used in chemistry and they have been officially chosen by the International Union of Pure and Applied Chemistry (IUPAC). There are also some historical symbols that are no longer officially used.

Attached subscripts or superscripts specifying a nuclide or molecule have the following meanings and positions:

The nucleon number (mass number) is shown in the left superscript position (e.g., 14N). This number defines the specific isotope. Various letters, such as "m" and "f" may also be used here to indicate a nuclear isomer (e.g., 99mTc). Alternately, the number here can represent a specific spin state (e.g., 1O2). These details can be omitted if not relevant in a certain context.

The proton number (atomic number) may be indicated in the left subscript position (e.g., 64Gd). The atomic number is redundant to the chemical element, but is sometimes used to emphasize the change of numbers of nucleons in a nuclear reaction.

If necessary, a state of ionization or an excited state may be indicated in the right superscript position (e.g., state of ionization Ca2+).

The number of atoms of an element in a molecule or chemical compound is shown in the right subscript position (e.g., N2 or Fe2O3). If this number is one, it is normally omitted - the number one is then implicit.

A radical is indicated by a dot on the right side (e.g., Cl• for a neutral chlorine atom). This is often omitted unless relevant to a certain context because it is already deducible from the charge and atomic number information values.In Chinese, each chemical element has a dedicated character, usually created for the purpose (see Chemical elements in East Asian languages). However, Latin symbols are also used, especially in formulas.

A list of current, dated, as well as proposed and historical signs and symbols is included here with its signification. Also given is each element's atomic number, atomic weight or the atomic mass of the most stable isotope, group and period numbers on the periodic table, and etymology of the symbol.

Hazard pictographs are another type of symbols used in chemistry.

Unbiunium

Unbiunium, also known as eka-actinium or simply element 121, is the hypothetical chemical element with symbol Ubu and atomic number 121. Unbiunium and Ubu are the temporary systematic IUPAC name and symbol respectively, until a permanent name is decided upon. In the periodic table of the elements, it is expected to be the first of the superactinides, and the third element in the eighth period: analogously to lanthanum and actinium, it could be considered the fifth member of group 3 and the first member of the fifth-row transition metals. It has attracted attention because of some predictions that it may be in the island of stability, although newer calculations expect the island to actually occur at a slightly lower atomic number, closer to copernicium and flerovium.

Unbiunium has not yet been synthesized. Nevertheless, because it is only three elements away from the heaviest known element, oganesson (element 118), its synthesis may come in the near future; it is expected to be one of the last few reachable elements with current technology, and the limit may be anywhere between element 120 and 124. It will also likely be far more difficult to synthesize than the elements known so far up to 118, and still more difficult than elements 119 and 120. The team at RIKEN in Japan has plans to attempt the synthesis of element 121 in the future after its attempts on elements 119 and 120.

The position of unbiunium in the periodic table suggests that it would have similar properties to its lighter congeners, scandium, yttrium, lanthanum, and actinium; however, relativistic effects may cause some of its properties to differ from those expected from a straight application of periodic trends. For example, unbiunium is expected to have a s2p valence electron configuration instead of the s2d of its lighter congeners in group 3, but this is not expected to significantly affect its chemistry, which is predicted to be that of a normal group 3 element; it would on the other hand significantly lower its first ionisation energy beyond what would be expected from periodic trends.

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